N2-Cu-F

A complex of dinitrogen and cuprous fluoride characterized by rotational spectroscopy

Simon G. Francis, Steven L. Matthews, Oleg Kh Poleshchuk, Nicholas R. Walker, Anthony C. Legon

    Research output: Contribution to journal › Article

    31 Citations (Scopus)

    Abstract

    (Graph Presented) Dinitrogen bound: A compound formed by dinitrogen with cuprous fluoride has been synthesized by laser ablation of a copper rod in the presence of a source of F atoms and N2. The rotational spectrum of 15N2-Cu-F has been assigned, and the rotational, centrifugal, and nuclear hyperfine coupling constants have been determined. These constants and electronic structure calculations give conclusions about the nature of this novel molecule.

    Original languageEnglish
    Pages (from-to)6341-6343
    Number of pages3
    JournalAngewandte Chemie - International Edition
    Volume45
    Issue number38
    DOIs
    Publication statusPublished - 25 Sep 2006

    Fingerprint

    Laser ablation
    Fluorides
    Electronic structure
    Copper
    Spectroscopy
    Atoms
    Molecules

    Keywords

    • Copper
    • Dinitrogen
    • Electronic structure
    • Fluorine
    • Rotational spectroscopy

    ASJC Scopus subject areas

    • Chemistry(all)

    Cite this

    N2-Cu-F : A complex of dinitrogen and cuprous fluoride characterized by rotational spectroscopy. / Francis, Simon G.; Matthews, Steven L.; Poleshchuk, Oleg Kh; Walker, Nicholas R.; Legon, Anthony C.

    In: Angewandte Chemie - International Edition, Vol. 45, No. 38, 25.09.2006, p. 6341-6343.

    Research output: Contribution to journal › Article

    Francis, SG, Matthews, SL, Poleshchuk, OK, Walker, NR & Legon, AC 2006, 'N2-Cu-F: A complex of dinitrogen and cuprous fluoride characterized by rotational spectroscopy', Angewandte Chemie - International Edition, vol. 45, no. 38, pp. 6341-6343. https://doi.org/10.1002/anie.200601988
    Francis SG, Matthews SL, Poleshchuk OK, Walker NR, Legon AC. N2-Cu-F: A complex of dinitrogen and cuprous fluoride characterized by rotational spectroscopy. Angewandte Chemie - International Edition. 2006 Sep 25;45(38):6341-6343. https://doi.org/10.1002/anie.200601988
    Francis, Simon G. ; Matthews, Steven L. ; Poleshchuk, Oleg Kh ; Walker, Nicholas R. ; Legon, Anthony C. / N2-Cu-F : A complex of dinitrogen and cuprous fluoride characterized by rotational spectroscopy. In: Angewandte Chemie - International Edition. 2006 ; Vol. 45, No. 38. pp. 6341-6343.
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    AU - Poleshchuk, Oleg Kh

    AU - Walker, Nicholas R.

    AU - Legon, Anthony C.

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    KW - Rotational spectroscopy

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