Abstract
Regularities of the dicyclopentadiene cationic oligomerization under influence of the catalytic system AlEt2Cl: TiCl4 in toluene solution were studied. The most probable mechanism of polymerization in this system is the propagation chain on the contact or solvate -separated ion pairs. The effective rate constant of solvation of the catalyst and chain propagation were calculated. The thermal oligomerization effect and heat of the catalyst system components solvation are determined by heat of oligomerization raw material containing dicyclopentadiene. When taking into account the data of both material and thermal balance the experimental data were described adequately.
| Original language | English |
|---|---|
| Title of host publication | Advanced Materials Research |
| Pages | 205-211 |
| Number of pages | 7 |
| Volume | 880 |
| DOIs | |
| Publication status | Published - 2014 |
| Event | 10th International Conference on Prospects of Fundamental Sciences Development, PFSD-2013 - Tomsk, Russian Federation Duration: 23 Apr 2013 → 26 Apr 2013 |
Publication series
| Name | Advanced Materials Research |
|---|---|
| Volume | 880 |
| ISSN (Print) | 10226680 |
Other
| Other | 10th International Conference on Prospects of Fundamental Sciences Development, PFSD-2013 |
|---|---|
| Country | Russian Federation |
| City | Tomsk |
| Period | 23.4.13 → 26.4.13 |
Fingerprint
Keywords
- Cationic olygomerization
- Dicyclopentadiene
- Diethyl aluminum chloride
- Inverse kinetic problem
- Rate constants
- Titanium tetrachloride
- Toluene
ASJC Scopus subject areas
- Engineering(all)
Cite this
Modeling of the kinetic experiment of dicyclopentadiene olygomerization. / Lyapkov, Alexey; Bondaletov, Vladimir; Melnik, Elena; Borisov, Georgy.
Advanced Materials Research. Vol. 880 2014. p. 205-211 (Advanced Materials Research; Vol. 880).Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Modeling of the kinetic experiment of dicyclopentadiene olygomerization
AU - Lyapkov, Alexey
AU - Bondaletov, Vladimir
AU - Melnik, Elena
AU - Borisov, Georgy
PY - 2014
Y1 - 2014
N2 - Regularities of the dicyclopentadiene cationic oligomerization under influence of the catalytic system AlEt2Cl: TiCl4 in toluene solution were studied. The most probable mechanism of polymerization in this system is the propagation chain on the contact or solvate -separated ion pairs. The effective rate constant of solvation of the catalyst and chain propagation were calculated. The thermal oligomerization effect and heat of the catalyst system components solvation are determined by heat of oligomerization raw material containing dicyclopentadiene. When taking into account the data of both material and thermal balance the experimental data were described adequately.
AB - Regularities of the dicyclopentadiene cationic oligomerization under influence of the catalytic system AlEt2Cl: TiCl4 in toluene solution were studied. The most probable mechanism of polymerization in this system is the propagation chain on the contact or solvate -separated ion pairs. The effective rate constant of solvation of the catalyst and chain propagation were calculated. The thermal oligomerization effect and heat of the catalyst system components solvation are determined by heat of oligomerization raw material containing dicyclopentadiene. When taking into account the data of both material and thermal balance the experimental data were described adequately.
KW - Cationic olygomerization
KW - Dicyclopentadiene
KW - Diethyl aluminum chloride
KW - Inverse kinetic problem
KW - Rate constants
KW - Titanium tetrachloride
KW - Toluene
UR - http://www.scopus.com/inward/record.url?scp=84893936356&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84893936356&partnerID=8YFLogxK
U2 - 10.4028/www.scientific.net/AMR.880.205
DO - 10.4028/www.scientific.net/AMR.880.205
M3 - Conference contribution
AN - SCOPUS:84893936356
SN - 9783038350040
VL - 880
T3 - Advanced Materials Research
SP - 205
EP - 211
BT - Advanced Materials Research
ER -