Iodonium salts in organic synthesis

Mekhman S. Yusubov, Andrey V. Maskaev, Viktor Vladimirovich Zhdankin

Research School of Chemistry & Applied Biomedical Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

This review summarizes the chemistry of iodonium salts with emphasis of their synthetic applications. The preparation and reactions of diaryliodonium, alkenyl(aryl)iodonium, alkynyl(aryl)iodonium, and alkyl(aryl)iodonium salts are overviewed. Application of these reagents allows mild and highly selective arylations, alkenylations, alkynylations, and alkylations of various organic and inorganic substrates in a facile and environmentally friendly manner.

Original language	English
Pages (from-to)	370-409
Number of pages	40
Journal	Arkivoc
Volume	2011
Issue number	1
DOIs	https://doi.org/10.3998/ark.5550190.0012.107
Publication status	Published - 23 Sep 2011

Keywords

Alkenyl(aryl)iodonium
Alkyl(aryl)iodonium salts
Alkynyl(aryl)iodonium
Diaryliodonium
Hypervalent iodine

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.3998/ark.5550190.0012.107

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abstract = "This review summarizes the chemistry of iodonium salts with emphasis of their synthetic applications. The preparation and reactions of diaryliodonium, alkenyl(aryl)iodonium, alkynyl(aryl)iodonium, and alkyl(aryl)iodonium salts are overviewed. Application of these reagents allows mild and highly selective arylations, alkenylations, alkynylations, and alkylations of various organic and inorganic substrates in a facile and environmentally friendly manner.",

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AB - This review summarizes the chemistry of iodonium salts with emphasis of their synthetic applications. The preparation and reactions of diaryliodonium, alkenyl(aryl)iodonium, alkynyl(aryl)iodonium, and alkyl(aryl)iodonium salts are overviewed. Application of these reagents allows mild and highly selective arylations, alkenylations, alkynylations, and alkylations of various organic and inorganic substrates in a facile and environmentally friendly manner.

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KW - Hypervalent iodine

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