Molecular structure and paramagnetic properties of Tris-diisobutyl- dithiophosphinate complexes of europium(III) with 2,2′-Bipyridyl in solution using NMR

Sergey P. Babailov, Anna V. Goryunova, Andrey V. Dudnikov

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Tris-diisobutyl-dithiophosphinate complexes of europium(III) with 2,2′-Bipyridyl are of great interest as promising luminescent sensors for biology and medicine. 1H and 13C NMR measurements are reported for the CDCl 3 solution of [Eu(2,2′-Bipy)(i-DBDTPh) 3] complex. The analysis of the structural parameters found by relaxation spectroscopy NMR testifies that the bipyridyl and i-DBDTPh anions are in the first coordination sphere of a Ln cation. The found experimental results indicate that the structure of these complexes in solution is similar to that one in the solid state (known from the X-ray crystal structure data). Paramagnetic complex investigated in the paper represents the new type of thermometric NMR sensors and lanthanide paramagnetic probes for in situ temperature control in solution.

Original languageEnglish
Pages (from-to)107-109
Number of pages3
JournalJournal of Molecular Structure
Volume1028
DOIs
Publication statusPublished - 28 Nov 2012
Externally publishedYes

Fingerprint

Europium
2,2'-Dipyridyl
Molecular structure
Nuclear magnetic resonance
Lanthanoid Series Elements
Sensors
Temperature control
Nuclear magnetic resonance spectroscopy
Medicine
Anions
Cations
Crystal structure
X rays

Keywords

  • Lanthanide-induced shifts
  • Lanthanides
  • Luminescent sensors
  • Magnetic resonance thermometric sensors
  • Paramagnetic lanthanide complexes
  • Relaxation spectroscopy of NMR

ASJC Scopus subject areas

  • Spectroscopy
  • Analytical Chemistry
  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Molecular structure and paramagnetic properties of Tris-diisobutyl- dithiophosphinate complexes of europium(III) with 2,2′-Bipyridyl in solution using NMR. / Babailov, Sergey P.; Goryunova, Anna V.; Dudnikov, Andrey V.

In: Journal of Molecular Structure, Vol. 1028, 28.11.2012, p. 107-109.

Research output: Contribution to journalArticle

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abstract = "Tris-diisobutyl-dithiophosphinate complexes of europium(III) with 2,2′-Bipyridyl are of great interest as promising luminescent sensors for biology and medicine. 1H and 13C NMR measurements are reported for the CDCl 3 solution of [Eu(2,2′-Bipy)(i-DBDTPh) 3] complex. The analysis of the structural parameters found by relaxation spectroscopy NMR testifies that the bipyridyl and i-DBDTPh anions are in the first coordination sphere of a Ln cation. The found experimental results indicate that the structure of these complexes in solution is similar to that one in the solid state (known from the X-ray crystal structure data). Paramagnetic complex investigated in the paper represents the new type of thermometric NMR sensors and lanthanide paramagnetic probes for in situ temperature control in solution.",
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