Modeling of oligomerization of C<sub>9</sub> fraction of petrol pyrolysis

Abstract

Process of terpolymerization of basic unsaturated components of liquid products of pyrolysis of straight-run gasoline in toluene solution has been studied as model of oligomerization of C₉ fraction under the action of catalytic system TiCl₄-Al(C₂H₅)₂Cl. Relative reactivity of styrene, indene and dicyclopentadiene(80-85 % from total amount of monomers)was established. On the basis of data of adiabatic thermometry, IR and ¹H NMR spectroscopy we revealed possibilityto synthesize polymeric and oligomeric products.These products basically correspondto the industrial petropolymericresinsobtained from C₉ fraction.

Original language	English
Title of host publication	Advanced Materials Research
Pages	292-296
Number of pages	5
Volume	772
DOIs	https://doi.org/10.4028/www.scientific.net/AMR.772.292
Publication status	Published - 2013
Event	2013 International Conference on Future Energy and Materials Research, FEMR 2013 - , Singapore Duration: 1 Jun 2013 → 2 Jun 2013

Publication series

Name	Advanced Materials Research
Volume	772
ISSN (Print)	10226680

Other

Other	2013 International Conference on Future Energy and Materials Research, FEMR 2013
Country	Singapore
Period	1.6.13 → 2.6.13

Keywords

Catalytic oligomerization
Dicyclopentadiene
Indene
Liquid products of pyrolysis
Petropolymeric resins
Styrene

ASJC Scopus subject areas

Engineering(all)

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Lyapkov, AA, Ionova, EI, Bondaletov, VG & Pestryakov, AN 2013, Modeling of oligomerization of C₉ fraction of petrol pyrolysis. in Advanced Materials Research. vol. 772, Advanced Materials Research, vol. 772, pp. 292-296, 2013 International Conference on Future Energy and Materials Research, FEMR 2013, Singapore, 1.6.13. https://doi.org/10.4028/www.scientific.net/AMR.772.292

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abstract = "Process of terpolymerization of basic unsaturated components of liquid products of pyrolysis of straight-run gasoline in toluene solution has been studied as model of oligomerization of C9 fraction under the action of catalytic system TiCl4-Al(C2H5)2Cl. Relative reactivity of styrene, indene and dicyclopentadiene(80-85 % from total amount of monomers)was established. On the basis of data of adiabatic thermometry, IR and 1H NMR spectroscopy we revealed possibilityto synthesize polymeric and oligomeric products.These products basically correspondto the industrial petropolymericresinsobtained from C9 fraction.",

keywords = "Catalytic oligomerization, Dicyclopentadiene, Indene, Liquid products of pyrolysis, Petropolymeric resins, Styrene",

author = "Lyapkov, {A. A.} and Ionova, {E. I.} and Bondaletov, {V. G.} and Pestryakov, {A. N.}",

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AU - Ionova, E. I.

AU - Bondaletov, V. G.

AU - Pestryakov, A. N.

PY - 2013

Y1 - 2013

N2 - Process of terpolymerization of basic unsaturated components of liquid products of pyrolysis of straight-run gasoline in toluene solution has been studied as model of oligomerization of C9 fraction under the action of catalytic system TiCl4-Al(C2H5)2Cl. Relative reactivity of styrene, indene and dicyclopentadiene(80-85 % from total amount of monomers)was established. On the basis of data of adiabatic thermometry, IR and 1H NMR spectroscopy we revealed possibilityto synthesize polymeric and oligomeric products.These products basically correspondto the industrial petropolymericresinsobtained from C9 fraction.

AB - Process of terpolymerization of basic unsaturated components of liquid products of pyrolysis of straight-run gasoline in toluene solution has been studied as model of oligomerization of C9 fraction under the action of catalytic system TiCl4-Al(C2H5)2Cl. Relative reactivity of styrene, indene and dicyclopentadiene(80-85 % from total amount of monomers)was established. On the basis of data of adiabatic thermometry, IR and 1H NMR spectroscopy we revealed possibilityto synthesize polymeric and oligomeric products.These products basically correspondto the industrial petropolymericresinsobtained from C9 fraction.

KW - Catalytic oligomerization

KW - Dicyclopentadiene

KW - Indene

KW - Liquid products of pyrolysis

KW - Petropolymeric resins

KW - Styrene

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Modeling of oligomerization of C9 fraction of petrol pyrolysis