Mild and efficient synthesis of iodylarenes using Oxone as oxidant

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Abstract

Mild and efficient method for the preparation of iodylarenes by oxidation of iodoarenes with Oxone in aqueous acetonitrile at room temperature is described. This new procedure allows the preparation of various iodylarenes with electron-donating or electron-withdrawing substituents in the aromatic ring including the previously unknown 1,2-diiodylbenzene.

Original languageEnglish
Pages (from-to)4254-4256
Number of pages3
JournalTetrahedron Letters
Volume57
Issue number37
DOIs
Publication statusPublished - 14 Sep 2016

Keywords

  • Hypervalent iodine
  • Iodine
  • Iodylarenes
  • Oxidation
  • Oxone

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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