IR spectroscopic method of observing the polymerization kinetics of 9-vinylcarbazole

A. A. Lyapkov, V. M. Sutyagin, V. P. Lopatinskii, Z. G. Kubits

Research School of Chemistry & Applied Biomedical Sciences

Research output: Contribution to journal › Article

Abstract

It is shown that the ratio of the optical density of the absorption band for the stretching vibrations of the vinyl bonds in the IR spectrum of 9-vinylcarbazole to the optical density of the band for the CC vibration bonds is linearly related to the mole fraction of 9-carbazole in its mixture with poly-9-vinyl carbazole. This relation is used to study the kinetics of polymerization of 9-vinyl carbazole in 1,2-dichloroethane solution under the action of diethylaluminium chloride.

Original language	English
Pages (from-to)	2939-2942
Number of pages	4
Journal	Polymer Science U.S.S.R.
Volume	29
Issue number	12
DOIs	https://doi.org/10.1016/0032-3950(87)90217-6
Publication status	Published - 1987

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Lyapkov, A. A., Sutyagin, V. M., Lopatinskii, V. P., & Kubits, Z. G. (1987). IR spectroscopic method of observing the polymerization kinetics of 9-vinylcarbazole. Polymer Science U.S.S.R., 29(12), 2939-2942. https://doi.org/10.1016/0032-3950(87)90217-6

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abstract = "It is shown that the ratio of the optical density of the absorption band for the stretching vibrations of the vinyl bonds in the IR spectrum of 9-vinylcarbazole to the optical density of the band for the CC vibration bonds is linearly related to the mole fraction of 9-carbazole in its mixture with poly-9-vinyl carbazole. This relation is used to study the kinetics of polymerization of 9-vinyl carbazole in 1,2-dichloroethane solution under the action of diethylaluminium chloride.",

author = "Lyapkov, {A. A.} and Sutyagin, {V. M.} and Lopatinskii, {V. P.} and Kubits, {Z. G.}",

year = "1987",

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T1 - IR spectroscopic method of observing the polymerization kinetics of 9-vinylcarbazole

AU - Lyapkov, A. A.

AU - Sutyagin, V. M.

AU - Lopatinskii, V. P.

AU - Kubits, Z. G.

PY - 1987

Y1 - 1987

N2 - It is shown that the ratio of the optical density of the absorption band for the stretching vibrations of the vinyl bonds in the IR spectrum of 9-vinylcarbazole to the optical density of the band for the CC vibration bonds is linearly related to the mole fraction of 9-carbazole in its mixture with poly-9-vinyl carbazole. This relation is used to study the kinetics of polymerization of 9-vinyl carbazole in 1,2-dichloroethane solution under the action of diethylaluminium chloride.

AB - It is shown that the ratio of the optical density of the absorption band for the stretching vibrations of the vinyl bonds in the IR spectrum of 9-vinylcarbazole to the optical density of the band for the CC vibration bonds is linearly related to the mole fraction of 9-carbazole in its mixture with poly-9-vinyl carbazole. This relation is used to study the kinetics of polymerization of 9-vinyl carbazole in 1,2-dichloroethane solution under the action of diethylaluminium chloride.

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DO - 10.1016/0032-3950(87)90217-6

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EP - 2942

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JF - Polymer science USSR

SN - 0032-3950

IS - 12

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10.1016/0032-3950(87)90217-6