Method of the effective flexible gyroscope in polyatomic molecules

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Abstract

On the basis of the general equations of perturbation theory a procedure is suggested for the partial diagonalization of the vibrational-rotational Hamiltonian of a molecule with respect to the vibrational quantum numbers of a nondegenerate vibrational state. Equations are derived for the complete vibrational-rotational wave function and the "effective" rotational Hamiltonian, which is constructed in such a way that the total energy is represented in the form of a sum of the vibrational and rotational energies.

Original language	English
Pages (from-to)	1106-1109
Number of pages	4
Journal	Soviet Physics Journal
Volume	18
Issue number	8
DOIs	https://doi.org/10.1007/BF01110030
Publication status	Published - 1 Aug 1975
Externally published	Yes

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ASJC Scopus subject areas

Physics and Astronomy(all)

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Makushkin, Y. S., & Ulenikov, O. N. (1975). Method of the effective flexible gyroscope in polyatomic molecules. Soviet Physics Journal, 18(8), 1106-1109. https://doi.org/10.1007/BF01110030

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Access to Document

10.1007/BF01110030