New oligogermane with a five coordinate germanium atom: the preparation of 1-germylgermatrane

The preparation of 1-germylgermatrane

Kirill V. Zaitsev, Andrei V. Churakov, Oleg Kh Poleshchuk, Yuri F. Oprunenko, Galina S. Zaitseva, Sergey S. Karlov

    Research output: Contribution to journal › Article

    16 Citations (Scopus)

    Abstract

    The first example of an oligogermane, N(CH2CH2O) 3Ge-Ge(SiMe3)3 (1), containing a hypercoordinate germanium atom was prepared and characterized by various methods (NMR, UV/vis, and X-ray analysis). The electronic structure of compound 1 was investigated via DFT calculations. This journal is

    Original languageEnglish
    Pages (from-to)6605-6609
    Number of pages5
    JournalDalton Transactions
    Volume43
    Issue number18
    DOIs
    Publication statusPublished - 14 May 2014

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    Germanium
    X ray analysis
    Discrete Fourier transforms
    Electronic structure
    Nuclear magnetic resonance
    Atoms

    ASJC Scopus subject areas

    • Inorganic Chemistry

    Cite this

    Zaitsev, K. V., Churakov, A. V., Poleshchuk, O. K., Oprunenko, Y. F., Zaitseva, G. S., & Karlov, S. S. (2014). New oligogermane with a five coordinate germanium atom: the preparation of 1-germylgermatrane: The preparation of 1-germylgermatrane. Dalton Transactions, 43(18), 6605-6609. https://doi.org/10.1039/c3dt53523a

    New oligogermane with a five coordinate germanium atom: the preparation of 1-germylgermatrane : The preparation of 1-germylgermatrane. / Zaitsev, Kirill V.; Churakov, Andrei V.; Poleshchuk, Oleg Kh; Oprunenko, Yuri F.; Zaitseva, Galina S.; Karlov, Sergey S.

    In: Dalton Transactions, Vol. 43, No. 18, 14.05.2014, p. 6605-6609.

    Research output: Contribution to journal › Article

    Zaitsev, KV, Churakov, AV, Poleshchuk, OK, Oprunenko, YF, Zaitseva, GS & Karlov, SS 2014, 'New oligogermane with a five coordinate germanium atom: the preparation of 1-germylgermatrane: The preparation of 1-germylgermatrane', Dalton Transactions, vol. 43, no. 18, pp. 6605-6609. https://doi.org/10.1039/c3dt53523a
    Zaitsev KV, Churakov AV, Poleshchuk OK, Oprunenko YF, Zaitseva GS, Karlov SS. New oligogermane with a five coordinate germanium atom: the preparation of 1-germylgermatrane: The preparation of 1-germylgermatrane. Dalton Transactions. 2014 May 14;43(18):6605-6609. https://doi.org/10.1039/c3dt53523a
    Zaitsev, Kirill V. ; Churakov, Andrei V. ; Poleshchuk, Oleg Kh ; Oprunenko, Yuri F. ; Zaitseva, Galina S. ; Karlov, Sergey S. / New oligogermane with a five coordinate germanium atom: the preparation of 1-germylgermatrane : The preparation of 1-germylgermatrane. In: Dalton Transactions. 2014 ; Vol. 43, No. 18. pp. 6605-6609.
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