Modeling of the kinetic experiment of dicyclopentadiene olygomerization

Alexey Lyapkov, Vladimir Bondaletov, Elena Melnik, Georgy Borisov

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

Regularities of the dicyclopentadiene cationic oligomerization under influence of the catalytic system AlEt₂Cl: TiCl₄ in toluene solution were studied. The most probable mechanism of polymerization in this system is the propagation chain on the contact or solvate -separated ion pairs. The effective rate constant of solvation of the catalyst and chain propagation were calculated. The thermal oligomerization effect and heat of the catalyst system components solvation are determined by heat of oligomerization raw material containing dicyclopentadiene. When taking into account the data of both material and thermal balance the experimental data were described adequately.

Original language	English
Title of host publication	Advanced Materials Research
Pages	205-211
Number of pages	7
Volume	880
DOIs	https://doi.org/10.4028/www.scientific.net/AMR.880.205
Publication status	Published - 2014
Event	10th International Conference on Prospects of Fundamental Sciences Development, PFSD-2013 - Tomsk, Russian Federation Duration: 23 Apr 2013 → 26 Apr 2013

Publication series

Name	Advanced Materials Research
Volume	880
ISSN (Print)	10226680

Other

Other	10th International Conference on Prospects of Fundamental Sciences Development, PFSD-2013
Country	Russian Federation
City	Tomsk
Period	23.4.13 → 26.4.13

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Keywords

Cationic olygomerization
Dicyclopentadiene
Diethyl aluminum chloride
Inverse kinetic problem
Rate constants
Titanium tetrachloride
Toluene

ASJC Scopus subject areas

Engineering(all)

Cite this

Lyapkov, A., Bondaletov, V., Melnik, E., & Borisov, G. (2014). Modeling of the kinetic experiment of dicyclopentadiene olygomerization. In Advanced Materials Research (Vol. 880, pp. 205-211). (Advanced Materials Research; Vol. 880). https://doi.org/10.4028/www.scientific.net/AMR.880.205

Lyapkov, A , Bondaletov, V, Melnik, E & Borisov, G 2014, Modeling of the kinetic experiment of dicyclopentadiene olygomerization. in Advanced Materials Research. vol. 880, Advanced Materials Research, vol. 880, pp. 205-211, 10th International Conference on Prospects of Fundamental Sciences Development, PFSD-2013, Tomsk, Russian Federation, 23.4.13. https://doi.org/10.4028/www.scientific.net/AMR.880.205

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title = "Modeling of the kinetic experiment of dicyclopentadiene olygomerization",

abstract = "Regularities of the dicyclopentadiene cationic oligomerization under influence of the catalytic system AlEt2Cl: TiCl4 in toluene solution were studied. The most probable mechanism of polymerization in this system is the propagation chain on the contact or solvate -separated ion pairs. The effective rate constant of solvation of the catalyst and chain propagation were calculated. The thermal oligomerization effect and heat of the catalyst system components solvation are determined by heat of oligomerization raw material containing dicyclopentadiene. When taking into account the data of both material and thermal balance the experimental data were described adequately.",

keywords = "Cationic olygomerization, Dicyclopentadiene, Diethyl aluminum chloride, Inverse kinetic problem, Rate constants, Titanium tetrachloride, Toluene",

author = "Alexey Lyapkov and Vladimir Bondaletov and Elena Melnik and Georgy Borisov",

year = "2014",

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AU - Lyapkov, Alexey

AU - Bondaletov, Vladimir

AU - Melnik, Elena

AU - Borisov, Georgy

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N2 - Regularities of the dicyclopentadiene cationic oligomerization under influence of the catalytic system AlEt2Cl: TiCl4 in toluene solution were studied. The most probable mechanism of polymerization in this system is the propagation chain on the contact or solvate -separated ion pairs. The effective rate constant of solvation of the catalyst and chain propagation were calculated. The thermal oligomerization effect and heat of the catalyst system components solvation are determined by heat of oligomerization raw material containing dicyclopentadiene. When taking into account the data of both material and thermal balance the experimental data were described adequately.

AB - Regularities of the dicyclopentadiene cationic oligomerization under influence of the catalytic system AlEt2Cl: TiCl4 in toluene solution were studied. The most probable mechanism of polymerization in this system is the propagation chain on the contact or solvate -separated ion pairs. The effective rate constant of solvation of the catalyst and chain propagation were calculated. The thermal oligomerization effect and heat of the catalyst system components solvation are determined by heat of oligomerization raw material containing dicyclopentadiene. When taking into account the data of both material and thermal balance the experimental data were described adequately.

KW - Cationic olygomerization

KW - Dicyclopentadiene

KW - Diethyl aluminum chloride

KW - Inverse kinetic problem

KW - Rate constants

KW - Titanium tetrachloride

KW - Toluene

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Access to Document

10.4028/www.scientific.net/AMR.880.205