Model of autowave propagation of solid-state low-temperature chlorination of butyl chloride

A. G. Knyazeva, E. A. Dyukarev

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

A mathematical model of autowave propagation of solid-state low-temperature chlorination of butyl chloride is proposed. The model is of a coupled character and includes nonlinear equations of thermal conductivity and chemical kinetics and a balance equation for defectiveness of the medium with corresponding boundary conditions. The eigenvalues and eigenfunctions of the problem are found by a numerical method. The inverse problem is solved, and possible magnitudes of the heat effects of the chemical reactions and fracture are determined. The calculation results are in qualitative agreement with the experimental data.

Original languageEnglish
Pages (from-to)556-565
Number of pages10
JournalCombustion, Explosion and Shock Waves
Volume34
Issue number5
DOIs
Publication statusPublished - 1 Jan 1998

Fingerprint

chlorination
Chlorination
Inverse problems
Nonlinear equations
Eigenvalues and eigenfunctions
Reaction kinetics
Thermal effects
nonlinear equations
temperature effects
Chemical reactions
Thermal conductivity
Numerical methods
mathematical models
chemical reactions
eigenvectors
reaction kinetics
eigenvalues
thermal conductivity
chlorides
Boundary conditions

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Physics and Astronomy(all)

Cite this

Model of autowave propagation of solid-state low-temperature chlorination of butyl chloride. / Knyazeva, A. G.; Dyukarev, E. A.

In: Combustion, Explosion and Shock Waves, Vol. 34, No. 5, 01.01.1998, p. 556-565.

Research output: Contribution to journalArticle

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