Novel highly energetic pyrazoles

N-fluorodinitromethyl and N-[(difluoroamino)dinitromethyl] derivatives

Igor L. Dalinger, Aleksandr Kh Shakhnes, Konstantin A. Monogarov, Kyrill Yu Suponitsky, Aleksei B. Sheremetev

    Research output: Contribution to journalArticle

    35 Citations (Scopus)

    Abstract

    Treatment of 1,1-dinitro-1-(3,5-dinitropyrazol-1-yl)methanide with electrophilic fluorinating or difluoroaminating agents affords the corresponding fluorodinitromethyl or (difluoroamino)dinitromethyl pyrazole derivatives. Single crystal X-ray diffraction analysis shows a remarkable high density and DSC exhibits acceptable thermal stability of the compounds.

    Original languageEnglish
    Pages (from-to)429-431
    Number of pages3
    JournalMendeleev Communications
    Volume25
    Issue number6
    DOIs
    Publication statusPublished - 1 Nov 2015

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    Pyrazoles
    X ray diffraction analysis
    Thermodynamic stability
    Single crystals
    Derivatives
    pyrazole

    ASJC Scopus subject areas

    • Chemistry(all)

    Cite this

    Dalinger, I. L., Shakhnes, A. K., Monogarov, K. A., Suponitsky, K. Y., & Sheremetev, A. B. (2015). Novel highly energetic pyrazoles: N-fluorodinitromethyl and N-[(difluoroamino)dinitromethyl] derivatives. Mendeleev Communications, 25(6), 429-431. https://doi.org/10.1016/j.mencom.2015.11.010

    Novel highly energetic pyrazoles : N-fluorodinitromethyl and N-[(difluoroamino)dinitromethyl] derivatives. / Dalinger, Igor L.; Shakhnes, Aleksandr Kh; Monogarov, Konstantin A.; Suponitsky, Kyrill Yu; Sheremetev, Aleksei B.

    In: Mendeleev Communications, Vol. 25, No. 6, 01.11.2015, p. 429-431.

    Research output: Contribution to journalArticle

    Dalinger, IL, Shakhnes, AK, Monogarov, KA, Suponitsky, KY & Sheremetev, AB 2015, 'Novel highly energetic pyrazoles: N-fluorodinitromethyl and N-[(difluoroamino)dinitromethyl] derivatives', Mendeleev Communications, vol. 25, no. 6, pp. 429-431. https://doi.org/10.1016/j.mencom.2015.11.010
    Dalinger, Igor L. ; Shakhnes, Aleksandr Kh ; Monogarov, Konstantin A. ; Suponitsky, Kyrill Yu ; Sheremetev, Aleksei B. / Novel highly energetic pyrazoles : N-fluorodinitromethyl and N-[(difluoroamino)dinitromethyl] derivatives. In: Mendeleev Communications. 2015 ; Vol. 25, No. 6. pp. 429-431.
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    AU - Monogarov, Konstantin A.

    AU - Suponitsky, Kyrill Yu

    AU - Sheremetev, Aleksei B.

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