Abstract
m-lodosylbenzoic acid performs iodinations of arenes in the presence of iodine at room temperature in acetonitrile. Separation of pure products is conveniently achieved by scavenging any aryl iodide by ion exchange with IRA-900 (hydroxide form). The reduced form of the reagent, m-iodobenzoic acid, can be easily recovered from the ion exchange resin or from the basic aqueous solution by simple acidification with HCl.
| Original language | English |
|---|---|
| Article number | 19 |
| Journal | Beilstein Journal of Organic Chemistry |
| Volume | 3 |
| DOIs | |
| Publication status | Published - 1 Aug 2007 |
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ASJC Scopus subject areas
- Organic Chemistry
Cite this
M-lodosylbenzoic acid - A convenient recyclable reagent for highly efficient aromatic iodinations. / Kirschning, Andreas; Yusubov, Mekhman S.; Yusubova, Roza Y.; Chi, Ki Whan; Park, Joo Y.
In: Beilstein Journal of Organic Chemistry, Vol. 3, 19, 01.08.2007.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - M-lodosylbenzoic acid - A convenient recyclable reagent for highly efficient aromatic iodinations
AU - Kirschning, Andreas
AU - Yusubov, Mekhman S.
AU - Yusubova, Roza Y.
AU - Chi, Ki Whan
AU - Park, Joo Y.
PY - 2007/8/1
Y1 - 2007/8/1
N2 - m-lodosylbenzoic acid performs iodinations of arenes in the presence of iodine at room temperature in acetonitrile. Separation of pure products is conveniently achieved by scavenging any aryl iodide by ion exchange with IRA-900 (hydroxide form). The reduced form of the reagent, m-iodobenzoic acid, can be easily recovered from the ion exchange resin or from the basic aqueous solution by simple acidification with HCl.
AB - m-lodosylbenzoic acid performs iodinations of arenes in the presence of iodine at room temperature in acetonitrile. Separation of pure products is conveniently achieved by scavenging any aryl iodide by ion exchange with IRA-900 (hydroxide form). The reduced form of the reagent, m-iodobenzoic acid, can be easily recovered from the ion exchange resin or from the basic aqueous solution by simple acidification with HCl.
UR - http://www.scopus.com/inward/record.url?scp=34547190676&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=34547190676&partnerID=8YFLogxK
U2 - 10.1186/1860-5397-3-19
DO - 10.1186/1860-5397-3-19
M3 - Article
AN - SCOPUS:34547190676
VL - 3
JO - Beilstein Journal of Organic Chemistry
JF - Beilstein Journal of Organic Chemistry
SN - 1860-5397
M1 - 19
ER -