Molecular structure of paramagnetic bis-diisobutyl dithiophosphinate complexes of lanthanides(III) with 1,10-phenanthroline in solution by the data of NMR relaxation spectroscopy

S. P. Babailov, V. L. Varand

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

NMR relaxation spectroscopy (RS) is used to examine the molecular structure of paramagnetic bis-diisobutyl dithiophosphinate complexes of lanthanides (by the example of europium and lutetium) with 1,10-phenanthroline in CDCl 3 solution. The results obtained are consistent with the results of studying the molecular structure of bis-diisobutyl dithiophosphinate complexes of yttrium with 1,10-phenanthroline in the crystalline phase by XRD.

Original languageEnglish
Pages (from-to)348-350
Number of pages3
JournalJournal of Structural Chemistry
Volume50
Issue number2
DOIs
Publication statusPublished - Apr 2009
Externally publishedYes

Fingerprint

Lanthanoid Series Elements
Rare earth elements
Molecular structure
molecular structure
Lutetium
Nuclear magnetic resonance
Spectroscopy
Europium
Yttrium
lutetium
nuclear magnetic resonance
europium
yttrium
spectroscopy
Crystalline materials
1,10-phenanthroline

Keywords

  • Lanthanide-induced shifts
  • Lanthanides
  • Molecular structure
  • NMR relaxation spectroscopy
  • Nuclear magnetic resonance (NMR)
  • Paramagnetic complexes of lanthanides
  • Paramagnetic lanthanide-induced enhancement of spin-lattice relaxation rates

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

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abstract = "NMR relaxation spectroscopy (RS) is used to examine the molecular structure of paramagnetic bis-diisobutyl dithiophosphinate complexes of lanthanides (by the example of europium and lutetium) with 1,10-phenanthroline in CDCl 3 solution. The results obtained are consistent with the results of studying the molecular structure of bis-diisobutyl dithiophosphinate complexes of yttrium with 1,10-phenanthroline in the crystalline phase by XRD.",
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T1 - Molecular structure of paramagnetic bis-diisobutyl dithiophosphinate complexes of lanthanides(III) with 1,10-phenanthroline in solution by the data of NMR relaxation spectroscopy

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AU - Varand, V. L.

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KW - Paramagnetic lanthanide-induced enhancement of spin-lattice relaxation rates

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