Kinetic studies of methanol dehydrogenation. Part III

carbon-supported copper catalysts

Ekaterina V. Shelepova, Ludmila Yu Ilina, Aleksey A. Vedyagin

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The kinetics of methanol dehydrogenation over carbon-supported copper catalyst was studied. The catalyst was prepared by the incipient wetness impregnation of carbonaceous graphite-like material Sibunit with aqueous solution of copper nitrate. The resulting Cu/C samples were calcined and reduced in a hydrogen flow within temperature interval of 200–400 °C. Experiments were carried out in a flow-through fixed-bed tubular reactor. Observable rate constants were determined for the reactions of methanol dehydrogenation to methyl formate and methyl formate decomposition on carbon monoxide and hydrogen. The process of methanol dehydrogenation in a tubular reactor was simulated by means of mathematical modeling. The estimation of kinetic parameters in accordance with experimental data obtained for the Cu/C sample reduced at 300 °C has allowed us to consider the reversibility of methanol dehydrogenation reaction.

Original languageEnglish
Pages (from-to)1-14
Number of pages14
JournalReaction Kinetics, Mechanisms and Catalysis
Volume122
Issue number1
DOIs
Publication statusAccepted/In press - 14 Jun 2017

Fingerprint

Dehydrogenation
dehydrogenation
Methanol
Copper
Carbon
methyl alcohol
catalysts
copper
Catalysts
Kinetics
carbon
formates
kinetics
Hydrogen
reactors
Graphite
hydrogen
Carbon Monoxide
Kinetic parameters
Impregnation

Keywords

  • Carbon-supported copper catalysts
  • Kinetics
  • Methanol dehydrogenation
  • Methyl formate
  • Rate constants
  • Sibunit

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

Cite this

Kinetic studies of methanol dehydrogenation. Part III : carbon-supported copper catalysts. / Shelepova, Ekaterina V.; Ilina, Ludmila Yu; Vedyagin, Aleksey A.

In: Reaction Kinetics, Mechanisms and Catalysis, Vol. 122, No. 1, 14.06.2017, p. 1-14.

Research output: Contribution to journalArticle

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