Mathematical Modeling Sulfuric Acid Catalyzed Alkylation of Isobutane with Olefins

Abstract

The article provides the results of applied mathematical model of sulfuric acid catalyzed alkylation of isobutane with olefins. It was shown that increasing the content of propylene in the feedstock to 2% leads to decrease in octane number of alkylate to 0.5-1.0 points. Alkylates produced from feedstock with less isobutane mass fraction have a smaller value of octane number. Using mathematic model it was determined that the main parameter influencing the acid activity in the alkylation process is the fresh acid concentration.

Original language	English
Pages (from-to)	81-86
Number of pages	6
Journal	Procedia Engineering
Volume	152
DOIs	https://doi.org/10.1016/j.proeng.2016.07.632
Publication status	Published - 2016

Keywords

alkylate
mathematical modeling
octane number
optimization
sulfuric acid alkylation

ASJC Scopus subject areas

Engineering(all)

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10.1016/j.proeng.2016.07.632

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@article{d0c489bc0d56460f938c369a5e832044,

title = "Mathematical Modeling Sulfuric Acid Catalyzed Alkylation of Isobutane with Olefins",

abstract = "The article provides the results of applied mathematical model of sulfuric acid catalyzed alkylation of isobutane with olefins. It was shown that increasing the content of propylene in the feedstock to 2% leads to decrease in octane number of alkylate to 0.5-1.0 points. Alkylates produced from feedstock with less isobutane mass fraction have a smaller value of octane number. Using mathematic model it was determined that the main parameter influencing the acid activity in the alkylation process is the fresh acid concentration.",

keywords = "alkylate, mathematical modeling, octane number, optimization, sulfuric acid alkylation",

author = "Ivashkina, {E. N.} and Ivanchina, {E. D.} and Nurmakanova, {A. E.} and Boychenko, {S. S.} and Ushakov, {A. S.} and Dolganova, {I. O.}",

year = "2016",

doi = "10.1016/j.proeng.2016.07.632",

language = "English",

volume = "152",

pages = "81--86",

journal = "Procedia Engineering",

issn = "1877-7058",

publisher = "Elsevier BV",

}

TY - JOUR

T1 - Mathematical Modeling Sulfuric Acid Catalyzed Alkylation of Isobutane with Olefins

AU - Ivashkina, E. N.

AU - Ivanchina, E. D.

AU - Nurmakanova, A. E.

AU - Boychenko, S. S.

AU - Ushakov, A. S.

AU - Dolganova, I. O.

PY - 2016

Y1 - 2016

N2 - The article provides the results of applied mathematical model of sulfuric acid catalyzed alkylation of isobutane with olefins. It was shown that increasing the content of propylene in the feedstock to 2% leads to decrease in octane number of alkylate to 0.5-1.0 points. Alkylates produced from feedstock with less isobutane mass fraction have a smaller value of octane number. Using mathematic model it was determined that the main parameter influencing the acid activity in the alkylation process is the fresh acid concentration.

AB - The article provides the results of applied mathematical model of sulfuric acid catalyzed alkylation of isobutane with olefins. It was shown that increasing the content of propylene in the feedstock to 2% leads to decrease in octane number of alkylate to 0.5-1.0 points. Alkylates produced from feedstock with less isobutane mass fraction have a smaller value of octane number. Using mathematic model it was determined that the main parameter influencing the acid activity in the alkylation process is the fresh acid concentration.

KW - alkylate

KW - mathematical modeling

KW - octane number

KW - optimization

KW - sulfuric acid alkylation

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U2 - 10.1016/j.proeng.2016.07.632

DO - 10.1016/j.proeng.2016.07.632

M3 - Article

AN - SCOPUS:84985962869

VL - 152

SP - 81

EP - 86

JO - Procedia Engineering

JF - Procedia Engineering

SN - 1877-7058

ER -