Molecular structure of paramagnetic bis-diisobutyl dithiophosphinate complexes of lanthanides(III) with 1,10-phenanthroline in solution by the data of NMR relaxation spectroscopy

S. P. Babailov, V. L. Varand

Research output: Contribution to journal › Article

Abstract

NMR relaxation spectroscopy (RS) is used to examine the molecular structure of paramagnetic bis-diisobutyl dithiophosphinate complexes of lanthanides (by the example of europium and lutetium) with 1,10-phenanthroline in CDCl ₃ solution. The results obtained are consistent with the results of studying the molecular structure of bis-diisobutyl dithiophosphinate complexes of yttrium with 1,10-phenanthroline in the crystalline phase by XRD.

Original language	English
Pages (from-to)	348-350
Number of pages	3
Journal	Journal of Structural Chemistry
Volume	50
Issue number	2
DOIs	https://doi.org/10.1007/s10947-009-0048-5
Publication status	Published - Apr 2009
Externally published	Yes

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Keywords

Lanthanide-induced shifts
Lanthanides
Molecular structure
NMR relaxation spectroscopy
Nuclear magnetic resonance (NMR)
Paramagnetic complexes of lanthanides
Paramagnetic lanthanide-induced enhancement of spin-lattice relaxation rates

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Chemistry

Cite this

Babailov, S. P., & Varand, V. L. (2009). Molecular structure of paramagnetic bis-diisobutyl dithiophosphinate complexes of lanthanides(III) with 1,10-phenanthroline in solution by the data of NMR relaxation spectroscopy. Journal of Structural Chemistry, 50(2), 348-350. https://doi.org/10.1007/s10947-009-0048-5

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abstract = "NMR relaxation spectroscopy (RS) is used to examine the molecular structure of paramagnetic bis-diisobutyl dithiophosphinate complexes of lanthanides (by the example of europium and lutetium) with 1,10-phenanthroline in CDCl 3 solution. The results obtained are consistent with the results of studying the molecular structure of bis-diisobutyl dithiophosphinate complexes of yttrium with 1,10-phenanthroline in the crystalline phase by XRD.",

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KW - NMR relaxation spectroscopy

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KW - Paramagnetic lanthanide-induced enhancement of spin-lattice relaxation rates

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10.1007/s10947-009-0048-5