Mild and efficient synthesis of iodylarenes using Oxone as oxidant

Natalia Soldatova, Pavel Postnikov, Anna A. Troyan, Akira Yoshimura, Mekhman S. Yusubov, Viktor V. Zhdankin

Research output: Contribution to journal › Article

10 Citations (Scopus)

Abstract

Mild and efficient method for the preparation of iodylarenes by oxidation of iodoarenes with Oxone in aqueous acetonitrile at room temperature is described. This new procedure allows the preparation of various iodylarenes with electron-donating or electron-withdrawing substituents in the aromatic ring including the previously unknown 1,2-diiodylbenzene.

Original languageEnglish
Pages (from-to)4254-4256
Number of pages3
JournalTetrahedron Letters
Volume57
Issue number37
DOIs
Publication statusPublished - 14 Sep 2016

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Oxidants
Electrons
Oxidation
Temperature
potassium peroxymonosulfuric acid
acetonitrile

Keywords

  • Hypervalent iodine
  • Iodine
  • Iodylarenes
  • Oxidation
  • Oxone

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Mild and efficient synthesis of iodylarenes using Oxone as oxidant. / Soldatova, Natalia; Postnikov, Pavel; Troyan, Anna A.; Yoshimura, Akira; Yusubov, Mekhman S.; Zhdankin, Viktor V.

In: Tetrahedron Letters, Vol. 57, No. 37, 14.09.2016, p. 4254-4256.

Research output: Contribution to journal › Article

Soldatova, N, Postnikov, P, Troyan, AA, Yoshimura, A, Yusubov, MS & Zhdankin, VV 2016, 'Mild and efficient synthesis of iodylarenes using Oxone as oxidant', Tetrahedron Letters, vol. 57, no. 37, pp. 4254-4256. https://doi.org/10.1016/j.tetlet.2016.08.038
Soldatova N, Postnikov P, Troyan AA, Yoshimura A, Yusubov MS, Zhdankin VV. Mild and efficient synthesis of iodylarenes using Oxone as oxidant. Tetrahedron Letters. 2016 Sep 14;57(37):4254-4256. https://doi.org/10.1016/j.tetlet.2016.08.038
Soldatova, Natalia ; Postnikov, Pavel ; Troyan, Anna A. ; Yoshimura, Akira ; Yusubov, Mekhman S. ; Zhdankin, Viktor V. / Mild and efficient synthesis of iodylarenes using Oxone as oxidant. In: Tetrahedron Letters. 2016 ; Vol. 57, No. 37. pp. 4254-4256.
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