Abstract
Water objects of Siberia north contain impurities in water in colloid form. The impurities are stable to physical and chemical influence. Search ways of decreasing of natural colloid solutions stability is topical issue. Destruction of colloid particles makes it possible to produce qualitative potable water. In the present work factors influenced on aggregate stability of colloid solutions are represented. It is shown that a disperse phase of natural colloid systems consists of iron and silicium ions and humic organic substances in the ratio 5.6 mg/L : 20 mg/L : 2.2 mg/L, respectively. Calculated electrokinetic potential of colloid solutions is in the range from -23 up to -32 mV. Stability of colloid iron is studied at the presence of CaCl2 and AlCl3 electrolits. Coagulation thresholds of CaCl2 and AlCl3 are equal to 1.25 mmol/L and 0.0074 mmol/L, respectively. Furthermore, it is shown pH is also influenced on stability of the colloid system. When pH of solution is 4.5 colloid iron system coagulates. This fact allows developing a method of removal of colloid iron by temporal decreasing of pH by using of carbon dioxide. This method is ecologically safe and allows simplifying technology of water-preparation due to exception of the thin filtration which is used for removal colloid particals. The pH renewal is spontaneous process which is going while carbonization is going. Thermodynamic calculations of reactions describing the destruction mechanism of colloid iron are represented.
| Original language | English |
|---|---|
| Title of host publication | Proceedings - 2012 7th International Forum on Strategic Technology, IFOST 2012 |
| DOIs | |
| Publication status | Published - 2012 |
| Event | 2012 7th International Forum on Strategic Technology, IFOST 2012 - Tomsk, Russian Federation Duration: 18 Sep 2012 → 21 Sep 2012 |
Other
| Other | 2012 7th International Forum on Strategic Technology, IFOST 2012 |
|---|---|
| Country | Russian Federation |
| City | Tomsk |
| Period | 18.9.12 → 21.9.12 |
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Keywords
- carbon dioxide
- colloid iron
- groundwater
- model solution
- pH decreasing
ASJC Scopus subject areas
- Management of Technology and Innovation
Cite this
Method of removal of colloid iron from groundwater of Western Siberia region by using of carbon dioxide. / Machekhina, Ksenia; Shiyan, Ludmila; Tropina, Elena; Voyno, Denis.
Proceedings - 2012 7th International Forum on Strategic Technology, IFOST 2012. 2012. 6357483.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Method of removal of colloid iron from groundwater of Western Siberia region by using of carbon dioxide
AU - Machekhina, Ksenia
AU - Shiyan, Ludmila
AU - Tropina, Elena
AU - Voyno, Denis
PY - 2012
Y1 - 2012
N2 - Water objects of Siberia north contain impurities in water in colloid form. The impurities are stable to physical and chemical influence. Search ways of decreasing of natural colloid solutions stability is topical issue. Destruction of colloid particles makes it possible to produce qualitative potable water. In the present work factors influenced on aggregate stability of colloid solutions are represented. It is shown that a disperse phase of natural colloid systems consists of iron and silicium ions and humic organic substances in the ratio 5.6 mg/L : 20 mg/L : 2.2 mg/L, respectively. Calculated electrokinetic potential of colloid solutions is in the range from -23 up to -32 mV. Stability of colloid iron is studied at the presence of CaCl2 and AlCl3 electrolits. Coagulation thresholds of CaCl2 and AlCl3 are equal to 1.25 mmol/L and 0.0074 mmol/L, respectively. Furthermore, it is shown pH is also influenced on stability of the colloid system. When pH of solution is 4.5 colloid iron system coagulates. This fact allows developing a method of removal of colloid iron by temporal decreasing of pH by using of carbon dioxide. This method is ecologically safe and allows simplifying technology of water-preparation due to exception of the thin filtration which is used for removal colloid particals. The pH renewal is spontaneous process which is going while carbonization is going. Thermodynamic calculations of reactions describing the destruction mechanism of colloid iron are represented.
AB - Water objects of Siberia north contain impurities in water in colloid form. The impurities are stable to physical and chemical influence. Search ways of decreasing of natural colloid solutions stability is topical issue. Destruction of colloid particles makes it possible to produce qualitative potable water. In the present work factors influenced on aggregate stability of colloid solutions are represented. It is shown that a disperse phase of natural colloid systems consists of iron and silicium ions and humic organic substances in the ratio 5.6 mg/L : 20 mg/L : 2.2 mg/L, respectively. Calculated electrokinetic potential of colloid solutions is in the range from -23 up to -32 mV. Stability of colloid iron is studied at the presence of CaCl2 and AlCl3 electrolits. Coagulation thresholds of CaCl2 and AlCl3 are equal to 1.25 mmol/L and 0.0074 mmol/L, respectively. Furthermore, it is shown pH is also influenced on stability of the colloid system. When pH of solution is 4.5 colloid iron system coagulates. This fact allows developing a method of removal of colloid iron by temporal decreasing of pH by using of carbon dioxide. This method is ecologically safe and allows simplifying technology of water-preparation due to exception of the thin filtration which is used for removal colloid particals. The pH renewal is spontaneous process which is going while carbonization is going. Thermodynamic calculations of reactions describing the destruction mechanism of colloid iron are represented.
KW - carbon dioxide
KW - colloid iron
KW - groundwater
KW - model solution
KW - pH decreasing
UR - http://www.scopus.com/inward/record.url?scp=84871826283&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84871826283&partnerID=8YFLogxK
U2 - 10.1109/IFOST.2012.6357483
DO - 10.1109/IFOST.2012.6357483
M3 - Conference contribution
AN - SCOPUS:84871826283
SN - 9781467317702
BT - Proceedings - 2012 7th International Forum on Strategic Technology, IFOST 2012
ER -