Molecular structure of paramagnetic bis-diisobutyl dithiophosphinate complexes of lanthanides(III) with 1,10-phenanthroline in solution by the data of NMR relaxation spectroscopy

Abstract

NMR relaxation spectroscopy (RS) is used to examine the molecular structure of paramagnetic bis-diisobutyl dithiophosphinate complexes of lanthanides (by the example of europium and lutetium) with 1,10-phenanthroline in CDCl ₃ solution. The results obtained are consistent with the results of studying the molecular structure of bis-diisobutyl dithiophosphinate complexes of yttrium with 1,10-phenanthroline in the crystalline phase by XRD.

Original language	English
Pages (from-to)	348-350
Number of pages	3
Journal	Journal of Structural Chemistry
Volume	50
Issue number	2
DOIs	https://doi.org/10.1007/s10947-009-0048-5
Publication status	Published - Apr 2009
Externally published	Yes

Keywords

Lanthanide-induced shifts
Lanthanides
Molecular structure
NMR relaxation spectroscopy
Nuclear magnetic resonance (NMR)
Paramagnetic complexes of lanthanides
Paramagnetic lanthanide-induced enhancement of spin-lattice relaxation rates

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Chemistry

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10.1007/s10947-009-0048-5

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@article{015246c9190443ac9d252b1c5b781c3d,

title = "Molecular structure of paramagnetic bis-diisobutyl dithiophosphinate complexes of lanthanides(III) with 1,10-phenanthroline in solution by the data of NMR relaxation spectroscopy",

abstract = "NMR relaxation spectroscopy (RS) is used to examine the molecular structure of paramagnetic bis-diisobutyl dithiophosphinate complexes of lanthanides (by the example of europium and lutetium) with 1,10-phenanthroline in CDCl 3 solution. The results obtained are consistent with the results of studying the molecular structure of bis-diisobutyl dithiophosphinate complexes of yttrium with 1,10-phenanthroline in the crystalline phase by XRD.",

keywords = "Lanthanide-induced shifts, Lanthanides, Molecular structure, NMR relaxation spectroscopy, Nuclear magnetic resonance (NMR), Paramagnetic complexes of lanthanides, Paramagnetic lanthanide-induced enhancement of spin-lattice relaxation rates",

author = "Babailov, {S. P.} and Varand, {V. L.}",

year = "2009",

month = apr,

doi = "10.1007/s10947-009-0048-5",

language = "English",

volume = "50",

pages = "348--350",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "2",

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TY - JOUR

T1 - Molecular structure of paramagnetic bis-diisobutyl dithiophosphinate complexes of lanthanides(III) with 1,10-phenanthroline in solution by the data of NMR relaxation spectroscopy

AU - Babailov, S. P.

AU - Varand, V. L.

PY - 2009/4

Y1 - 2009/4

N2 - NMR relaxation spectroscopy (RS) is used to examine the molecular structure of paramagnetic bis-diisobutyl dithiophosphinate complexes of lanthanides (by the example of europium and lutetium) with 1,10-phenanthroline in CDCl 3 solution. The results obtained are consistent with the results of studying the molecular structure of bis-diisobutyl dithiophosphinate complexes of yttrium with 1,10-phenanthroline in the crystalline phase by XRD.

AB - NMR relaxation spectroscopy (RS) is used to examine the molecular structure of paramagnetic bis-diisobutyl dithiophosphinate complexes of lanthanides (by the example of europium and lutetium) with 1,10-phenanthroline in CDCl 3 solution. The results obtained are consistent with the results of studying the molecular structure of bis-diisobutyl dithiophosphinate complexes of yttrium with 1,10-phenanthroline in the crystalline phase by XRD.

KW - Lanthanide-induced shifts

KW - Lanthanides

KW - Molecular structure

KW - NMR relaxation spectroscopy

KW - Nuclear magnetic resonance (NMR)

KW - Paramagnetic complexes of lanthanides

KW - Paramagnetic lanthanide-induced enhancement of spin-lattice relaxation rates

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U2 - 10.1007/s10947-009-0048-5

DO - 10.1007/s10947-009-0048-5

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JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

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