Iodine Monoacetate for Efficient Oxyiodinations of Alkenes and Alkynes

Tobias Hokamp, Alena Therese Storm, Mekhman Yusubov, Thomas Wirth

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

A novel and inexpensive, environmentally friendly method for the preparation of iodine monoacetate is presented using iodine and Oxone in acetic acid/acetic anhydride. The reagent is used in a highly efficient approach for the regio- and diastereoselective iodo­acetoxylation of alkenes and alkynes in a simple one-pot process.

Original languageEnglish
Article numberst-2017-r0670-c
Pages (from-to)415-418
Number of pages4
JournalSynlett
Volume29
Issue number4
DOIs
Publication statusAccepted/In press - 27 Sep 2017
Externally publishedYes

Fingerprint

Alkynes
Alkenes
Iodine
Acetic Acid
potassium peroxymonosulfuric acid
acetic anhydride

Keywords

  • alkenes
  • alkynes
  • iodine
  • iodine(I)acetate
  • oxyiodination

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Hokamp, T., Storm, A. T., Yusubov, M., & Wirth, T. (Accepted/In press). Iodine Monoacetate for Efficient Oxyiodinations of Alkenes and Alkynes. Synlett, 29(4), 415-418. [st-2017-r0670-c]. https://doi.org/10.1055/s-0036-1589119

Iodine Monoacetate for Efficient Oxyiodinations of Alkenes and Alkynes. / Hokamp, Tobias; Storm, Alena Therese; Yusubov, Mekhman; Wirth, Thomas.

In: Synlett, Vol. 29, No. 4, st-2017-r0670-c, 27.09.2017, p. 415-418.

Research output: Contribution to journalArticle

Hokamp, T, Storm, AT, Yusubov, M & Wirth, T 2017, 'Iodine Monoacetate for Efficient Oxyiodinations of Alkenes and Alkynes', Synlett, vol. 29, no. 4, st-2017-r0670-c, pp. 415-418. https://doi.org/10.1055/s-0036-1589119
Hokamp, Tobias ; Storm, Alena Therese ; Yusubov, Mekhman ; Wirth, Thomas. / Iodine Monoacetate for Efficient Oxyiodinations of Alkenes and Alkynes. In: Synlett. 2017 ; Vol. 29, No. 4. pp. 415-418.
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