Localized surface curvature artifacts in tip-enhanced nanospectroscopy imaging

E. Sheremet, L. Kim, D. Stepanichsheva, V. Kolchuzhin, A. Milekhin, D. R.T. Zahn, R. D. Rodriguez

Research output: Contribution to journalArticle

Abstract

Tip-enhanced Raman spectroscopy (TERS) allows the chemical analysis with a spatial resolution at the nanoscale, well beyond what the diffraction limit of light makes possible. We can further boost the TERS sensitivity by using a metallic substrate in the so-called gap-mode TERS. In this context, the goal of this work is to provide a generalized view of imaging artifacts in TERS and near-field imaging that occur due to tip-sample coupling. Contrary to the case of gap-mode with a flat substrate where the size of the enhanced region is smaller than the tip size when visualizing 3D nanostructures the tip convolution effect may broaden the observed dimensions due to the local curvature of the sample. This effect is particularly critical considering that most works on gap-mode TERS consider a perfectly flat substrate which is rarely the case in actual experiments. We investigate a range of substrates to evidence these geometrical effects and to obtain an understanding of the nanoscale curvature role in TERS imaging. Our experimental results are complemented by numerical simulations and an analogy with atomic force microscopy artifacts is introduced. As a result, this work offers a useful analysis of gap-mode TERS imaging with tip- and substrate-related artifacts furthering our understanding and the reliability of near-field optical nanospectroscopy.

Original languageEnglish
Article number112811
JournalUltramicroscopy
Volume206
DOIs
Publication statusPublished - 1 Nov 2019

Fingerprint

Raman spectroscopy
artifacts
curvature
Imaging techniques
Substrates
near fields
Convolution
Atomic force microscopy
Nanostructures
Diffraction
acceleration (physics)
chemical analysis
convolution integrals
Computer simulation
Chemical analysis
spatial resolution
atomic force microscopy
Experiments
sensitivity
diffraction

Keywords

  • Imaging artifacts
  • Nanospectroscopy
  • Plasmonics
  • Scanning probe microscopy
  • TERS

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Atomic and Molecular Physics, and Optics
  • Instrumentation

Cite this

Localized surface curvature artifacts in tip-enhanced nanospectroscopy imaging. / Sheremet, E.; Kim, L.; Stepanichsheva, D.; Kolchuzhin, V.; Milekhin, A.; Zahn, D. R.T.; Rodriguez, R. D.

In: Ultramicroscopy, Vol. 206, 112811, 01.11.2019.

Research output: Contribution to journalArticle

Sheremet, E. ; Kim, L. ; Stepanichsheva, D. ; Kolchuzhin, V. ; Milekhin, A. ; Zahn, D. R.T. ; Rodriguez, R. D. / Localized surface curvature artifacts in tip-enhanced nanospectroscopy imaging. In: Ultramicroscopy. 2019 ; Vol. 206.
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