Ni-Cu and Ni-Co alloys: Synthesis, structure, and catalytic activity for the decomposition of chlorinated hydrocarbons

A. V. Rudnev, A. S. Lysakova, Pavel E. Plyusnin, Yu I. Bauman, Yu V. Shubin, I. V. Mishakov, Aleksey A. Vedyagin, R. A. Buyanov

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Homogeneous Ni x Cu1 - x and Ni x Co 1 - x (x = 0.90-0.99) alloys have been prepared through the coprecipitation of precursors (hydroxides or carbonates) and reduction of the precipitate. The formation of single-phase Ni x M1 - x alloys in all of the samples has been confirmed by X-ray diffraction. We have assessed the catalytic activity of the alloys for 1,2-dichloroethane decomposition with carbon nanomaterial (CNM) formation. The highest catalytic activity (CNM yield, 26-27 g/gcat) was offered by the nickel alloys containing ∼1 at % Cu or Co. The carbon material obtained has the form of segmented submicron wires with high morphological uniformity.

Original languageEnglish
Pages (from-to)566-571
Number of pages6
JournalInorganic Materials
Volume50
Issue number6
DOIs
Publication statusPublished - 2014
Externally publishedYes

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Chlorinated Hydrocarbons
Catalyst activity
Carbon
Decomposition
Nanostructured materials
Hydroxides
Carbonates
Nickel alloys
Coprecipitation
Precipitates
Wire
X ray diffraction

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Chemical Engineering(all)
  • Materials Chemistry
  • Metals and Alloys

Cite this

Ni-Cu and Ni-Co alloys : Synthesis, structure, and catalytic activity for the decomposition of chlorinated hydrocarbons. / Rudnev, A. V.; Lysakova, A. S.; Plyusnin, Pavel E.; Bauman, Yu I.; Shubin, Yu V.; Mishakov, I. V.; Vedyagin, Aleksey A.; Buyanov, R. A.

In: Inorganic Materials, Vol. 50, No. 6, 2014, p. 566-571.

Research output: Contribution to journalArticle

Rudnev, A. V. ; Lysakova, A. S. ; Plyusnin, Pavel E. ; Bauman, Yu I. ; Shubin, Yu V. ; Mishakov, I. V. ; Vedyagin, Aleksey A. ; Buyanov, R. A. / Ni-Cu and Ni-Co alloys : Synthesis, structure, and catalytic activity for the decomposition of chlorinated hydrocarbons. In: Inorganic Materials. 2014 ; Vol. 50, No. 6. pp. 566-571.
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AU - Bauman, Yu I.

AU - Shubin, Yu V.

AU - Mishakov, I. V.

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