New functional form of the dependence of rotational and centrifugal distortional parameters of the water molecule on the bending vibration v₂

V. I. Starikov, Vl G. Tyuterev

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Abstract

A regularity is found for the anomalous behavior of the rotational and centrifugal distortion parameters of the water molecule in the bending states (0v₂0). This regularity is described by simple nonpolynomial formulae which are used to calculate Watson's parameters A, Δ_K, Δ_KJ, δ_K, H_K, H_KJ, h_K, L_K, L_KKJ, and l_K for the states (010), (020), (030), and (040). The calculated v₂ behavior of these parameters is in agreement with the experimental one.

Original language	English
Pages (from-to)	288-296
Number of pages	9
Journal	Journal of Molecular Spectroscopy
Volume	95
Issue number	2
DOIs	https://doi.org/10.1016/0022-2852(82)90129-1
Publication status	Published - 1982

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ASJC Scopus subject areas

Physical and Theoretical Chemistry
Spectroscopy
Atomic and Molecular Physics, and Optics

Cite this

Starikov, V. I., & Tyuterev, V. G. (1982). New functional form of the dependence of rotational and centrifugal distortional parameters of the water molecule on the bending vibration v₂ Journal of Molecular Spectroscopy, 95(2), 288-296. https://doi.org/10.1016/0022-2852(82)90129-1

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abstract = "A regularity is found for the anomalous behavior of the rotational and centrifugal distortion parameters of the water molecule in the bending states (0v20). This regularity is described by simple nonpolynomial formulae which are used to calculate Watson's parameters A, ΔK, ΔKJ, δK, HK, HKJ, hK, LK, LKKJ, and lK for the states (010), (020), (030), and (040). The calculated v2 behavior of these parameters is in agreement with the experimental one.",

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N2 - A regularity is found for the anomalous behavior of the rotational and centrifugal distortion parameters of the water molecule in the bending states (0v20). This regularity is described by simple nonpolynomial formulae which are used to calculate Watson's parameters A, ΔK, ΔKJ, δK, HK, HKJ, hK, LK, LKKJ, and lK for the states (010), (020), (030), and (040). The calculated v2 behavior of these parameters is in agreement with the experimental one.

AB - A regularity is found for the anomalous behavior of the rotational and centrifugal distortion parameters of the water molecule in the bending states (0v20). This regularity is described by simple nonpolynomial formulae which are used to calculate Watson's parameters A, ΔK, ΔKJ, δK, HK, HKJ, hK, LK, LKKJ, and lK for the states (010), (020), (030), and (040). The calculated v2 behavior of these parameters is in agreement with the experimental one.

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10.1016/0022-2852(82)90129-1