NMR in photo-induced chemical exchange systems. Double-resonance inverse fractional population transfer application for investigation of 1,2-(2,2′-dipyridyl)ethene photoisomerization kinetics

Sergey P. Babailov, Alexander I. Kruppa, Evgeni M. Glebov, Victor F. Plyusnin

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

The analytical expression describing the dynamics of nuclear magnetization with the use of double-resonance NMR by the procedure of inverse fractional population transfer in requirements of photo-induced chemical exchange (PICE) is obtained in this article. Laser-induced (λ = 308 nm) photoisomerization of 1,2-(2,2′-dipyridyl)ethene was studied by NMR and UV absorption spectroscopy under irreversible and photostationary conditions.

Original languageEnglish
Pages (from-to)337-346
Number of pages10
JournalConcepts in Magnetic Resonance Part A: Bridging Education and Research
Volume28
Issue number5
DOIs
Publication statusPublished - Sep 2006
Externally publishedYes

Keywords

  • cis-trans photoisomerization
  • Double-resonance NMR
  • Dynamic NMR
  • Inverse fractional population transfer
  • Photo-induced chemical exchange
  • Photochemistry
  • Reversible photochemical processes
  • UV absorption spectroscopy

ASJC Scopus subject areas

  • Chemistry(all)
  • Physical and Theoretical Chemistry
  • Spectroscopy

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