Abstract
(Diacetoxyiodo)benzene or iodine(III) catalyst, insitu generated from iodobenzene precatalyst with Oxone, promotes the cycloisomerization-amination sequence of N-propargyl carboxamides with bis(sulfonyl)imides under mild conditions, thereby leading to the direct formation of oxazoles bearing nitrogen functional groups.
| Original language | English |
|---|---|
| Pages (from-to) | 3243-3247 |
| Number of pages | 5 |
| Journal | Advanced Synthesis and Catalysis |
| Volume | 359 |
| Issue number | 18 |
| DOIs | |
| Publication status | Accepted/In press - 2017 |
Keywords
- Amides
- Amination
- Cycloisomerization
- Iodine
- Oxazoles
ASJC Scopus subject areas
- Catalysis
- Organic Chemistry
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Cite this
Okamura, Y., Sato, D., Yoshimura, A., Zhdankin, V. V., & Saito, A. (Accepted/In press). Iodine(III)-Mediated/Catalyzed Cycloisomerization-Amination Sequence of N-Propargyl Carboxamides. Advanced Synthesis and Catalysis, 359(18), 3243-3247. https://doi.org/10.1002/adsc.201700587