New type of prototropic tautomerism involving carbon, hydrogen, and oxygen atoms

Abstract

A low-molecular weight analog of the vinyl chloride-maleic anhydride copolymer, chloromethylsuccinic anhydride gives rise to a new type of prototropic tautomerism, cyclic anhydride-enol, with formation of quasiaromatic enol and dienol derivatives. The ratio of the anhydride and enol tautomers in solution at room temperature is 7:1.

Original language	English
Pages (from-to)	462-466
Number of pages	5
Journal	Russian Journal of Organic Chemistry
Volume	40
Issue number	4
DOIs	https://doi.org/10.1023/B:RUJO.0000036062.82821.ab
Publication status	Published - Apr 2004

ASJC Scopus subject areas

Organic Chemistry

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10.1023/B:RUJO.0000036062.82821.ab

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Filimoshkin, A. G., Kosolapova, V. F., Petrenko, T. V., Aksenov, V. S., & Poleshchuk, O. K. (2004). New type of prototropic tautomerism involving carbon, hydrogen, and oxygen atoms. Russian Journal of Organic Chemistry, 40(4), 462-466. https://doi.org/10.1023/B:RUJO.0000036062.82821.ab

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abstract = "A low-molecular weight analog of the vinyl chloride-maleic anhydride copolymer, chloromethylsuccinic anhydride gives rise to a new type of prototropic tautomerism, cyclic anhydride-enol, with formation of quasiaromatic enol and dienol derivatives. The ratio of the anhydride and enol tautomers in solution at room temperature is 7:1.",

author = "Filimoshkin, {A. G.} and Kosolapova, {V. F.} and Petrenko, {T. V.} and Aksenov, {V. S.} and Poleshchuk, {O. Kh}",

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AU - Filimoshkin, A. G.

AU - Kosolapova, V. F.

AU - Petrenko, T. V.

AU - Aksenov, V. S.

AU - Poleshchuk, O. Kh

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N2 - A low-molecular weight analog of the vinyl chloride-maleic anhydride copolymer, chloromethylsuccinic anhydride gives rise to a new type of prototropic tautomerism, cyclic anhydride-enol, with formation of quasiaromatic enol and dienol derivatives. The ratio of the anhydride and enol tautomers in solution at room temperature is 7:1.

AB - A low-molecular weight analog of the vinyl chloride-maleic anhydride copolymer, chloromethylsuccinic anhydride gives rise to a new type of prototropic tautomerism, cyclic anhydride-enol, with formation of quasiaromatic enol and dienol derivatives. The ratio of the anhydride and enol tautomers in solution at room temperature is 7:1.

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