Abstract
This review describes recent results regarding voltammetric and amperometric determination of submicromolar concentrations of various environmentally important biologically active organic substances using nontraditional types of electrodes either in batch analysis or in flow liquid systems (especially HPLC or FIA with electrochemical detection). Attention is paid to solid amalgam electrodes (environmentally friendly alternatives to mercury electrodes), to carbon paste electrodes with easily renewable surface, to boron doped diamond film electrodes with very low noise and broad potential window, and to inexpensive solid composite electrodes with high signal-to-noise ratio, compatibility with organic solvents and easy mechanical or electrochemical pretreatment. The review concentrates on our own results in the context of the general development in the filed.
| Original language | English |
|---|---|
| Pages (from-to) | 2003-2014 |
| Number of pages | 12 |
| Journal | Electroanalysis |
| Volume | 19 |
| Issue number | 19-20 |
| DOIs | |
| Publication status | Published - 1 Oct 2007 |
| Externally published | Yes |
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Keywords
- Amperometry
- Boron doped diamond film electrodes
- Carbon paste electrodes
- Chemical carcinogens
- FIA-ED
- HPLC-ED
- Organic pollutants
- Pesticides
- Phenols
- Solid amalgam electrodes
- Solid composite electrodes
- Voltammetry
ASJC Scopus subject areas
- Analytical Chemistry
- Electrochemistry
Cite this
Nontraditional electrode materials in environmental analysis of biologically active organic compounds. / Barek, Jiří; Fischer, Jan; Navrátil, Tomáš; Pecková, Karolina; Yosypchuk, Bogdan; Zima, Jiří.
In: Electroanalysis, Vol. 19, No. 19-20, 01.10.2007, p. 2003-2014.Research output: Contribution to journal › Review article
}
TY - JOUR
T1 - Nontraditional electrode materials in environmental analysis of biologically active organic compounds
AU - Barek, Jiří
AU - Fischer, Jan
AU - Navrátil, Tomáš
AU - Pecková, Karolina
AU - Yosypchuk, Bogdan
AU - Zima, Jiří
PY - 2007/10/1
Y1 - 2007/10/1
N2 - This review describes recent results regarding voltammetric and amperometric determination of submicromolar concentrations of various environmentally important biologically active organic substances using nontraditional types of electrodes either in batch analysis or in flow liquid systems (especially HPLC or FIA with electrochemical detection). Attention is paid to solid amalgam electrodes (environmentally friendly alternatives to mercury electrodes), to carbon paste electrodes with easily renewable surface, to boron doped diamond film electrodes with very low noise and broad potential window, and to inexpensive solid composite electrodes with high signal-to-noise ratio, compatibility with organic solvents and easy mechanical or electrochemical pretreatment. The review concentrates on our own results in the context of the general development in the filed.
AB - This review describes recent results regarding voltammetric and amperometric determination of submicromolar concentrations of various environmentally important biologically active organic substances using nontraditional types of electrodes either in batch analysis or in flow liquid systems (especially HPLC or FIA with electrochemical detection). Attention is paid to solid amalgam electrodes (environmentally friendly alternatives to mercury electrodes), to carbon paste electrodes with easily renewable surface, to boron doped diamond film electrodes with very low noise and broad potential window, and to inexpensive solid composite electrodes with high signal-to-noise ratio, compatibility with organic solvents and easy mechanical or electrochemical pretreatment. The review concentrates on our own results in the context of the general development in the filed.
KW - Amperometry
KW - Boron doped diamond film electrodes
KW - Carbon paste electrodes
KW - Chemical carcinogens
KW - FIA-ED
KW - HPLC-ED
KW - Organic pollutants
KW - Pesticides
KW - Phenols
KW - Solid amalgam electrodes
KW - Solid composite electrodes
KW - Voltammetry
UR - http://www.scopus.com/inward/record.url?scp=35348989847&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=35348989847&partnerID=8YFLogxK
U2 - 10.1002/elan.200703918
DO - 10.1002/elan.200703918
M3 - Review article
AN - SCOPUS:35348989847
VL - 19
SP - 2003
EP - 2014
JO - Macromolecular Chemistry and Physics
JF - Macromolecular Chemistry and Physics
SN - 1040-0397
IS - 19-20
ER -