Mononuclear bromide complexes of Sb(V)

crystal structures and thermal behaviour

Sergey A. Adonin, Mikhail A. Bondarenko, Denis G. Samsonenko, Evgeniy Yu Semitut, Maxim N. Sokolov, Vladimir P. Fedin

    Research output: Contribution to journalArticle

    3 Citations (Scopus)

    Abstract

    Reactions of Sb2O3 dissolved in HBr/Br2 and bromides of pyridinium-derived cations result in mononuclear complexes of Sb(V) – (cation)[SbBr6] (cation = 2-chloropyridinium (1), 2-bromopyridinium (2)). Thermal behaviour of 1 and 2, as well as similar previously reported complexes Et4N [SbBr6] (3) and (N-EtPy)[SbBr6] (4), was studied and discussed.

    Original languageEnglish
    Pages (from-to)102-106
    Number of pages5
    JournalJournal of Molecular Structure
    Volume1160
    DOIs
    Publication statusPublished - 15 May 2018

    Fingerprint

    Bromides
    Cations
    Crystal structure
    Hot Temperature

    Keywords

    • Antimony
    • Halide complexes
    • Thermogravimetry
    • X-ray diffractometry

    ASJC Scopus subject areas

    • Analytical Chemistry
    • Spectroscopy
    • Organic Chemistry
    • Inorganic Chemistry

    Cite this

    Adonin, S. A., Bondarenko, M. A., Samsonenko, D. G., Semitut, E. Y., Sokolov, M. N., & Fedin, V. P. (2018). Mononuclear bromide complexes of Sb(V): crystal structures and thermal behaviour. Journal of Molecular Structure, 1160, 102-106. https://doi.org/10.1016/j.molstruc.2018.01.092

    Mononuclear bromide complexes of Sb(V) : crystal structures and thermal behaviour. / Adonin, Sergey A.; Bondarenko, Mikhail A.; Samsonenko, Denis G.; Semitut, Evgeniy Yu; Sokolov, Maxim N.; Fedin, Vladimir P.

    In: Journal of Molecular Structure, Vol. 1160, 15.05.2018, p. 102-106.

    Research output: Contribution to journalArticle

    Adonin, SA, Bondarenko, MA, Samsonenko, DG, Semitut, EY, Sokolov, MN & Fedin, VP 2018, 'Mononuclear bromide complexes of Sb(V): crystal structures and thermal behaviour', Journal of Molecular Structure, vol. 1160, pp. 102-106. https://doi.org/10.1016/j.molstruc.2018.01.092
    Adonin SA, Bondarenko MA, Samsonenko DG, Semitut EY, Sokolov MN, Fedin VP. Mononuclear bromide complexes of Sb(V): crystal structures and thermal behaviour. Journal of Molecular Structure. 2018 May 15;1160:102-106. https://doi.org/10.1016/j.molstruc.2018.01.092
    Adonin, Sergey A. ; Bondarenko, Mikhail A. ; Samsonenko, Denis G. ; Semitut, Evgeniy Yu ; Sokolov, Maxim N. ; Fedin, Vladimir P. / Mononuclear bromide complexes of Sb(V) : crystal structures and thermal behaviour. In: Journal of Molecular Structure. 2018 ; Vol. 1160. pp. 102-106.
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    abstract = "Reactions of Sb2O3 dissolved in HBr/Br2 and bromides of pyridinium-derived cations result in mononuclear complexes of Sb(V) – (cation)[SbBr6] (cation = 2-chloropyridinium (1), 2-bromopyridinium (2)). Thermal behaviour of 1 and 2, as well as similar previously reported complexes Et4N [SbBr6] (3) and (N-EtPy)[SbBr6] (4), was studied and discussed.",
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    AU - Adonin, Sergey A.

    AU - Bondarenko, Mikhail A.

    AU - Samsonenko, Denis G.

    AU - Semitut, Evgeniy Yu

    AU - Sokolov, Maxim N.

    AU - Fedin, Vladimir P.

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    KW - Antimony

    KW - Halide complexes

    KW - Thermogravimetry

    KW - X-ray diffractometry

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