Latent ruthenium carbene complexes with six-membered N- and S-chelate rings

N. M. Shcheglova, V. D. Kolesnik, R. V. Ashirov, E. A. Krasnokutskaya

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

New ruthenium carbene complexes with chelating N- and S-benzylidene ligands were synthesized by the reactions of second- and third-generation Grubbs catalysts with ortho-vinylbenzyl-substituted amines or sulfides. These complexes were shown to exhibit catalytic activity in ring-opening metathesis polymerization and ring-closing metathesis.

Original languageEnglish
Pages (from-to)490-497
Number of pages8
JournalRussian Chemical Bulletin
Volume65
Issue number2
DOIs
Publication statusPublished - 1 Feb 2016

Keywords

  • carbene complexes
  • catalyst
  • dicyclopentadiene
  • metathesis
  • polydicyclopentadiene
  • polymerization
  • ruthenium

ASJC Scopus subject areas

  • Chemistry(all)

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