Magnetic properties of new complexes of 3d metal chlorides with 3-amino-4-ethoxycarbonylpyrazole

Abstract

New complexes of Co(II), Ni(II), and Cu(II) chlorides with 3-amino-4-ethoxycarbonylpyrazole (L) of the composition ML₂Cl ₂ are synthesized. The compounds are studied by powder X-ray diffraction, electronic and IR spectroscopy, static magnetic susceptibility (temperature range 2-300 K). It is found that in the ML₂Cl ₂ complexes (M = Co(II), Ni(II), Cu(II)) ferromagnetic exchange interactions between the unpaired electrons of metal ions occur. In [CoL ₂Cl₂] and [NiL₂Cl₂] compounds a transition to the magnetically ordered state (T _c â‰Š 10-12 K) is observed.

Original language	English
Pages (from-to)	713-718
Number of pages	6
Journal	Journal of Structural Chemistry
Volume	54
Issue number	4
DOIs	https://doi.org/10.1134/S0022476613040082
Publication status	Published - 18 Oct 2013
Externally published	Yes

Keywords

3-amino-4-ethoxycarbonylpyrazole
3d metals
complexes
electronic and IR spectroscopy
magnetochemistry
synthesis

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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@article{86f63f2b241d4b62909f001bfd514bfd,

title = "Magnetic properties of new complexes of 3d metal chlorides with 3-amino-4-ethoxycarbonylpyrazole",

abstract = "New complexes of Co(II), Ni(II), and Cu(II) chlorides with 3-amino-4-ethoxycarbonylpyrazole (L) of the composition ML2Cl 2 are synthesized. The compounds are studied by powder X-ray diffraction, electronic and IR spectroscopy, static magnetic susceptibility (temperature range 2-300 K). It is found that in the ML2Cl 2 complexes (M = Co(II), Ni(II), Cu(II)) ferromagnetic exchange interactions between the unpaired electrons of metal ions occur. In [CoL 2Cl2] and [NiL2Cl2] compounds a transition to the magnetically ordered state (T c {\^a}‰{\v S} 10-12 K) is observed.",

keywords = "3-amino-4-ethoxycarbonylpyrazole, 3d metals, complexes, electronic and IR spectroscopy, magnetochemistry, synthesis",

author = "Lavrenova, {L. G.} and Zhilin, {A. S.} and Bogomyakov, {A. S.} and Sheludyakova, {L. A.} and Alekseev, {A. V.} and Vasilevskii, {S. F.}",

year = "2013",

month = oct,

day = "18",

doi = "10.1134/S0022476613040082",

language = "English",

volume = "54",

pages = "713--718",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "4",

}

TY - JOUR

T1 - Magnetic properties of new complexes of 3d metal chlorides with 3-amino-4-ethoxycarbonylpyrazole

AU - Lavrenova, L. G.

AU - Zhilin, A. S.

AU - Bogomyakov, A. S.

AU - Sheludyakova, L. A.

AU - Alekseev, A. V.

AU - Vasilevskii, S. F.

PY - 2013/10/18

Y1 - 2013/10/18

N2 - New complexes of Co(II), Ni(II), and Cu(II) chlorides with 3-amino-4-ethoxycarbonylpyrazole (L) of the composition ML2Cl 2 are synthesized. The compounds are studied by powder X-ray diffraction, electronic and IR spectroscopy, static magnetic susceptibility (temperature range 2-300 K). It is found that in the ML2Cl 2 complexes (M = Co(II), Ni(II), Cu(II)) ferromagnetic exchange interactions between the unpaired electrons of metal ions occur. In [CoL 2Cl2] and [NiL2Cl2] compounds a transition to the magnetically ordered state (T c â‰Š 10-12 K) is observed.

AB - New complexes of Co(II), Ni(II), and Cu(II) chlorides with 3-amino-4-ethoxycarbonylpyrazole (L) of the composition ML2Cl 2 are synthesized. The compounds are studied by powder X-ray diffraction, electronic and IR spectroscopy, static magnetic susceptibility (temperature range 2-300 K). It is found that in the ML2Cl 2 complexes (M = Co(II), Ni(II), Cu(II)) ferromagnetic exchange interactions between the unpaired electrons of metal ions occur. In [CoL 2Cl2] and [NiL2Cl2] compounds a transition to the magnetically ordered state (T c â‰Š 10-12 K) is observed.

KW - 3-amino-4-ethoxycarbonylpyrazole

KW - 3d metals

KW - complexes

KW - electronic and IR spectroscopy

KW - magnetochemistry

KW - synthesis

UR - http://www.scopus.com/inward/record.url?scp=84885436607&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84885436607&partnerID=8YFLogxK

U2 - 10.1134/S0022476613040082

DO - 10.1134/S0022476613040082

M3 - Article

AN - SCOPUS:84885436607

VL - 54

SP - 713

EP - 718

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 4