Kinetics of methane hydrate dissociation

V. E. Nakoryakov, S. Ya Misyura

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The methane hydrate dissociation at an external pressure of 1 bar has been experimentally studied. The methane dissociation rate depends on the heat transfer intensity in the course of dissociation. Quasi-isothermal and nonisothermal conditions of clathrate dissociation have been compared. Under nonisothermal conditions, the dissociation rate depends on the heat flux density. The lowest heat flux was achieved in a quasi-stationary mode, and the highest heat flux was achieved through combustion of methane released from the clathrate powder. The 54-fold increase in heat flux leads to the ninefold increase in the methane dissociation rate. Depending on the heat flux density, the following variants of clathrate dissociation were observed: without self-preservation, partial self-preservation with one dissociation rate minimum, and partial self-preservation with two minima.

Original languageEnglish
Pages (from-to)244-246
Number of pages3
JournalDoklady Physical Chemistry
Volume464
Issue number2
DOIs
Publication statusPublished - 1 Oct 2015
Externally publishedYes

Fingerprint

Methane
Hydrates
hydrates
methane
dissociation
Kinetics
kinetics
Heat flux
heat flux
clathrates
flux density
Powders
heat transfer
Heat transfer

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Kinetics of methane hydrate dissociation. / Nakoryakov, V. E.; Misyura, S. Ya.

In: Doklady Physical Chemistry, Vol. 464, No. 2, 01.10.2015, p. 244-246.

Research output: Contribution to journalArticle

Nakoryakov, V. E. ; Misyura, S. Ya. / Kinetics of methane hydrate dissociation. In: Doklady Physical Chemistry. 2015 ; Vol. 464, No. 2. pp. 244-246.
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