M-lodosylbenzoic acid - A convenient recyclable reagent for highly efficient aromatic iodinations — National Research Tomsk Polytechnic University

Abstract

m-lodosylbenzoic acid performs iodinations of arenes in the presence of iodine at room temperature in acetonitrile. Separation of pure products is conveniently achieved by scavenging any aryl iodide by ion exchange with IRA-900 (hydroxide form). The reduced form of the reagent, m-iodobenzoic acid, can be easily recovered from the ion exchange resin or from the basic aqueous solution by simple acidification with HCl.

Original language	English
Article number	19
Journal	Beilstein Journal of Organic Chemistry
Volume	3
DOIs	https://doi.org/10.1186/1860-5397-3-19
Publication status	Published - 1 Aug 2007

ASJC Scopus subject areas

Organic Chemistry

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10.1186/1860-5397-3-19

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title = "M-lodosylbenzoic acid - A convenient recyclable reagent for highly efficient aromatic iodinations",

abstract = "m-lodosylbenzoic acid performs iodinations of arenes in the presence of iodine at room temperature in acetonitrile. Separation of pure products is conveniently achieved by scavenging any aryl iodide by ion exchange with IRA-900 (hydroxide form). The reduced form of the reagent, m-iodobenzoic acid, can be easily recovered from the ion exchange resin or from the basic aqueous solution by simple acidification with HCl.",

author = "Andreas Kirschning and Yusubov, {Mekhman S.} and Yusubova, {Roza Y.} and Chi, {Ki Whan} and Park, {Joo Y.}",

year = "2007",

month = aug,

day = "1",

doi = "10.1186/1860-5397-3-19",

language = "English",

volume = "3",

journal = "Beilstein Journal of Organic Chemistry",

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T1 - M-lodosylbenzoic acid - A convenient recyclable reagent for highly efficient aromatic iodinations

AU - Kirschning, Andreas

AU - Yusubov, Mekhman S.

AU - Yusubova, Roza Y.

AU - Chi, Ki Whan

AU - Park, Joo Y.

PY - 2007/8/1

Y1 - 2007/8/1

N2 - m-lodosylbenzoic acid performs iodinations of arenes in the presence of iodine at room temperature in acetonitrile. Separation of pure products is conveniently achieved by scavenging any aryl iodide by ion exchange with IRA-900 (hydroxide form). The reduced form of the reagent, m-iodobenzoic acid, can be easily recovered from the ion exchange resin or from the basic aqueous solution by simple acidification with HCl.

AB - m-lodosylbenzoic acid performs iodinations of arenes in the presence of iodine at room temperature in acetonitrile. Separation of pure products is conveniently achieved by scavenging any aryl iodide by ion exchange with IRA-900 (hydroxide form). The reduced form of the reagent, m-iodobenzoic acid, can be easily recovered from the ion exchange resin or from the basic aqueous solution by simple acidification with HCl.

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