Matsuda-Heck reaction with arenediazonium tosylates in water

Ksenia V. Kutonova, Marina E. Trusova, Andrey V. Stankevich, Pavel S. Postnikov, Victor D. Filimonov

Research output: Contribution to journal › Article › peer-review

Abstract

An environmentally friendly Matsuda-Heck reaction with arenediazonium tosylates has been developed for the first time. A range of alkenes was arylated in good to quantitative yields in water. The reaction is significantly accelerated when carried out under microwave heating. The arylation of haloalkylacrylates with diazonium salts has been implemented for the first time.

Original language	English
Pages (from-to)	358-362
Number of pages	5
Journal	Beilstein Journal of Organic Chemistry
Volume	11
DOIs	https://doi.org/10.3762/bjoc.11.41
Publication status	Published - 16 Mar 2015

Keywords

Alkyl cinnamates
Diazonium salts
Matsuda-Heck reaction
Microwave-assisted synthesis
Stilbenes

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.3762/bjoc.11.41

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title = "Matsuda-Heck reaction with arenediazonium tosylates in water",

abstract = "An environmentally friendly Matsuda-Heck reaction with arenediazonium tosylates has been developed for the first time. A range of alkenes was arylated in good to quantitative yields in water. The reaction is significantly accelerated when carried out under microwave heating. The arylation of haloalkylacrylates with diazonium salts has been implemented for the first time.",

keywords = "Alkyl cinnamates, Diazonium salts, Matsuda-Heck reaction, Microwave-assisted synthesis, Stilbenes",

author = "Kutonova, {Ksenia V.} and Trusova, {Marina E.} and Stankevich, {Andrey V.} and Postnikov, {Pavel S.} and Filimonov, {Victor D.}",

year = "2015",

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doi = "10.3762/bjoc.11.41",

language = "English",

volume = "11",

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publisher = "Beilstein-Institut Zur Forderung der Chemischen Wissenschaften",

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AU - Kutonova, Ksenia V.

AU - Trusova, Marina E.

AU - Stankevich, Andrey V.

AU - Postnikov, Pavel S.

AU - Filimonov, Victor D.

PY - 2015/3/16

Y1 - 2015/3/16

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AB - An environmentally friendly Matsuda-Heck reaction with arenediazonium tosylates has been developed for the first time. A range of alkenes was arylated in good to quantitative yields in water. The reaction is significantly accelerated when carried out under microwave heating. The arylation of haloalkylacrylates with diazonium salts has been implemented for the first time.

KW - Alkyl cinnamates

KW - Diazonium salts

KW - Matsuda-Heck reaction

KW - Microwave-assisted synthesis

KW - Stilbenes

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