Mechanical and tribological properties of Sn-Cu-O films prepared by reactive magnetron sputtering

Jindřich Musil, Martin Hromádka, Radomír Čerstvý, Zbyněk Soukup

Research output: Contribution to journalArticle

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Abstract

Tin-copper-oxide (Sn-Cu-O) thin films were deposited by reactive magnetron sputtering in an argon-oxygen atmosphere. The effect of the substrate temperature Ts and the amount of Cu in the Sn-Cu-O film on its mechanical and tribological properties was investigated in detail. It was found out that (i) the Sn-Cu-O films prepared at Ts = 500 C are more crystalline and exhibit a higher hardness H (up to 19.5 GPa) compared with the Sn-Cu-O films sputtered on unheated substrates at room temperature (H ≈ 11 GPa), (ii) the coefficient of friction μ of the Sn-Cu-O film is relatively high and decreases from ∼0.9 to ∼0.5 with a decreasing ratio H/E* of the hardness H and the effective Young's modulus E; here E* = E/(1 - ν2), E is the Young's modulus and ν is the Poisson's ratio, (iii) the coefficient of friction μ strongly depends on the relative humidity RH and decreases with an increasing RH of air used in the tribological test, and (iv) the sputtered Sn-Cu-O films exhibit a very low wear rate k, less than ∼2 × 10-6 mm3/Nm. The most important result of the investigation reported is the finding that the knowledge of interrelationships between the mechanical and tribological properties of films makes it possible to optimize their tribological properties and to prepare Sn-Cu-O films with minimum values of the coefficient of friction and wear rate k.

Original languageEnglish
Article number4859275
JournalJournal of Vacuum Science and Technology A: Vacuum, Surfaces and Films
Volume32
Issue number2
DOIs
Publication statusPublished - 1 Mar 2014

Fingerprint

Reactive sputtering
Magnetron sputtering
magnetron sputtering
mechanical properties
coefficient of friction
Friction
modulus of elasticity
argon-oxygen atmospheres
hardness
Elastic moduli
Hardness
Wear of materials
Copper oxides
Argon
Poisson ratio
copper oxides
Substrates
Tin oxides
tin oxides
humidity

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films

Cite this

Mechanical and tribological properties of Sn-Cu-O films prepared by reactive magnetron sputtering. / Musil, Jindřich; Hromádka, Martin; Čerstvý, Radomír; Soukup, Zbyněk.

In: Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films, Vol. 32, No. 2, 4859275, 01.03.2014.

Research output: Contribution to journalArticle

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