Joint Rotational Analysis of 24 Bands of the H<sub>2</sub>Se Molecule

Abstract

A global fit of all currently available rotation-vibration energies has been made for 24 vibrational states of the H⁸⁰₂Se molecule. The resulting set of 112 parameters reproduces the initial 3516 vibration-rotation energies with a mean accuracy of 10.6 × 10^-3 cm^-1. Using this model as a starting point, the rotational fine structure of the extremely weak local mode bands (13⁺; 1)/(13^-; 1) and (06⁺; 0)/(06^-; 0) could be analyzed; the results are discussed.

Original language	English
Pages (from-to)	29-39
Number of pages	11
Journal	Journal of Molecular Spectroscopy
Volume	189
Issue number	1
DOIs	https://doi.org/10.1006/jmsp.1997.7498
Publication status	Published - 1 Jan 1998

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Spectroscopy
Physical and Theoretical Chemistry

Access to Document

10.1006/jmsp.1997.7498

Fingerprint Dive into the research topics of 'Joint Rotational Analysis of 24 Bands of the H<sub>2</sub>Se Molecule'. Together they form a unique fingerprint.

Cite this

Ulenikov, O. N., Onopenko, G. A., Hai-Lin, Zhang, J. H., Zhou, Z. Y., Zhu, Q. S., & Tolchenov, R. N. (1998). Joint Rotational Analysis of 24 Bands of the H₂Se Molecule. Journal of Molecular Spectroscopy, 189(1), 29-39. https://doi.org/10.1006/jmsp.1997.7498

@article{35a2a44d7a2b4b8088ce611c9d109aec,

title = "Joint Rotational Analysis of 24 Bands of the H2Se Molecule",

abstract = "A global fit of all currently available rotation-vibration energies has been made for 24 vibrational states of the H802Se molecule. The resulting set of 112 parameters reproduces the initial 3516 vibration-rotation energies with a mean accuracy of 10.6 × 10-3 cm-1. Using this model as a starting point, the rotational fine structure of the extremely weak local mode bands (13+; 1)/(13-; 1) and (06+; 0)/(06-; 0) could be analyzed; the results are discussed.",

author = "Ulenikov, {O. N.} and Onopenko, {G. A.} and Hai-Lin and Zhang, {Jin Hui} and Zhou, {Ze Yi} and Zhu, {Qing Shi} and Tolchenov, {R. N.}",

year = "1998",

month = jan,

day = "1",

doi = "10.1006/jmsp.1997.7498",

language = "English",

volume = "189",

pages = "29--39",

journal = "Journal of Molecular Spectroscopy",

issn = "0022-2852",

publisher = "Academic Press Inc.",

number = "1",

}

TY - JOUR

T1 - Joint Rotational Analysis of 24 Bands of the H2Se Molecule

AU - Ulenikov, O. N.

AU - Onopenko, G. A.

AU - Hai-Lin,

AU - Zhang, Jin Hui

AU - Zhou, Ze Yi

AU - Zhu, Qing Shi

AU - Tolchenov, R. N.

PY - 1998/1/1

Y1 - 1998/1/1

N2 - A global fit of all currently available rotation-vibration energies has been made for 24 vibrational states of the H802Se molecule. The resulting set of 112 parameters reproduces the initial 3516 vibration-rotation energies with a mean accuracy of 10.6 × 10-3 cm-1. Using this model as a starting point, the rotational fine structure of the extremely weak local mode bands (13+; 1)/(13-; 1) and (06+; 0)/(06-; 0) could be analyzed; the results are discussed.

AB - A global fit of all currently available rotation-vibration energies has been made for 24 vibrational states of the H802Se molecule. The resulting set of 112 parameters reproduces the initial 3516 vibration-rotation energies with a mean accuracy of 10.6 × 10-3 cm-1. Using this model as a starting point, the rotational fine structure of the extremely weak local mode bands (13+; 1)/(13-; 1) and (06+; 0)/(06-; 0) could be analyzed; the results are discussed.

UR - http://www.scopus.com/inward/record.url?scp=0002643410&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0002643410&partnerID=8YFLogxK

U2 - 10.1006/jmsp.1997.7498

DO - 10.1006/jmsp.1997.7498

M3 - Article

AN - SCOPUS:0002643410

VL - 189

SP - 29

EP - 39

JO - Journal of Molecular Spectroscopy

JF - Journal of Molecular Spectroscopy

SN - 0022-2852

IS - 1

ER -