Model of autowave propagation of solid-state low-temperature chlorination of butyl chloride

R&D Laboratory for Modeling of Technological Processes

Research output: Contribution to journal › Article

Abstract

A mathematical model of autowave propagation of solid-state low-temperature chlorination of butyl chloride is proposed. The model is of a coupled character and includes nonlinear equations of thermal conductivity and chemical kinetics and a balance equation for defectiveness of the medium with corresponding boundary conditions. The eigenvalues and eigenfunctions of the problem are found by a numerical method. The inverse problem is solved, and possible magnitudes of the heat effects of the chemical reactions and fracture are determined. The calculation results are in qualitative agreement with the experimental data.

Original language	English
Pages (from-to)	556-565
Number of pages	10
Journal	Combustion, Explosion and Shock Waves
Volume	34
Issue number	5
DOIs	https://doi.org/10.1007/BF02672679
Publication status	Published - 1 Jan 1998

Fingerprint

chlorination

Chlorination

Inverse problems

Nonlinear equations

Eigenvalues and eigenfunctions

Reaction kinetics

Thermal effects

nonlinear equations

temperature effects

Chemical reactions

Thermal conductivity

Numerical methods

mathematical models

chemical reactions

eigenvectors

reaction kinetics

eigenvalues

thermal conductivity

chlorides

Boundary conditions

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Fuel Technology
Energy Engineering and Power Technology
Physics and Astronomy(all)

Cite this

Knyazeva, A. G., & Dyukarev, E. A. (1998). Model of autowave propagation of solid-state low-temperature chlorination of butyl chloride. Combustion, Explosion and Shock Waves, 34(5), 556-565. https://doi.org/10.1007/BF02672679

Model of autowave propagation of solid-state low-temperature chlorination of butyl chloride. / Knyazeva, A. G.; Dyukarev, E. A.

In: Combustion, Explosion and Shock Waves, Vol. 34, No. 5, 01.01.1998, p. 556-565.

Research output: Contribution to journal › Article

Knyazeva, AG & Dyukarev, EA 1998, 'Model of autowave propagation of solid-state low-temperature chlorination of butyl chloride', Combustion, Explosion and Shock Waves, vol. 34, no. 5, pp. 556-565. https://doi.org/10.1007/BF02672679

Knyazeva AG, Dyukarev EA. Model of autowave propagation of solid-state low-temperature chlorination of butyl chloride. Combustion, Explosion and Shock Waves. 1998 Jan 1;34(5):556-565. https://doi.org/10.1007/BF02672679

Knyazeva, A. G. ; Dyukarev, E. A. / Model of autowave propagation of solid-state low-temperature chlorination of butyl chloride. In: Combustion, Explosion and Shock Waves. 1998 ; Vol. 34, No. 5. pp. 556-565.

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10.1007/BF02672679