M-lodosylbenzoic acid - A convenient recyclable reagent for highly efficient aromatic iodinations

Andreas Kirschning, Mekhman S. Yusubov, Roza Y. Yusubova, Ki Whan Chi, Joo Y. Park

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

m-lodosylbenzoic acid performs iodinations of arenes in the presence of iodine at room temperature in acetonitrile. Separation of pure products is conveniently achieved by scavenging any aryl iodide by ion exchange with IRA-900 (hydroxide form). The reduced form of the reagent, m-iodobenzoic acid, can be easily recovered from the ion exchange resin or from the basic aqueous solution by simple acidification with HCl.

Original languageEnglish
Article number19
JournalBeilstein Journal of Organic Chemistry
Volume3
DOIs
Publication statusPublished - 1 Aug 2007

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Iodobenzoates
Ion Exchange Resins
Acidification
Scavenging
Iodides
Iodine
Ion exchange
Acids
Temperature
hydroxide ion
acetonitrile

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

M-lodosylbenzoic acid - A convenient recyclable reagent for highly efficient aromatic iodinations. / Kirschning, Andreas; Yusubov, Mekhman S.; Yusubova, Roza Y.; Chi, Ki Whan; Park, Joo Y.

In: Beilstein Journal of Organic Chemistry, Vol. 3, 19, 01.08.2007.

Research output: Contribution to journalArticle

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