Mononuclear bromide complexes of Sb(V): crystal structures and thermal behaviour

Sergey A. Adonin, Mikhail A. Bondarenko, Denis G. Samsonenko, Evgeniy Yu Semitut, Maxim N. Sokolov, Vladimir P. Fedin

    Research output: Contribution to journalArticle

    6 Citations (Scopus)

    Abstract

    Reactions of Sb2O3 dissolved in HBr/Br2 and bromides of pyridinium-derived cations result in mononuclear complexes of Sb(V) – (cation)[SbBr6] (cation = 2-chloropyridinium (1), 2-bromopyridinium (2)). Thermal behaviour of 1 and 2, as well as similar previously reported complexes Et4N [SbBr6] (3) and (N-EtPy)[SbBr6] (4), was studied and discussed.

    Original languageEnglish
    Pages (from-to)102-106
    Number of pages5
    JournalJournal of Molecular Structure
    Volume1160
    DOIs
    Publication statusPublished - 15 May 2018

    Keywords

    • Antimony
    • Halide complexes
    • Thermogravimetry
    • X-ray diffractometry

    ASJC Scopus subject areas

    • Analytical Chemistry
    • Spectroscopy
    • Organic Chemistry
    • Inorganic Chemistry

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    Adonin, S. A., Bondarenko, M. A., Samsonenko, D. G., Semitut, E. Y., Sokolov, M. N., & Fedin, V. P. (2018). Mononuclear bromide complexes of Sb(V): crystal structures and thermal behaviour. Journal of Molecular Structure, 1160, 102-106. https://doi.org/10.1016/j.molstruc.2018.01.092