Metal dusting as a route to produce active catalyst for processing chlorinated hydrocarbons into carbon nanomaterials

Ilya V. Mishakov, Yuri I. Bauman, Denis V. Korneev, Aleksey A. Vedyagin

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

The interaction of 1,2-dichloroethane (DCE) vapors with bulk NiCr alloy resulting in complete metal wastage with the formation of carbon nanofibers (CNFs) has been described from mechanistic point of view. The genesis of surface transformations of the bulk NiCr alloy exposed to corrosive reaction mix Ar/H2/DCE at 550 C was studied by AFM, SEM and TEM techniques. The mechanism of metal dusting in aggressive reaction media was suggested. The observed process has been considered as a way to produce the self-organizing Ni/CNF catalyst which is effective for further decomposition of chlorinated hydrocarbons leading to nanostructured carbon product.

Original languageEnglish
Pages (from-to)1026-1032
Number of pages7
JournalTopics in Catalysis
Volume56
Issue number11
DOIs
Publication statusPublished - Aug 2013
Externally publishedYes

Fingerprint

Chlorinated Hydrocarbons
Carbon nanofibers
Nanostructured materials
Carbon
Metals
Caustics
Catalysts
Processing
Vapors
Transmission electron microscopy
Decomposition
Scanning electron microscopy
ethylene dichloride

Keywords

  • 1,2-dichloroethane
  • Bulk metals and alloys
  • Carbon nanofibers
  • Chlorinated hydrocarbons
  • Metal dusting
  • NiCr alloy

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this

Metal dusting as a route to produce active catalyst for processing chlorinated hydrocarbons into carbon nanomaterials. / Mishakov, Ilya V.; Bauman, Yuri I.; Korneev, Denis V.; Vedyagin, Aleksey A.

In: Topics in Catalysis, Vol. 56, No. 11, 08.2013, p. 1026-1032.

Research output: Contribution to journalArticle

@article{054e2a5a67f44cb6bf9d316b3a22a646,
title = "Metal dusting as a route to produce active catalyst for processing chlorinated hydrocarbons into carbon nanomaterials",
abstract = "The interaction of 1,2-dichloroethane (DCE) vapors with bulk NiCr alloy resulting in complete metal wastage with the formation of carbon nanofibers (CNFs) has been described from mechanistic point of view. The genesis of surface transformations of the bulk NiCr alloy exposed to corrosive reaction mix Ar/H2/DCE at 550 C was studied by AFM, SEM and TEM techniques. The mechanism of metal dusting in aggressive reaction media was suggested. The observed process has been considered as a way to produce the self-organizing Ni/CNF catalyst which is effective for further decomposition of chlorinated hydrocarbons leading to nanostructured carbon product.",
keywords = "1,2-dichloroethane, Bulk metals and alloys, Carbon nanofibers, Chlorinated hydrocarbons, Metal dusting, NiCr alloy",
author = "Mishakov, {Ilya V.} and Bauman, {Yuri I.} and Korneev, {Denis V.} and Vedyagin, {Aleksey A.}",
year = "2013",
month = "8",
doi = "10.1007/s11244-013-0066-6",
language = "English",
volume = "56",
pages = "1026--1032",
journal = "Topics in Catalysis",
issn = "1022-5528",
publisher = "Springer Netherlands",
number = "11",

}

TY - JOUR

T1 - Metal dusting as a route to produce active catalyst for processing chlorinated hydrocarbons into carbon nanomaterials

AU - Mishakov, Ilya V.

AU - Bauman, Yuri I.

AU - Korneev, Denis V.

AU - Vedyagin, Aleksey A.

PY - 2013/8

Y1 - 2013/8

N2 - The interaction of 1,2-dichloroethane (DCE) vapors with bulk NiCr alloy resulting in complete metal wastage with the formation of carbon nanofibers (CNFs) has been described from mechanistic point of view. The genesis of surface transformations of the bulk NiCr alloy exposed to corrosive reaction mix Ar/H2/DCE at 550 C was studied by AFM, SEM and TEM techniques. The mechanism of metal dusting in aggressive reaction media was suggested. The observed process has been considered as a way to produce the self-organizing Ni/CNF catalyst which is effective for further decomposition of chlorinated hydrocarbons leading to nanostructured carbon product.

AB - The interaction of 1,2-dichloroethane (DCE) vapors with bulk NiCr alloy resulting in complete metal wastage with the formation of carbon nanofibers (CNFs) has been described from mechanistic point of view. The genesis of surface transformations of the bulk NiCr alloy exposed to corrosive reaction mix Ar/H2/DCE at 550 C was studied by AFM, SEM and TEM techniques. The mechanism of metal dusting in aggressive reaction media was suggested. The observed process has been considered as a way to produce the self-organizing Ni/CNF catalyst which is effective for further decomposition of chlorinated hydrocarbons leading to nanostructured carbon product.

KW - 1,2-dichloroethane

KW - Bulk metals and alloys

KW - Carbon nanofibers

KW - Chlorinated hydrocarbons

KW - Metal dusting

KW - NiCr alloy

UR - http://www.scopus.com/inward/record.url?scp=84880420077&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84880420077&partnerID=8YFLogxK

U2 - 10.1007/s11244-013-0066-6

DO - 10.1007/s11244-013-0066-6

M3 - Article

VL - 56

SP - 1026

EP - 1032

JO - Topics in Catalysis

JF - Topics in Catalysis

SN - 1022-5528

IS - 11

ER -