On the ambiguity of the intermolecular interaction potential determined from spectroscopic data

V. I. Starikov

    Research output: Contribution to journalArticle

    Abstract

    It was shown that the interaction potential for NH3-Ar and NH3-He systems is determined ambiguously from experimentally measured broadening coefficients γ of NH3 absorption lines. Different sets of model interaction potentials, given the same calculation accuracy of the coefficients of broadening by pressure of these gases at room temperature, determine these coefficients for other temperatures in different ways. This difference is the most pronounced for NH3 lines in a NH3-He mixture. For NH3 lines in a NH3-Ar mixture, this difference becomes apparent for lines with small rotational quantum numbers K; this effect weakens for K → J.

    Original languageEnglish
    Pages (from-to)222-229
    Number of pages8
    JournalAtmospheric and Oceanic Optics
    Volume27
    Issue number3
    DOIs
    Publication statusPublished - 1 May 2014

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    ambiguity
    coefficients
    temperature
    interactions
    quantum numbers
    gas
    room temperature
    gases
    calculation
    effect

    ASJC Scopus subject areas

    • Oceanography
    • Atomic and Molecular Physics, and Optics
    • Earth-Surface Processes
    • Atmospheric Science

    Cite this

    On the ambiguity of the intermolecular interaction potential determined from spectroscopic data. / Starikov, V. I.

    In: Atmospheric and Oceanic Optics, Vol. 27, No. 3, 01.05.2014, p. 222-229.

    Research output: Contribution to journalArticle

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