Abstract
On the basis of the general equations of perturbation theory a procedure is suggested for the partial diagonalization of the vibrational-rotational Hamiltonian of a molecule with respect to the vibrational quantum numbers of a nondegenerate vibrational state. Equations are derived for the complete vibrational-rotational wave function and the "effective" rotational Hamiltonian, which is constructed in such a way that the total energy is represented in the form of a sum of the vibrational and rotational energies.
Original language | English |
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Pages (from-to) | 1106-1109 |
Number of pages | 4 |
Journal | Soviet Physics Journal |
Volume | 18 |
Issue number | 8 |
DOIs | |
Publication status | Published - 1 Aug 1975 |
Externally published | Yes |
ASJC Scopus subject areas
- Physics and Astronomy(all)