New functional form of the dependence of rotational and centrifugal distortional parameters of the water molecule on the bending vibration v2

V. I. Starikov, Vl G. Tyuterev

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    15 Citations (Scopus)


    A regularity is found for the anomalous behavior of the rotational and centrifugal distortion parameters of the water molecule in the bending states (0v20). This regularity is described by simple nonpolynomial formulae which are used to calculate Watson's parameters A, ΔK, ΔKJ, δK, HK, HKJ, hK, LK, LKKJ, and lK for the states (010), (020), (030), and (040). The calculated v2 behavior of these parameters is in agreement with the experimental one.

    Original languageEnglish
    Pages (from-to)288-296
    Number of pages9
    JournalJournal of Molecular Spectroscopy
    Issue number2
    Publication statusPublished - 1982


    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry
    • Spectroscopy
    • Atomic and Molecular Physics, and Optics

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