Abstract
A global fit of all currently available rotation-vibration energies has been made for 24 vibrational states of the H802Se molecule. The resulting set of 112 parameters reproduces the initial 3516 vibration-rotation energies with a mean accuracy of 10.6 × 10-3 cm-1. Using this model as a starting point, the rotational fine structure of the extremely weak local mode bands (13+; 1)/(13-; 1) and (06+; 0)/(06-; 0) could be analyzed; the results are discussed.
Original language | English |
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Pages (from-to) | 29-39 |
Number of pages | 11 |
Journal | Journal of Molecular Spectroscopy |
Volume | 189 |
Issue number | 1 |
DOIs | |
Publication status | Published - 1 Jan 1998 |
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
- Spectroscopy
- Physical and Theoretical Chemistry