N<sub>2</sub>-Cu-F: A complex of dinitrogen and cuprous fluoride characterized by rotational spectroscopy

Abstract

(Graph Presented) Dinitrogen bound: A compound formed by dinitrogen with cuprous fluoride has been synthesized by laser ablation of a copper rod in the presence of a source of F atoms and N₂. The rotational spectrum of ¹⁵N₂-Cu-F has been assigned, and the rotational, centrifugal, and nuclear hyperfine coupling constants have been determined. These constants and electronic structure calculations give conclusions about the nature of this novel molecule.

Original language	English
Pages (from-to)	6341-6343
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	38
DOIs	https://doi.org/10.1002/anie.200601988
Publication status	Published - 25 Sep 2006

Keywords

Copper
Dinitrogen
Electronic structure
Fluorine
Rotational spectroscopy

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1002/anie.200601988

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title = "N2-Cu-F: A complex of dinitrogen and cuprous fluoride characterized by rotational spectroscopy",

abstract = "(Graph Presented) Dinitrogen bound: A compound formed by dinitrogen with cuprous fluoride has been synthesized by laser ablation of a copper rod in the presence of a source of F atoms and N2. The rotational spectrum of 15N2-Cu-F has been assigned, and the rotational, centrifugal, and nuclear hyperfine coupling constants have been determined. These constants and electronic structure calculations give conclusions about the nature of this novel molecule.",

keywords = "Copper, Dinitrogen, Electronic structure, Fluorine, Rotational spectroscopy",

author = "Francis, {Simon G.} and Matthews, {Steven L.} and Poleshchuk, {Oleg Kh} and Walker, {Nicholas R.} and Legon, {Anthony C.}",

year = "2006",

month = sep,

day = "25",

doi = "10.1002/anie.200601988",

language = "English",

volume = "45",

pages = "6341--6343",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "38",

}

TY - JOUR

T1 - N2-Cu-F

T2 - A complex of dinitrogen and cuprous fluoride characterized by rotational spectroscopy

AU - Francis, Simon G.

AU - Matthews, Steven L.

AU - Poleshchuk, Oleg Kh

AU - Walker, Nicholas R.

AU - Legon, Anthony C.

PY - 2006/9/25

Y1 - 2006/9/25

N2 - (Graph Presented) Dinitrogen bound: A compound formed by dinitrogen with cuprous fluoride has been synthesized by laser ablation of a copper rod in the presence of a source of F atoms and N2. The rotational spectrum of 15N2-Cu-F has been assigned, and the rotational, centrifugal, and nuclear hyperfine coupling constants have been determined. These constants and electronic structure calculations give conclusions about the nature of this novel molecule.

AB - (Graph Presented) Dinitrogen bound: A compound formed by dinitrogen with cuprous fluoride has been synthesized by laser ablation of a copper rod in the presence of a source of F atoms and N2. The rotational spectrum of 15N2-Cu-F has been assigned, and the rotational, centrifugal, and nuclear hyperfine coupling constants have been determined. These constants and electronic structure calculations give conclusions about the nature of this novel molecule.

KW - Copper

KW - Dinitrogen

KW - Electronic structure

KW - Fluorine

KW - Rotational spectroscopy

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DO - 10.1002/anie.200601988

M3 - Article

C2 - 16937427

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SP - 6341

EP - 6343

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

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