Abstract
Efficient nitrene precursors: Highly reactive iminoiodane-based nitrene precursors were prepared from ortho-alkoxyiodobenzenes. Owing to the presence of the ortho-substituent on the phenyl ring, these new iminoiodanes have excellent solubility in organic solvents and are efficient reagents for the catalytic aziridination of alkenes or the metal-free tosylamination of organic substrates (see scheme, Ts=tosyl).
| Original language | English |
|---|---|
| Pages (from-to) | 10538-10541 |
| Number of pages | 4 |
| Journal | Chemistry - A European Journal |
| Volume | 17 |
| Issue number | 38 |
| DOIs | |
| Publication status | Published - 12 Sep 2011 |
| Externally published | Yes |
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Keywords
- amination
- aziridination
- hypervalent compounds
- iodine
- oxidation
ASJC Scopus subject areas
- Chemistry(all)
Cite this
O-alkoxyphenyliminoiodanes : Highly efficient reagents for the catalytic aziridination of alkenes and the metal-free amination of organic substrates. / Yoshimura, Akira; Nemykin, Victor N.; Zhdankin, Viktor V.
In: Chemistry - A European Journal, Vol. 17, No. 38, 12.09.2011, p. 10538-10541.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - O-alkoxyphenyliminoiodanes
T2 - Highly efficient reagents for the catalytic aziridination of alkenes and the metal-free amination of organic substrates
AU - Yoshimura, Akira
AU - Nemykin, Victor N.
AU - Zhdankin, Viktor V.
PY - 2011/9/12
Y1 - 2011/9/12
N2 - Efficient nitrene precursors: Highly reactive iminoiodane-based nitrene precursors were prepared from ortho-alkoxyiodobenzenes. Owing to the presence of the ortho-substituent on the phenyl ring, these new iminoiodanes have excellent solubility in organic solvents and are efficient reagents for the catalytic aziridination of alkenes or the metal-free tosylamination of organic substrates (see scheme, Ts=tosyl).
AB - Efficient nitrene precursors: Highly reactive iminoiodane-based nitrene precursors were prepared from ortho-alkoxyiodobenzenes. Owing to the presence of the ortho-substituent on the phenyl ring, these new iminoiodanes have excellent solubility in organic solvents and are efficient reagents for the catalytic aziridination of alkenes or the metal-free tosylamination of organic substrates (see scheme, Ts=tosyl).
KW - amination
KW - aziridination
KW - hypervalent compounds
KW - iodine
KW - oxidation
UR - http://www.scopus.com/inward/record.url?scp=80052515754&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=80052515754&partnerID=8YFLogxK
U2 - 10.1002/chem.201102265
DO - 10.1002/chem.201102265
M3 - Article
VL - 17
SP - 10538
EP - 10541
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
SN - 0947-6539
IS - 38
ER -