Abstract
NMR relaxation spectroscopy (RS) is used to examine the molecular structure of paramagnetic bis-diisobutyl dithiophosphinate complexes of lanthanides (by the example of europium and lutetium) with 1,10-phenanthroline in CDCl 3 solution. The results obtained are consistent with the results of studying the molecular structure of bis-diisobutyl dithiophosphinate complexes of yttrium with 1,10-phenanthroline in the crystalline phase by XRD.
| Original language | English |
|---|---|
| Pages (from-to) | 348-350 |
| Number of pages | 3 |
| Journal | Journal of Structural Chemistry |
| Volume | 50 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - Apr 2009 |
| Externally published | Yes |
Keywords
- Lanthanide-induced shifts
- Lanthanides
- Molecular structure
- NMR relaxation spectroscopy
- Nuclear magnetic resonance (NMR)
- Paramagnetic complexes of lanthanides
- Paramagnetic lanthanide-induced enhancement of spin-lattice relaxation rates
ASJC Scopus subject areas
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
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Cite this
Babailov, S. P., & Varand, V. L. (2009). Molecular structure of paramagnetic bis-diisobutyl dithiophosphinate complexes of lanthanides(III) with 1,10-phenanthroline in solution by the data of NMR relaxation spectroscopy. Journal of Structural Chemistry, 50(2), 348-350. https://doi.org/10.1007/s10947-009-0048-5