Abstract
On the basis of the general equations of perturbation theory a procedure is suggested for the partial diagonalization of the vibrational-rotational Hamiltonian of a molecule with respect to the vibrational quantum numbers of a nondegenerate vibrational state. Equations are derived for the complete vibrational-rotational wave function and the "effective" rotational Hamiltonian, which is constructed in such a way that the total energy is represented in the form of a sum of the vibrational and rotational energies.
| Original language | English |
|---|---|
| Pages (from-to) | 1106-1109 |
| Number of pages | 4 |
| Journal | Soviet Physics Journal |
| Volume | 18 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - 1 Aug 1975 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Physics and Astronomy(all)
Cite this
Method of the effective flexible gyroscope in polyatomic molecules. / Makushkin, Yu S.; Ulenikov, O. N.
In: Soviet Physics Journal, Vol. 18, No. 8, 01.08.1975, p. 1106-1109.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Method of the effective flexible gyroscope in polyatomic molecules
AU - Makushkin, Yu S.
AU - Ulenikov, O. N.
PY - 1975/8/1
Y1 - 1975/8/1
N2 - On the basis of the general equations of perturbation theory a procedure is suggested for the partial diagonalization of the vibrational-rotational Hamiltonian of a molecule with respect to the vibrational quantum numbers of a nondegenerate vibrational state. Equations are derived for the complete vibrational-rotational wave function and the "effective" rotational Hamiltonian, which is constructed in such a way that the total energy is represented in the form of a sum of the vibrational and rotational energies.
AB - On the basis of the general equations of perturbation theory a procedure is suggested for the partial diagonalization of the vibrational-rotational Hamiltonian of a molecule with respect to the vibrational quantum numbers of a nondegenerate vibrational state. Equations are derived for the complete vibrational-rotational wave function and the "effective" rotational Hamiltonian, which is constructed in such a way that the total energy is represented in the form of a sum of the vibrational and rotational energies.
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UR - http://www.scopus.com/inward/citedby.url?scp=34250390499&partnerID=8YFLogxK
U2 - 10.1007/BF01110030
DO - 10.1007/BF01110030
M3 - Article
VL - 18
SP - 1106
EP - 1109
JO - Russian Physics Journal
JF - Russian Physics Journal
SN - 1064-8887
IS - 8
ER -