Iodine Monoacetate for Efficient Oxyiodinations of Alkenes and Alkynes

Abstract

A novel and inexpensive, environmentally friendly method for the preparation of iodine monoacetate is presented using iodine and Oxone in acetic acid/acetic anhydride. The reagent is used in a highly efficient approach for the regio- and diastereoselective iodoacetoxylation of alkenes and alkynes in a simple one-pot process.

Original language	English
Article number	st-2017-r0670-c
Pages (from-to)	415-418
Number of pages	4
Journal	Synlett
Volume	29
Issue number	4
DOIs	https://doi.org/10.1055/s-0036-1589119
Publication status	Accepted/In press - 27 Sep 2017
Externally published	Yes

Keywords

alkenes
alkynes
iodine
iodine(I)acetate
oxyiodination

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.1055/s-0036-1589119

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title = "Iodine Monoacetate for Efficient Oxyiodinations of Alkenes and Alkynes",

abstract = "A novel and inexpensive, environmentally friendly method for the preparation of iodine monoacetate is presented using iodine and Oxone in acetic acid/acetic anhydride. The reagent is used in a highly efficient approach for the regio- and diastereoselective iodoacetoxylation of alkenes and alkynes in a simple one-pot process.",

keywords = "alkenes, alkynes, iodine, iodine(I)acetate, oxyiodination",

author = "Tobias Hokamp and Storm, {Alena Therese} and Mekhman Yusubov and Thomas Wirth",

year = "2017",

month = sep,

day = "27",

doi = "10.1055/s-0036-1589119",

language = "English",

volume = "29",

pages = "415--418",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

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T1 - Iodine Monoacetate for Efficient Oxyiodinations of Alkenes and Alkynes

AU - Hokamp, Tobias

AU - Storm, Alena Therese

AU - Yusubov, Mekhman

AU - Wirth, Thomas

PY - 2017/9/27

Y1 - 2017/9/27

N2 - A novel and inexpensive, environmentally friendly method for the preparation of iodine monoacetate is presented using iodine and Oxone in acetic acid/acetic anhydride. The reagent is used in a highly efficient approach for the regio- and diastereoselective iodoacetoxylation of alkenes and alkynes in a simple one-pot process.

AB - A novel and inexpensive, environmentally friendly method for the preparation of iodine monoacetate is presented using iodine and Oxone in acetic acid/acetic anhydride. The reagent is used in a highly efficient approach for the regio- and diastereoselective iodoacetoxylation of alkenes and alkynes in a simple one-pot process.

KW - alkenes

KW - alkynes

KW - iodine

KW - iodine(I)acetate

KW - oxyiodination

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U2 - 10.1055/s-0036-1589119

DO - 10.1055/s-0036-1589119

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EP - 418

JO - Synlett

JF - Synlett

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