NMR application for a study of reversible photochemical kinetics: A multisite case

Abstract

Expressions describing the NMR signal shape for photoinduced chemical exchange in a multi-site system without spin-spin splitting are obtained by dynamic NMR techniques. The methods provide a framework for planning experimental strategies aimed at studies of photoinduced chemical exchange in dissolved substances.

Original language	English
Pages (from-to)	140-146
Number of pages	7
Journal	Concepts in Magnetic Resonance Part A: Bridging Education and Research
Volume	30
Issue number	3
DOIs	https://doi.org/10.1002/cmr.a.20082
Publication status	Published - May 2007
Externally published	Yes

Keywords

Dynamic NMR
Lineshape analysis
Multisite chemical exchange
Rate constants
Reversible photoinduced chemical reactions

ASJC Scopus subject areas

Chemistry(all)
Physical and Theoretical Chemistry
Spectroscopy

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10.1002/cmr.a.20082

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title = "NMR application for a study of reversible photochemical kinetics: A multisite case",

abstract = "Expressions describing the NMR signal shape for photoinduced chemical exchange in a multi-site system without spin-spin splitting are obtained by dynamic NMR techniques. The methods provide a framework for planning experimental strategies aimed at studies of photoinduced chemical exchange in dissolved substances.",

keywords = "Dynamic NMR, Lineshape analysis, Multisite chemical exchange, Rate constants, Reversible photoinduced chemical reactions",

author = "Babailov, {S. P.} and Mainichev, {D. A.} and Purtov, {P. A.}",

year = "2007",

month = may,

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journal = "Concepts in Magnetic Resonance Part A: Bridging Education and Research",

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AU - Purtov, P. A.

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AB - Expressions describing the NMR signal shape for photoinduced chemical exchange in a multi-site system without spin-spin splitting are obtained by dynamic NMR techniques. The methods provide a framework for planning experimental strategies aimed at studies of photoinduced chemical exchange in dissolved substances.

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KW - Lineshape analysis

KW - Multisite chemical exchange

KW - Rate constants

KW - Reversible photoinduced chemical reactions

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