Abstract
New complexes of Co(II), Ni(II), and Cu(II) chlorides with 3-amino-4-ethoxycarbonylpyrazole (L) of the composition ML2Cl 2 are synthesized. The compounds are studied by powder X-ray diffraction, electronic and IR spectroscopy, static magnetic susceptibility (temperature range 2-300 K). It is found that in the ML2Cl 2 complexes (M = Co(II), Ni(II), Cu(II)) ferromagnetic exchange interactions between the unpaired electrons of metal ions occur. In [CoL 2Cl2] and [NiL2Cl2] compounds a transition to the magnetically ordered state (T c ≊ 10-12 K) is observed.
| Original language | English |
|---|---|
| Pages (from-to) | 713-718 |
| Number of pages | 6 |
| Journal | Journal of Structural Chemistry |
| Volume | 54 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - 18 Oct 2013 |
| Externally published | Yes |
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Keywords
- 3-amino-4-ethoxycarbonylpyrazole
- 3d metals
- complexes
- electronic and IR spectroscopy
- magnetochemistry
- synthesis
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry
Cite this
Magnetic properties of new complexes of 3d metal chlorides with 3-amino-4-ethoxycarbonylpyrazole. / Lavrenova, L. G.; Zhilin, A. S.; Bogomyakov, A. S.; Sheludyakova, L. A.; Alekseev, A. V.; Vasilevskii, S. F.
In: Journal of Structural Chemistry, Vol. 54, No. 4, 18.10.2013, p. 713-718.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Magnetic properties of new complexes of 3d metal chlorides with 3-amino-4-ethoxycarbonylpyrazole
AU - Lavrenova, L. G.
AU - Zhilin, A. S.
AU - Bogomyakov, A. S.
AU - Sheludyakova, L. A.
AU - Alekseev, A. V.
AU - Vasilevskii, S. F.
PY - 2013/10/18
Y1 - 2013/10/18
N2 - New complexes of Co(II), Ni(II), and Cu(II) chlorides with 3-amino-4-ethoxycarbonylpyrazole (L) of the composition ML2Cl 2 are synthesized. The compounds are studied by powder X-ray diffraction, electronic and IR spectroscopy, static magnetic susceptibility (temperature range 2-300 K). It is found that in the ML2Cl 2 complexes (M = Co(II), Ni(II), Cu(II)) ferromagnetic exchange interactions between the unpaired electrons of metal ions occur. In [CoL 2Cl2] and [NiL2Cl2] compounds a transition to the magnetically ordered state (T c ≊ 10-12 K) is observed.
AB - New complexes of Co(II), Ni(II), and Cu(II) chlorides with 3-amino-4-ethoxycarbonylpyrazole (L) of the composition ML2Cl 2 are synthesized. The compounds are studied by powder X-ray diffraction, electronic and IR spectroscopy, static magnetic susceptibility (temperature range 2-300 K). It is found that in the ML2Cl 2 complexes (M = Co(II), Ni(II), Cu(II)) ferromagnetic exchange interactions between the unpaired electrons of metal ions occur. In [CoL 2Cl2] and [NiL2Cl2] compounds a transition to the magnetically ordered state (T c ≊ 10-12 K) is observed.
KW - 3-amino-4-ethoxycarbonylpyrazole
KW - 3d metals
KW - complexes
KW - electronic and IR spectroscopy
KW - magnetochemistry
KW - synthesis
UR - http://www.scopus.com/inward/record.url?scp=84885436607&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84885436607&partnerID=8YFLogxK
U2 - 10.1134/S0022476613040082
DO - 10.1134/S0022476613040082
M3 - Article
AN - SCOPUS:84885436607
VL - 54
SP - 713
EP - 718
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 4
ER -