Modeling of oligomerization of C9 fraction of petrol pyrolysis

A. A. Lyapkov, E. I. Ionova, V. G. Bondaletov, A. N. Pestryakov

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

Process of terpolymerization of basic unsaturated components of liquid products of pyrolysis of straight-run gasoline in toluene solution has been studied as model of oligomerization of C9 fraction under the action of catalytic system TiCl4-Al(C2H5)2Cl. Relative reactivity of styrene, indene and dicyclopentadiene(80-85 % from total amount of monomers)was established. On the basis of data of adiabatic thermometry, IR and 1H NMR spectroscopy we revealed possibilityto synthesize polymeric and oligomeric products.These products basically correspondto the industrial petropolymericresinsobtained from C9 fraction.

Original languageEnglish
Title of host publicationAdvanced Materials Research
Pages292-296
Number of pages5
Volume772
DOIs
Publication statusPublished - 2013
Event2013 International Conference on Future Energy and Materials Research, FEMR 2013 - , Singapore
Duration: 1 Jun 2013 → 2 Jun 2013

Publication series

NameAdvanced Materials Research
Volume772
ISSN (Print)10226680

Other

Other2013 International Conference on Future Energy and Materials Research, FEMR 2013
CountrySingapore
Period1.6.13 → 2.6.13

Keywords

  • Catalytic oligomerization
  • Dicyclopentadiene
  • Indene
  • Liquid products of pyrolysis
  • Petropolymeric resins
  • Styrene

ASJC Scopus subject areas

  • Engineering(all)

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