Abstract
C1 Kα line shifts and 35Cl NQR frequencies have been measured for series of titanium tetrachloride complexes. Nonempirical calculations of corresponding free ligands have been carried out on the MP2/6-31G* level. Dependencies of the experimental data obtained on experimental and calculated parameters of ligand donor ability have been analyzed. It is shown that the electron density on acceptor chlorine atoms and the electric field gradient on their nuclei are determined at first by the polarizing effect of the ligand.
Original language | English |
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Pages (from-to) | 177-181 |
Number of pages | 5 |
Journal | Heteroatom Chemistry |
Volume | 11 |
Issue number | 3 |
DOIs | |
Publication status | Published - 2000 |
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ASJC Scopus subject areas
- Chemistry(all)
Cite this
Ligand effect on chlorine electron density distribution in titanium tetrachloride complexes. / Dolenko, G. N.; Gostevskii, B. A.; Poleshchuk, O. Kh; Latosinska, J.; Ostafin, M.; Belogolov, M. A.; Grechneva, M. V.
In: Heteroatom Chemistry, Vol. 11, No. 3, 2000, p. 177-181.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Ligand effect on chlorine electron density distribution in titanium tetrachloride complexes
AU - Dolenko, G. N.
AU - Gostevskii, B. A.
AU - Poleshchuk, O. Kh
AU - Latosinska, J.
AU - Ostafin, M.
AU - Belogolov, M. A.
AU - Grechneva, M. V.
PY - 2000
Y1 - 2000
N2 - C1 Kα line shifts and 35Cl NQR frequencies have been measured for series of titanium tetrachloride complexes. Nonempirical calculations of corresponding free ligands have been carried out on the MP2/6-31G* level. Dependencies of the experimental data obtained on experimental and calculated parameters of ligand donor ability have been analyzed. It is shown that the electron density on acceptor chlorine atoms and the electric field gradient on their nuclei are determined at first by the polarizing effect of the ligand.
AB - C1 Kα line shifts and 35Cl NQR frequencies have been measured for series of titanium tetrachloride complexes. Nonempirical calculations of corresponding free ligands have been carried out on the MP2/6-31G* level. Dependencies of the experimental data obtained on experimental and calculated parameters of ligand donor ability have been analyzed. It is shown that the electron density on acceptor chlorine atoms and the electric field gradient on their nuclei are determined at first by the polarizing effect of the ligand.
UR - http://www.scopus.com/inward/record.url?scp=0033693251&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0033693251&partnerID=8YFLogxK
U2 - 10.1002/(SICI)1098-1071(2000)11:3<177::AID-HC2>3.0.CO;2-Y
DO - 10.1002/(SICI)1098-1071(2000)11:3<177::AID-HC2>3.0.CO;2-Y
M3 - Article
AN - SCOPUS:0033693251
VL - 11
SP - 177
EP - 181
JO - Heteroatom Chemistry
JF - Heteroatom Chemistry
SN - 1042-7163
IS - 3
ER -