On some new aspects in the conventional theory of vibration-rotation states of molecules

Yu S. Makushkin, O. V. Naumenko, O. N. Ulenikov

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

An approach which enables consideration of the problem of determining the energy spectrum of molecules containing vibrations of large amplitude within the framework of the standard Nielsen theory without the use of the Hougen-Bunker-Johns model is presented. The use of the H2O molecule as an example has shown that such an approach allows the behavior of rotational and centrifugal constants of (0v0) states with the increasing quantum number v to be described not only qualitatively but also quantitatively.

Original languageEnglish
Pages (from-to)221-230
Number of pages10
JournalJournal of Molecular Spectroscopy
Volume103
Issue number2
DOIs
Publication statusPublished - 1984

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vibration
Molecules
quantum numbers
molecules
energy spectra

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

Cite this

On some new aspects in the conventional theory of vibration-rotation states of molecules. / Makushkin, Yu S.; Naumenko, O. V.; Ulenikov, O. N.

In: Journal of Molecular Spectroscopy, Vol. 103, No. 2, 1984, p. 221-230.

Research output: Contribution to journalArticle

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