NMR in photoinduced chemical exchange systems: Theoretical basis of double-resonance inverse fractional population transfer

S. P. Babailov, D. A. Mainichev

Research output: Contribution to journalReview article

3 Citations (Scopus)

Abstract

The analytical expression describing dynamics of the nuclear magnetization with the use of double-resonance NMR in the transfer of inverse fractional population under photoinduced chemical exchange is obtained. An experimental procedure for the definition of effective rate constants and quantum yield of responses is considered. The technical approach created allows for planning experimental strategies for the study of photoinduced chemical exchange in any solvable substances.

Original languageEnglish
Pages (from-to)299-305
Number of pages7
JournalConcepts in Magnetic Resonance Part A: Bridging Education and Research
Volume28
Issue number4
DOIs
Publication statusPublished - Jul 2006
Externally publishedYes

Keywords

  • Chemical exchange
  • Double-resonance inverse fractional population transfer
  • Dynamic NMR
  • Kinetics
  • Rate constants
  • reversible photoinduced chemical reactions

ASJC Scopus subject areas

  • Chemistry(all)
  • Physical and Theoretical Chemistry
  • Spectroscopy

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