Abstract
The electrochemical behavior of coarse-grained and nanostructured titanium in various media is studied by the methods of potentiodynamic polarization and impedance spectroscopy and by the analysis of the etching curves. It is found that the dissolution rate of nanostructured titanium increases in a Ringer- Locke solution at 37°C in comparison with the coarse-grained state owing to a more defective structure of the natural oxide layer on the surface of nanostructured titanium and its lower polarization resistance. It is demonstrated that the etching of nanostructured titanium in a mixture of hydrofluoric and sulfuric acids occurs mostly via the mechanism of local destruction, whereas overall uniform etching occurs in the case of coarsegrained titanium, which is considerably displayed in a range from 40 to 75°C.
| Original language | English |
|---|---|
| Pages (from-to) | 44-53 |
| Number of pages | 10 |
| Journal | Inorganic Materials: Applied Research |
| Volume | 5 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 2014 |
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Keywords
- Coarse-grained and nanostructured titanium
- Corrosion
- Impedance spectroscopy
- Implants
- Mechanical properties
- Polarization curves
- Structure
ASJC Scopus subject areas
- Materials Science(all)
- Engineering(all)
Cite this
Nanostructured titanium : Structure, mechanical and electrochemical properties. / Legostaeva, E. V.; Egorkin, V. S.; Sinebryukhov, S. L.; Eroshenko, A. Yu; Lyamina, G. V.; Komarova, E. G.; Gnedenkov, S. V.; Sharkeev, Yu P.
In: Inorganic Materials: Applied Research, Vol. 5, No. 1, 2014, p. 44-53.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Nanostructured titanium
T2 - Structure, mechanical and electrochemical properties
AU - Legostaeva, E. V.
AU - Egorkin, V. S.
AU - Sinebryukhov, S. L.
AU - Eroshenko, A. Yu
AU - Lyamina, G. V.
AU - Komarova, E. G.
AU - Gnedenkov, S. V.
AU - Sharkeev, Yu P.
PY - 2014
Y1 - 2014
N2 - The electrochemical behavior of coarse-grained and nanostructured titanium in various media is studied by the methods of potentiodynamic polarization and impedance spectroscopy and by the analysis of the etching curves. It is found that the dissolution rate of nanostructured titanium increases in a Ringer- Locke solution at 37°C in comparison with the coarse-grained state owing to a more defective structure of the natural oxide layer on the surface of nanostructured titanium and its lower polarization resistance. It is demonstrated that the etching of nanostructured titanium in a mixture of hydrofluoric and sulfuric acids occurs mostly via the mechanism of local destruction, whereas overall uniform etching occurs in the case of coarsegrained titanium, which is considerably displayed in a range from 40 to 75°C.
AB - The electrochemical behavior of coarse-grained and nanostructured titanium in various media is studied by the methods of potentiodynamic polarization and impedance spectroscopy and by the analysis of the etching curves. It is found that the dissolution rate of nanostructured titanium increases in a Ringer- Locke solution at 37°C in comparison with the coarse-grained state owing to a more defective structure of the natural oxide layer on the surface of nanostructured titanium and its lower polarization resistance. It is demonstrated that the etching of nanostructured titanium in a mixture of hydrofluoric and sulfuric acids occurs mostly via the mechanism of local destruction, whereas overall uniform etching occurs in the case of coarsegrained titanium, which is considerably displayed in a range from 40 to 75°C.
KW - Coarse-grained and nanostructured titanium
KW - Corrosion
KW - Impedance spectroscopy
KW - Implants
KW - Mechanical properties
KW - Polarization curves
KW - Structure
UR - http://www.scopus.com/inward/record.url?scp=84898973449&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84898973449&partnerID=8YFLogxK
U2 - 10.1134/S2075113314010079
DO - 10.1134/S2075113314010079
M3 - Article
AN - SCOPUS:84898973449
VL - 5
SP - 44
EP - 53
JO - Inorganic Materials: Applied Research
JF - Inorganic Materials: Applied Research
SN - 2075-1133
IS - 1
ER -