Abstract
A global fit of all currently available rotation-vibration energies has been made for 24 vibrational states of the H802Se molecule. The resulting set of 112 parameters reproduces the initial 3516 vibration-rotation energies with a mean accuracy of 10.6 × 10-3 cm-1. Using this model as a starting point, the rotational fine structure of the extremely weak local mode bands (13+; 1)/(13-; 1) and (06+; 0)/(06-; 0) could be analyzed; the results are discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 29-39 |
| Number of pages | 11 |
| Journal | Journal of Molecular Spectroscopy |
| Volume | 189 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 1 Jan 1998 |
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ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
- Spectroscopy
- Physical and Theoretical Chemistry
Cite this
Joint Rotational Analysis of 24 Bands of the H2Se Molecule. / Ulenikov, O. N.; Onopenko, G. A.; Hai-Lin; Zhang, Jin Hui; Zhou, Ze Yi; Zhu, Qing Shi; Tolchenov, R. N.
In: Journal of Molecular Spectroscopy, Vol. 189, No. 1, 01.01.1998, p. 29-39.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Joint Rotational Analysis of 24 Bands of the H2Se Molecule
AU - Ulenikov, O. N.
AU - Onopenko, G. A.
AU - Hai-Lin,
AU - Zhang, Jin Hui
AU - Zhou, Ze Yi
AU - Zhu, Qing Shi
AU - Tolchenov, R. N.
PY - 1998/1/1
Y1 - 1998/1/1
N2 - A global fit of all currently available rotation-vibration energies has been made for 24 vibrational states of the H802Se molecule. The resulting set of 112 parameters reproduces the initial 3516 vibration-rotation energies with a mean accuracy of 10.6 × 10-3 cm-1. Using this model as a starting point, the rotational fine structure of the extremely weak local mode bands (13+; 1)/(13-; 1) and (06+; 0)/(06-; 0) could be analyzed; the results are discussed.
AB - A global fit of all currently available rotation-vibration energies has been made for 24 vibrational states of the H802Se molecule. The resulting set of 112 parameters reproduces the initial 3516 vibration-rotation energies with a mean accuracy of 10.6 × 10-3 cm-1. Using this model as a starting point, the rotational fine structure of the extremely weak local mode bands (13+; 1)/(13-; 1) and (06+; 0)/(06-; 0) could be analyzed; the results are discussed.
UR - http://www.scopus.com/inward/record.url?scp=0002643410&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0002643410&partnerID=8YFLogxK
U2 - 10.1006/jmsp.1997.7498
DO - 10.1006/jmsp.1997.7498
M3 - Article
VL - 189
SP - 29
EP - 39
JO - Journal of Molecular Spectroscopy
JF - Journal of Molecular Spectroscopy
SN - 0022-2852
IS - 1
ER -