Abstract
On the basis of the general equations of perturbation theory a procedure is suggested for the partial diagonalization of the vibrational-rotational Hamiltonian of a molecule with respect to the vibrational quantum numbers of a nondegenerate vibrational state. Equations are derived for the complete vibrational-rotational wave function and the "effective" rotational Hamiltonian, which is constructed in such a way that the total energy is represented in the form of a sum of the vibrational and rotational energies.
| Original language | English |
|---|---|
| Pages (from-to) | 1106-1109 |
| Number of pages | 4 |
| Journal | Soviet Physics Journal |
| Volume | 18 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - 1 Aug 1975 |
| Externally published | Yes |
ASJC Scopus subject areas
- Physics and Astronomy(all)
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Makushkin, Y. S., & Ulenikov, O. N. (1975). Method of the effective flexible gyroscope in polyatomic molecules. Soviet Physics Journal, 18(8), 1106-1109. https://doi.org/10.1007/BF01110030