Abstract
The kinetics of the metathesis polymerization of three isomeric 2,3-dicarbomethoxy-5-norbornenes on an original Hoveyda-Grubbs II type catalyst Has been investigated by 1H NMR spectroscopy. The activation energies of metathesis polymerization and the homopolymerization rate constants have been calculated for all esters from experimental data. The polymerization rate constant of endic acid dimethyl ester (endo,endo-2,3-dicarbomethoxy-5- norbornene) is almost two orders of magnitude lower than that of the reaction of exo,exo-2,3-dicarbomethoxy-5-norbornene. Selected parameters of the microstructure of the resulting polymers are presented.
| Original language | English |
|---|---|
| Pages (from-to) | 469-474 |
| Number of pages | 6 |
| Journal | Kinetics and Catalysis |
| Volume | 54 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - Jul 2013 |
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ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Computer Science Applications
- Modelling and Simulation
Cite this
Kinetics of the metathesis polymerization of 5,6-Di(methoxycarbonyl) bicyclo[2.2.1]hept-2-enes on an original Hoveyda-Grubbs II type catalyst. / Ashirov, R. V.; Zemlyakov, D. I.; Lyapkov, A. A.; Kiselev, S. A.
In: Kinetics and Catalysis, Vol. 54, No. 4, 07.2013, p. 469-474.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Kinetics of the metathesis polymerization of 5,6-Di(methoxycarbonyl) bicyclo[2.2.1]hept-2-enes on an original Hoveyda-Grubbs II type catalyst
AU - Ashirov, R. V.
AU - Zemlyakov, D. I.
AU - Lyapkov, A. A.
AU - Kiselev, S. A.
PY - 2013/7
Y1 - 2013/7
N2 - The kinetics of the metathesis polymerization of three isomeric 2,3-dicarbomethoxy-5-norbornenes on an original Hoveyda-Grubbs II type catalyst Has been investigated by 1H NMR spectroscopy. The activation energies of metathesis polymerization and the homopolymerization rate constants have been calculated for all esters from experimental data. The polymerization rate constant of endic acid dimethyl ester (endo,endo-2,3-dicarbomethoxy-5- norbornene) is almost two orders of magnitude lower than that of the reaction of exo,exo-2,3-dicarbomethoxy-5-norbornene. Selected parameters of the microstructure of the resulting polymers are presented.
AB - The kinetics of the metathesis polymerization of three isomeric 2,3-dicarbomethoxy-5-norbornenes on an original Hoveyda-Grubbs II type catalyst Has been investigated by 1H NMR spectroscopy. The activation energies of metathesis polymerization and the homopolymerization rate constants have been calculated for all esters from experimental data. The polymerization rate constant of endic acid dimethyl ester (endo,endo-2,3-dicarbomethoxy-5- norbornene) is almost two orders of magnitude lower than that of the reaction of exo,exo-2,3-dicarbomethoxy-5-norbornene. Selected parameters of the microstructure of the resulting polymers are presented.
UR - http://www.scopus.com/inward/record.url?scp=84887436182&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84887436182&partnerID=8YFLogxK
U2 - 10.1134/S0023158413040010
DO - 10.1134/S0023158413040010
M3 - Article
VL - 54
SP - 469
EP - 474
JO - Kinetics and Catalysis
JF - Kinetics and Catalysis
SN - 0023-1584
IS - 4
ER -