Model of autowave propagation of solid-state low-temperature chlorination of butyl chloride

Abstract

A mathematical model of autowave propagation of solid-state low-temperature chlorination of butyl chloride is proposed. The model is of a coupled character and includes nonlinear equations of thermal conductivity and chemical kinetics and a balance equation for defectiveness of the medium with corresponding boundary conditions. The eigenvalues and eigenfunctions of the problem are found by a numerical method. The inverse problem is solved, and possible magnitudes of the heat effects of the chemical reactions and fracture are determined. The calculation results are in qualitative agreement with the experimental data.

Original language	English
Pages (from-to)	556-565
Number of pages	10
Journal	Combustion, Explosion and Shock Waves
Volume	34
Issue number	5
DOIs	https://doi.org/10.1007/BF02672679
Publication status	Published - 1 Jan 1998

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Fuel Technology
Energy Engineering and Power Technology
Physics and Astronomy(all)

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10.1007/BF02672679

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title = "Model of autowave propagation of solid-state low-temperature chlorination of butyl chloride",

abstract = "A mathematical model of autowave propagation of solid-state low-temperature chlorination of butyl chloride is proposed. The model is of a coupled character and includes nonlinear equations of thermal conductivity and chemical kinetics and a balance equation for defectiveness of the medium with corresponding boundary conditions. The eigenvalues and eigenfunctions of the problem are found by a numerical method. The inverse problem is solved, and possible magnitudes of the heat effects of the chemical reactions and fracture are determined. The calculation results are in qualitative agreement with the experimental data.",

author = "Knyazeva, {A. G.} and Dyukarev, {E. A.}",

year = "1998",

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T1 - Model of autowave propagation of solid-state low-temperature chlorination of butyl chloride

AU - Knyazeva, A. G.

AU - Dyukarev, E. A.

PY - 1998/1/1

Y1 - 1998/1/1

N2 - A mathematical model of autowave propagation of solid-state low-temperature chlorination of butyl chloride is proposed. The model is of a coupled character and includes nonlinear equations of thermal conductivity and chemical kinetics and a balance equation for defectiveness of the medium with corresponding boundary conditions. The eigenvalues and eigenfunctions of the problem are found by a numerical method. The inverse problem is solved, and possible magnitudes of the heat effects of the chemical reactions and fracture are determined. The calculation results are in qualitative agreement with the experimental data.

AB - A mathematical model of autowave propagation of solid-state low-temperature chlorination of butyl chloride is proposed. The model is of a coupled character and includes nonlinear equations of thermal conductivity and chemical kinetics and a balance equation for defectiveness of the medium with corresponding boundary conditions. The eigenvalues and eigenfunctions of the problem are found by a numerical method. The inverse problem is solved, and possible magnitudes of the heat effects of the chemical reactions and fracture are determined. The calculation results are in qualitative agreement with the experimental data.

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SN - 0010-5082

IS - 5

ER -

Model of autowave propagation of solid-state low-temperature chlorination of butyl chloride

Abstract

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