New oxidative transformations of alkenes and alkynes under the action of diacetoxyiodobenzene

M. S. Yusubov, G. A. Zholobova, I. L. Filimonova, Ki Whan Chi

Research School of Chemistry & Applied Biomedical Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

Treatment of alkenes and alkynes with diacetoxyiodobenzene activated by mineral and organic acids predominantly results in oxidative rearrangement. 1,4-Diphenylbutadiene in MeOH gives 3,4-dimethoxy-1,4-diphenylbut-1-ene.

Original language	English
Pages (from-to)	1735-1742
Number of pages	8
Journal	Russian Chemical Bulletin
Volume	53
Issue number	8
DOIs	https://doi.org/10.1007/s11172-005-0027-8
Publication status	Published - 1 Aug 2004

Keywords

Alkenes
Alkynes
Diacetoxyiodobenzene
Oxidative rearrangement
Polyvalent iodine compounds

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1007/s11172-005-0027-8

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Cite this

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title = "New oxidative transformations of alkenes and alkynes under the action of diacetoxyiodobenzene",

abstract = "Treatment of alkenes and alkynes with diacetoxyiodobenzene activated by mineral and organic acids predominantly results in oxidative rearrangement. 1,4-Diphenylbutadiene in MeOH gives 3,4-dimethoxy-1,4-diphenylbut-1-ene.",

keywords = "Alkenes, Alkynes, Diacetoxyiodobenzene, Oxidative rearrangement, Polyvalent iodine compounds",

author = "Yusubov, {M. S.} and Zholobova, {G. A.} and Filimonova, {I. L.} and Chi, {Ki Whan}",

year = "2004",

month = aug,

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language = "English",

volume = "53",

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journal = "Russian Chemical Bulletin",

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T1 - New oxidative transformations of alkenes and alkynes under the action of diacetoxyiodobenzene

AU - Yusubov, M. S.

AU - Zholobova, G. A.

AU - Filimonova, I. L.

AU - Chi, Ki Whan

PY - 2004/8/1

Y1 - 2004/8/1

N2 - Treatment of alkenes and alkynes with diacetoxyiodobenzene activated by mineral and organic acids predominantly results in oxidative rearrangement. 1,4-Diphenylbutadiene in MeOH gives 3,4-dimethoxy-1,4-diphenylbut-1-ene.

AB - Treatment of alkenes and alkynes with diacetoxyiodobenzene activated by mineral and organic acids predominantly results in oxidative rearrangement. 1,4-Diphenylbutadiene in MeOH gives 3,4-dimethoxy-1,4-diphenylbut-1-ene.

KW - Alkenes

KW - Alkynes

KW - Diacetoxyiodobenzene

KW - Oxidative rearrangement

KW - Polyvalent iodine compounds

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