Low-temperature nanodoping of protonated LiNbO3 crystals by univalent ions

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

In the nanocomposite model developed here, crystals are treated as subordinate aggregate of pro- ton-selected structural elements, their blocks, and proton-containing quantum sublattices with preferred transport effects separating them. The formation of stratified reversible hexagonal structures is accompanied with protonation and formation of a dense network of H-bonds ensuring the nanocomposite properties. Nanodoping with H+ ions occurs during processing of crystals and glasses in melts as well as in aqueous solutions of Ag, Tl, Rb, and Cs salts. The isotope exchange H+ ↔ D+ and ion exchange H+ ↔ M+ lead to nanodoping of protonated materials with D+ and M+ ions. This is manifested especially clearly in Li-depleted nonequilibrium LiNbO3 and LiTaO3 crystals. Low-temperature proton-ion nanodoping over superlattices is a basically new approach to analysis of the structure and properties of extremely nonequilibrium materials.

Original languageEnglish
Pages (from-to)107-111
Number of pages5
JournalTechnical Physics
Volume60
Issue number1
DOIs
Publication statusPublished - Jan 2015

Fingerprint

crystals
protons
nanocomposites
ions
sublattices
superlattices
isotopes
aqueous solutions
salts
glass

ASJC Scopus subject areas

  • Physics and Astronomy (miscellaneous)

Cite this

Low-temperature nanodoping of protonated LiNbO3 crystals by univalent ions. / Borodin, Yu V.

In: Technical Physics, Vol. 60, No. 1, 01.2015, p. 107-111.

Research output: Contribution to journalArticle

@article{4af267d79f324f149595738a2eecb75e,
title = "Low-temperature nanodoping of protonated LiNbO3 crystals by univalent ions",
abstract = "In the nanocomposite model developed here, crystals are treated as subordinate aggregate of pro- ton-selected structural elements, their blocks, and proton-containing quantum sublattices with preferred transport effects separating them. The formation of stratified reversible hexagonal structures is accompanied with protonation and formation of a dense network of H-bonds ensuring the nanocomposite properties. Nanodoping with H+ ions occurs during processing of crystals and glasses in melts as well as in aqueous solutions of Ag, Tl, Rb, and Cs salts. The isotope exchange H+ ↔ D+ and ion exchange H+ ↔ M+ lead to nanodoping of protonated materials with D+ and M+ ions. This is manifested especially clearly in Li-depleted nonequilibrium LiNbO3 and LiTaO3 crystals. Low-temperature proton-ion nanodoping over superlattices is a basically new approach to analysis of the structure and properties of extremely nonequilibrium materials.",
author = "Borodin, {Yu V.}",
year = "2015",
month = "1",
doi = "10.1134/S1063784215010065",
language = "English",
volume = "60",
pages = "107--111",
journal = "Technical Physics",
issn = "1063-7842",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "1",

}

TY - JOUR

T1 - Low-temperature nanodoping of protonated LiNbO3 crystals by univalent ions

AU - Borodin, Yu V.

PY - 2015/1

Y1 - 2015/1

N2 - In the nanocomposite model developed here, crystals are treated as subordinate aggregate of pro- ton-selected structural elements, their blocks, and proton-containing quantum sublattices with preferred transport effects separating them. The formation of stratified reversible hexagonal structures is accompanied with protonation and formation of a dense network of H-bonds ensuring the nanocomposite properties. Nanodoping with H+ ions occurs during processing of crystals and glasses in melts as well as in aqueous solutions of Ag, Tl, Rb, and Cs salts. The isotope exchange H+ ↔ D+ and ion exchange H+ ↔ M+ lead to nanodoping of protonated materials with D+ and M+ ions. This is manifested especially clearly in Li-depleted nonequilibrium LiNbO3 and LiTaO3 crystals. Low-temperature proton-ion nanodoping over superlattices is a basically new approach to analysis of the structure and properties of extremely nonequilibrium materials.

AB - In the nanocomposite model developed here, crystals are treated as subordinate aggregate of pro- ton-selected structural elements, their blocks, and proton-containing quantum sublattices with preferred transport effects separating them. The formation of stratified reversible hexagonal structures is accompanied with protonation and formation of a dense network of H-bonds ensuring the nanocomposite properties. Nanodoping with H+ ions occurs during processing of crystals and glasses in melts as well as in aqueous solutions of Ag, Tl, Rb, and Cs salts. The isotope exchange H+ ↔ D+ and ion exchange H+ ↔ M+ lead to nanodoping of protonated materials with D+ and M+ ions. This is manifested especially clearly in Li-depleted nonequilibrium LiNbO3 and LiTaO3 crystals. Low-temperature proton-ion nanodoping over superlattices is a basically new approach to analysis of the structure and properties of extremely nonequilibrium materials.

UR - http://www.scopus.com/inward/record.url?scp=84921975126&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84921975126&partnerID=8YFLogxK

U2 - 10.1134/S1063784215010065

DO - 10.1134/S1063784215010065

M3 - Article

VL - 60

SP - 107

EP - 111

JO - Technical Physics

JF - Technical Physics

SN - 1063-7842

IS - 1

ER -