Abstract
Process of terpolymerization of basic unsaturated components of liquid products of pyrolysis of straight-run gasoline in toluene solution has been studied as model of oligomerization of C9 fraction under the action of catalytic system TiCl4-Al(C2H5)2Cl. Relative reactivity of styrene, indene and dicyclopentadiene(80-85 % from total amount of monomers)was established. On the basis of data of adiabatic thermometry, IR and 1H NMR spectroscopy we revealed possibilityto synthesize polymeric and oligomeric products.These products basically correspondto the industrial petropolymericresinsobtained from C9 fraction.
| Original language | English |
|---|---|
| Title of host publication | Advanced Materials Research |
| Pages | 292-296 |
| Number of pages | 5 |
| Volume | 772 |
| DOIs | |
| Publication status | Published - 2013 |
| Event | 2013 International Conference on Future Energy and Materials Research, FEMR 2013 - , Singapore Duration: 1 Jun 2013 → 2 Jun 2013 |
Publication series
| Name | Advanced Materials Research |
|---|---|
| Volume | 772 |
| ISSN (Print) | 10226680 |
Other
| Other | 2013 International Conference on Future Energy and Materials Research, FEMR 2013 |
|---|---|
| Country | Singapore |
| Period | 1.6.13 → 2.6.13 |
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Keywords
- Catalytic oligomerization
- Dicyclopentadiene
- Indene
- Liquid products of pyrolysis
- Petropolymeric resins
- Styrene
ASJC Scopus subject areas
- Engineering(all)
Cite this
Modeling of oligomerization of C9 fraction of petrol pyrolysis. / Lyapkov, A. A.; Ionova, E. I.; Bondaletov, V. G.; Pestryakov, A. N.
Advanced Materials Research. Vol. 772 2013. p. 292-296 (Advanced Materials Research; Vol. 772).Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Modeling of oligomerization of C9 fraction of petrol pyrolysis
AU - Lyapkov, A. A.
AU - Ionova, E. I.
AU - Bondaletov, V. G.
AU - Pestryakov, A. N.
PY - 2013
Y1 - 2013
N2 - Process of terpolymerization of basic unsaturated components of liquid products of pyrolysis of straight-run gasoline in toluene solution has been studied as model of oligomerization of C9 fraction under the action of catalytic system TiCl4-Al(C2H5)2Cl. Relative reactivity of styrene, indene and dicyclopentadiene(80-85 % from total amount of monomers)was established. On the basis of data of adiabatic thermometry, IR and 1H NMR spectroscopy we revealed possibilityto synthesize polymeric and oligomeric products.These products basically correspondto the industrial petropolymericresinsobtained from C9 fraction.
AB - Process of terpolymerization of basic unsaturated components of liquid products of pyrolysis of straight-run gasoline in toluene solution has been studied as model of oligomerization of C9 fraction under the action of catalytic system TiCl4-Al(C2H5)2Cl. Relative reactivity of styrene, indene and dicyclopentadiene(80-85 % from total amount of monomers)was established. On the basis of data of adiabatic thermometry, IR and 1H NMR spectroscopy we revealed possibilityto synthesize polymeric and oligomeric products.These products basically correspondto the industrial petropolymericresinsobtained from C9 fraction.
KW - Catalytic oligomerization
KW - Dicyclopentadiene
KW - Indene
KW - Liquid products of pyrolysis
KW - Petropolymeric resins
KW - Styrene
UR - http://www.scopus.com/inward/record.url?scp=84884955598&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84884955598&partnerID=8YFLogxK
U2 - 10.4028/www.scientific.net/AMR.772.292
DO - 10.4028/www.scientific.net/AMR.772.292
M3 - Conference contribution
AN - SCOPUS:84884955598
SN - 9783037857892
VL - 772
T3 - Advanced Materials Research
SP - 292
EP - 296
BT - Advanced Materials Research
ER -