Mild and efficient synthesis of iodylarenes using Oxone as oxidant

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Abstract

Mild and efficient method for the preparation of iodylarenes by oxidation of iodoarenes with Oxone in aqueous acetonitrile at room temperature is described. This new procedure allows the preparation of various iodylarenes with electron-donating or electron-withdrawing substituents in the aromatic ring including the previously unknown 1,2-diiodylbenzene.

Original languageEnglish
Pages (from-to)4254-4256
Number of pages3
JournalTetrahedron Letters
Volume57
Issue number37
DOIs
Publication statusPublished - 14 Sep 2016

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Oxidants
Electrons
Oxidation
Temperature
potassium peroxymonosulfuric acid
acetonitrile

Keywords

  • Hypervalent iodine
  • Iodine
  • Iodylarenes
  • Oxidation
  • Oxone

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

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title = "Mild and efficient synthesis of iodylarenes using Oxone as oxidant",
abstract = "Mild and efficient method for the preparation of iodylarenes by oxidation of iodoarenes with Oxone in aqueous acetonitrile at room temperature is described. This new procedure allows the preparation of various iodylarenes with electron-donating or electron-withdrawing substituents in the aromatic ring including the previously unknown 1,2-diiodylbenzene.",
keywords = "Hypervalent iodine, Iodine, Iodylarenes, Oxidation, Oxone",
author = "Natalia Soldatova and Pavel Postnikov and Troyan, {Anna A.} and Akira Yoshimura and Yusubov, {Mekhman S.} and Zhdankin, {Viktor V.}",
year = "2016",
month = "9",
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doi = "10.1016/j.tetlet.2016.08.038",
language = "English",
volume = "57",
pages = "4254--4256",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Limited",
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TY - JOUR

T1 - Mild and efficient synthesis of iodylarenes using Oxone as oxidant

AU - Soldatova, Natalia

AU - Postnikov, Pavel

AU - Troyan, Anna A.

AU - Yoshimura, Akira

AU - Yusubov, Mekhman S.

AU - Zhdankin, Viktor V.

PY - 2016/9/14

Y1 - 2016/9/14

N2 - Mild and efficient method for the preparation of iodylarenes by oxidation of iodoarenes with Oxone in aqueous acetonitrile at room temperature is described. This new procedure allows the preparation of various iodylarenes with electron-donating or electron-withdrawing substituents in the aromatic ring including the previously unknown 1,2-diiodylbenzene.

AB - Mild and efficient method for the preparation of iodylarenes by oxidation of iodoarenes with Oxone in aqueous acetonitrile at room temperature is described. This new procedure allows the preparation of various iodylarenes with electron-donating or electron-withdrawing substituents in the aromatic ring including the previously unknown 1,2-diiodylbenzene.

KW - Hypervalent iodine

KW - Iodine

KW - Iodylarenes

KW - Oxidation

KW - Oxone

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U2 - 10.1016/j.tetlet.2016.08.038

DO - 10.1016/j.tetlet.2016.08.038

M3 - Article

AN - SCOPUS:84983071330

VL - 57

SP - 4254

EP - 4256

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 37

ER -