Iodine(III)-Mediated/Catalyzed Cycloisomerization-Amination Sequence of N-Propargyl Carboxamides

Yuki Okamura, Daisuke Sato, Akira Yoshimura, Viktor V. Zhdankin, Akio Saito

Research output: Contribution to journal › Article

11 Citations (Scopus)

Abstract

(Diacetoxyiodo)benzene or iodine(III) catalyst, insitu generated from iodobenzene precatalyst with Oxone, promotes the cycloisomerization-amination sequence of N-propargyl carboxamides with bis(sulfonyl)imides under mild conditions, thereby leading to the direct formation of oxazoles bearing nitrogen functional groups.

Original languageEnglish
Pages (from-to)3243-3247
Number of pages5
JournalAdvanced Synthesis and Catalysis
Volume359
Issue number18
DOIs
Publication statusAccepted/In press - 2017

Fingerprint

Bearings (structural)
Oxazoles
Imides
Amination
Benzene
Iodine
Functional groups
Nitrogen
Catalysts
iodobenzene
N-propargyl
potassium peroxymonosulfuric acid

Keywords

  • Amides
  • Amination
  • Cycloisomerization
  • Iodine
  • Oxazoles

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

Cite this

Iodine(III)-Mediated/Catalyzed Cycloisomerization-Amination Sequence of N-Propargyl Carboxamides. / Okamura, Yuki; Sato, Daisuke; Yoshimura, Akira; Zhdankin, Viktor V.; Saito, Akio.

In: Advanced Synthesis and Catalysis, Vol. 359, No. 18, 2017, p. 3243-3247.

Research output: Contribution to journal › Article

Okamura, Y, Sato, D, Yoshimura, A, Zhdankin, VV & Saito, A 2017, 'Iodine(III)-Mediated/Catalyzed Cycloisomerization-Amination Sequence of N-Propargyl Carboxamides', Advanced Synthesis and Catalysis, vol. 359, no. 18, pp. 3243-3247. https://doi.org/10.1002/adsc.201700587
Okamura Y, Sato D, Yoshimura A, Zhdankin VV, Saito A. Iodine(III)-Mediated/Catalyzed Cycloisomerization-Amination Sequence of N-Propargyl Carboxamides. Advanced Synthesis and Catalysis. 2017;359(18):3243-3247. https://doi.org/10.1002/adsc.201700587
Okamura, Yuki ; Sato, Daisuke ; Yoshimura, Akira ; Zhdankin, Viktor V. ; Saito, Akio. / Iodine(III)-Mediated/Catalyzed Cycloisomerization-Amination Sequence of N-Propargyl Carboxamides. In: Advanced Synthesis and Catalysis. 2017 ; Vol. 359, No. 18. pp. 3243-3247.
@article{b893d1b30b8e499297e5d23a5743393a,
title = "Iodine(III)-Mediated/Catalyzed Cycloisomerization-Amination Sequence of N-Propargyl Carboxamides",
abstract = "(Diacetoxyiodo)benzene or iodine(III) catalyst, insitu generated from iodobenzene precatalyst with Oxone, promotes the cycloisomerization-amination sequence of N-propargyl carboxamides with bis(sulfonyl)imides under mild conditions, thereby leading to the direct formation of oxazoles bearing nitrogen functional groups.",
keywords = "Amides, Amination, Cycloisomerization, Iodine, Oxazoles",
author = "Yuki Okamura and Daisuke Sato and Akira Yoshimura and Zhdankin, {Viktor V.} and Akio Saito",
year = "2017",
doi = "10.1002/adsc.201700587",
language = "English",
volume = "359",
pages = "3243--3247",
journal = "Journal fur Praktische Chemie",
issn = "1436-9966",
publisher = "Wiley-VCH Verlag",
number = "18",

}

TY - JOUR

T1 - Iodine(III)-Mediated/Catalyzed Cycloisomerization-Amination Sequence of N-Propargyl Carboxamides

AU - Okamura, Yuki

AU - Sato, Daisuke

AU - Yoshimura, Akira

AU - Zhdankin, Viktor V.

AU - Saito, Akio

PY - 2017

Y1 - 2017

N2 - (Diacetoxyiodo)benzene or iodine(III) catalyst, insitu generated from iodobenzene precatalyst with Oxone, promotes the cycloisomerization-amination sequence of N-propargyl carboxamides with bis(sulfonyl)imides under mild conditions, thereby leading to the direct formation of oxazoles bearing nitrogen functional groups.

AB - (Diacetoxyiodo)benzene or iodine(III) catalyst, insitu generated from iodobenzene precatalyst with Oxone, promotes the cycloisomerization-amination sequence of N-propargyl carboxamides with bis(sulfonyl)imides under mild conditions, thereby leading to the direct formation of oxazoles bearing nitrogen functional groups.

KW - Amides

KW - Amination

KW - Cycloisomerization

KW - Iodine

KW - Oxazoles

UR - http://www.scopus.com/inward/record.url?scp=85026425598&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85026425598&partnerID=8YFLogxK

U2 - 10.1002/adsc.201700587

DO - 10.1002/adsc.201700587

M3 - Article

AN - SCOPUS:85026425598

VL - 359

SP - 3243

EP - 3247

JO - Journal fur Praktische Chemie

JF - Journal fur Praktische Chemie

SN - 1436-9966

IS - 18

ER -

Access to Document