Mild and efficient synthesis of iodylarenes using Oxone as oxidant

Natalia Soldatova, Pavel Postnikov, Anna A. Troyan, Akira Yoshimura, Mekhman S. Yusubov, Viktor V. Zhdankin

Research output: Contribution to journal › Article › peer-review

Abstract

Mild and efficient method for the preparation of iodylarenes by oxidation of iodoarenes with Oxone in aqueous acetonitrile at room temperature is described. This new procedure allows the preparation of various iodylarenes with electron-donating or electron-withdrawing substituents in the aromatic ring including the previously unknown 1,2-diiodylbenzene.

Original language	English
Pages (from-to)	4254-4256
Number of pages	3
Journal	Tetrahedron Letters
Volume	57
Issue number	37
DOIs	https://doi.org/10.1016/j.tetlet.2016.08.038
Publication status	Published - 14 Sep 2016

Keywords

Hypervalent iodine
Iodine
Iodylarenes
Oxidation
Oxone

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2016.08.038

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title = "Mild and efficient synthesis of iodylarenes using Oxone as oxidant",

abstract = "Mild and efficient method for the preparation of iodylarenes by oxidation of iodoarenes with Oxone in aqueous acetonitrile at room temperature is described. This new procedure allows the preparation of various iodylarenes with electron-donating or electron-withdrawing substituents in the aromatic ring including the previously unknown 1,2-diiodylbenzene.",

keywords = "Hypervalent iodine, Iodine, Iodylarenes, Oxidation, Oxone",

author = "Natalia Soldatova and Pavel Postnikov and Troyan, {Anna A.} and Akira Yoshimura and Yusubov, {Mekhman S.} and Zhdankin, {Viktor V.}",

year = "2016",

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journal = "Tetrahedron Letters",

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T1 - Mild and efficient synthesis of iodylarenes using Oxone as oxidant

AU - Soldatova, Natalia

AU - Postnikov, Pavel

AU - Troyan, Anna A.

AU - Yoshimura, Akira

AU - Yusubov, Mekhman S.

AU - Zhdankin, Viktor V.

PY - 2016/9/14

Y1 - 2016/9/14

N2 - Mild and efficient method for the preparation of iodylarenes by oxidation of iodoarenes with Oxone in aqueous acetonitrile at room temperature is described. This new procedure allows the preparation of various iodylarenes with electron-donating or electron-withdrawing substituents in the aromatic ring including the previously unknown 1,2-diiodylbenzene.

AB - Mild and efficient method for the preparation of iodylarenes by oxidation of iodoarenes with Oxone in aqueous acetonitrile at room temperature is described. This new procedure allows the preparation of various iodylarenes with electron-donating or electron-withdrawing substituents in the aromatic ring including the previously unknown 1,2-diiodylbenzene.

KW - Hypervalent iodine

KW - Iodine

KW - Iodylarenes

KW - Oxidation

KW - Oxone

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U2 - 10.1016/j.tetlet.2016.08.038

DO - 10.1016/j.tetlet.2016.08.038

M3 - Article

AN - SCOPUS:84983071330

VL - 57

SP - 4254

EP - 4256

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 37