Modeling of the kinetic experiment of dicyclopentadiene olygomerization

Alexey Lyapkov, Vladimir Bondaletov, Elena Melnik, Georgy Borisov

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

Regularities of the dicyclopentadiene cationic oligomerization under influence of the catalytic system AlEt2Cl: TiCl4 in toluene solution were studied. The most probable mechanism of polymerization in this system is the propagation chain on the contact or solvate -separated ion pairs. The effective rate constant of solvation of the catalyst and chain propagation were calculated. The thermal oligomerization effect and heat of the catalyst system components solvation are determined by heat of oligomerization raw material containing dicyclopentadiene. When taking into account the data of both material and thermal balance the experimental data were described adequately.

Original languageEnglish
Title of host publicationAdvanced Materials Research
Pages205-211
Number of pages7
Volume880
DOIs
Publication statusPublished - 2014
Event10th International Conference on Prospects of Fundamental Sciences Development, PFSD-2013 - Tomsk, Russian Federation
Duration: 23 Apr 201326 Apr 2013

Publication series

NameAdvanced Materials Research
Volume880
ISSN (Print)10226680

Other

Other10th International Conference on Prospects of Fundamental Sciences Development, PFSD-2013
CountryRussian Federation
CityTomsk
Period23.4.1326.4.13

Keywords

  • Cationic olygomerization
  • Dicyclopentadiene
  • Diethyl aluminum chloride
  • Inverse kinetic problem
  • Rate constants
  • Titanium tetrachloride
  • Toluene

ASJC Scopus subject areas

  • Engineering(all)

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  • Cite this

    Lyapkov, A., Bondaletov, V., Melnik, E., & Borisov, G. (2014). Modeling of the kinetic experiment of dicyclopentadiene olygomerization. In Advanced Materials Research (Vol. 880, pp. 205-211). (Advanced Materials Research; Vol. 880). https://doi.org/10.4028/www.scientific.net/AMR.880.205