Ligand effect on chlorine electron density distribution in titanium tetrachloride complexes

G. N. Dolenko, B. A. Gostevskii, O. Kh Poleshchuk, J. Latosinska, M. Ostafin, M. A. Belogolov, M. V. Grechneva

    Research output: Contribution to journal › Article

    Abstract

    C1 Kα line shifts and 35Cl NQR frequencies have been measured for series of titanium tetrachloride complexes. Nonempirical calculations of corresponding free ligands have been carried out on the MP2/6-31G* level. Dependencies of the experimental data obtained on experimental and calculated parameters of ligand donor ability have been analyzed. It is shown that the electron density on acceptor chlorine atoms and the electric field gradient on their nuclei are determined at first by the polarizing effect of the ligand.

    Original languageEnglish
    Pages (from-to)177-181
    Number of pages5
    JournalHeteroatom Chemistry
    Volume11
    Issue number3
    DOIs
    Publication statusPublished - 2000

    Fingerprint

    Electronic density of states
    Chlorine
    Ligands
    Carrier concentration
    Electric fields
    Atoms
    titanium tetrachloride

    ASJC Scopus subject areas

    • Chemistry(all)

    Cite this

    Dolenko, G. N., Gostevskii, B. A., Poleshchuk, O. K., Latosinska, J., Ostafin, M., Belogolov, M. A., & Grechneva, M. V. (2000). Ligand effect on chlorine electron density distribution in titanium tetrachloride complexes. Heteroatom Chemistry, 11(3), 177-181. https://doi.org/10.1002/(SICI)1098-1071(2000)11:3<177::AID-HC2>3.0.CO;2-Y

    Ligand effect on chlorine electron density distribution in titanium tetrachloride complexes. / Dolenko, G. N.; Gostevskii, B. A.; Poleshchuk, O. Kh; Latosinska, J.; Ostafin, M.; Belogolov, M. A.; Grechneva, M. V.

    In: Heteroatom Chemistry, Vol. 11, No. 3, 2000, p. 177-181.

    Research output: Contribution to journal › Article

    Dolenko, GN, Gostevskii, BA, Poleshchuk, OK, Latosinska, J, Ostafin, M, Belogolov, MA & Grechneva, MV 2000, 'Ligand effect on chlorine electron density distribution in titanium tetrachloride complexes', Heteroatom Chemistry, vol. 11, no. 3, pp. 177-181. https://doi.org/10.1002/(SICI)1098-1071(2000)11:3<177::AID-HC2>3.0.CO;2-Y
    Dolenko GN, Gostevskii BA, Poleshchuk OK, Latosinska J, Ostafin M, Belogolov MA et al. Ligand effect on chlorine electron density distribution in titanium tetrachloride complexes. Heteroatom Chemistry. 2000;11(3):177-181. https://doi.org/10.1002/(SICI)1098-1071(2000)11:3<177::AID-HC2>3.0.CO;2-Y
    Dolenko, G. N. ; Gostevskii, B. A. ; Poleshchuk, O. Kh ; Latosinska, J. ; Ostafin, M. ; Belogolov, M. A. ; Grechneva, M. V. / Ligand effect on chlorine electron density distribution in titanium tetrachloride complexes. In: Heteroatom Chemistry. 2000 ; Vol. 11, No. 3. pp. 177-181.
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    AU - Dolenko, G. N.

    AU - Gostevskii, B. A.

    AU - Poleshchuk, O. Kh

    AU - Latosinska, J.

    AU - Ostafin, M.

    AU - Belogolov, M. A.

    AU - Grechneva, M. V.

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    AB - C1 Kα line shifts and 35Cl NQR frequencies have been measured for series of titanium tetrachloride complexes. Nonempirical calculations of corresponding free ligands have been carried out on the MP2/6-31G* level. Dependencies of the experimental data obtained on experimental and calculated parameters of ligand donor ability have been analyzed. It is shown that the electron density on acceptor chlorine atoms and the electric field gradient on their nuclei are determined at first by the polarizing effect of the ligand.

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