NQR study of hydrogen bonded trichloroacetic acid complexes

O. Kh Poleshchuk, Yu K. Maksyutin, O. F. Sychev, K. K. Koshelev, I. G. Orlov

    Research output: Contribution to journalArticle

    1 Citation (Scopus)

    Abstract

    1. The35Cl NQR method was used to study 10 complexes of trichloroacetic acid with lactams, ketones, amides, and amines. 2. All of the studied compounds are complexes with a hydrogen bond. 3. The relation between the basicity of the donor and the average frequency shift is linear. 4. Employing the method of complete neglect of differential overlapping (second variation), it was shown by calculation that the relation between the negative charges on the chlorine atoms and the negative charge on the oxygen atom of the hydroxyl of the acceptor molecule is nonlinear.

    Original languageEnglish
    Pages (from-to)1325-1327
    Number of pages3
    JournalBulletin of the Academy of Sciences of the USSR Division of Chemical Science
    Volume24
    Issue number6
    DOIs
    Publication statusPublished - Jun 1975

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    Trichloroacetic Acid
    Hydrogen
    Lactams
    Atoms
    Chlorine
    Alkalinity
    Ketones
    Amides
    Hydroxyl Radical
    Amines
    Hydrogen bonds
    Oxygen
    Molecules

    ASJC Scopus subject areas

    • Chemistry(all)

    Cite this

    Poleshchuk, O. K., Maksyutin, Y. K., Sychev, O. F., Koshelev, K. K., & Orlov, I. G. (1975). NQR study of hydrogen bonded trichloroacetic acid complexes. Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 24(6), 1325-1327. https://doi.org/10.1007/BF00922076

    NQR study of hydrogen bonded trichloroacetic acid complexes. / Poleshchuk, O. Kh; Maksyutin, Yu K.; Sychev, O. F.; Koshelev, K. K.; Orlov, I. G.

    In: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, Vol. 24, No. 6, 06.1975, p. 1325-1327.

    Research output: Contribution to journalArticle

    Poleshchuk, O. Kh ; Maksyutin, Yu K. ; Sychev, O. F. ; Koshelev, K. K. ; Orlov, I. G. / NQR study of hydrogen bonded trichloroacetic acid complexes. In: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1975 ; Vol. 24, No. 6. pp. 1325-1327.
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