Abstract
A novel and inexpensive, environmentally friendly method for the preparation of iodine monoacetate is presented using iodine and Oxone in acetic acid/acetic anhydride. The reagent is used in a highly efficient approach for the regio- and diastereoselective iodoacetoxylation of alkenes and alkynes in a simple one-pot process.
| Original language | English |
|---|---|
| Article number | st-2017-r0670-c |
| Pages (from-to) | 415-418 |
| Number of pages | 4 |
| Journal | Synlett |
| Volume | 29 |
| Issue number | 4 |
| DOIs | |
| Publication status | Accepted/In press - 27 Sep 2017 |
| Externally published | Yes |
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Keywords
- alkenes
- alkynes
- iodine
- iodine(I)acetate
- oxyiodination
ASJC Scopus subject areas
- Organic Chemistry
Cite this
Iodine Monoacetate for Efficient Oxyiodinations of Alkenes and Alkynes. / Hokamp, Tobias; Storm, Alena Therese; Yusubov, Mekhman; Wirth, Thomas.
In: Synlett, Vol. 29, No. 4, st-2017-r0670-c, 27.09.2017, p. 415-418.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Iodine Monoacetate for Efficient Oxyiodinations of Alkenes and Alkynes
AU - Hokamp, Tobias
AU - Storm, Alena Therese
AU - Yusubov, Mekhman
AU - Wirth, Thomas
PY - 2017/9/27
Y1 - 2017/9/27
N2 - A novel and inexpensive, environmentally friendly method for the preparation of iodine monoacetate is presented using iodine and Oxone in acetic acid/acetic anhydride. The reagent is used in a highly efficient approach for the regio- and diastereoselective iodoacetoxylation of alkenes and alkynes in a simple one-pot process.
AB - A novel and inexpensive, environmentally friendly method for the preparation of iodine monoacetate is presented using iodine and Oxone in acetic acid/acetic anhydride. The reagent is used in a highly efficient approach for the regio- and diastereoselective iodoacetoxylation of alkenes and alkynes in a simple one-pot process.
KW - alkenes
KW - alkynes
KW - iodine
KW - iodine(I)acetate
KW - oxyiodination
UR - http://www.scopus.com/inward/record.url?scp=85031893963&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85031893963&partnerID=8YFLogxK
U2 - 10.1055/s-0036-1589119
DO - 10.1055/s-0036-1589119
M3 - Article
VL - 29
SP - 415
EP - 418
JO - Synlett
JF - Synlett
SN - 0936-5214
IS - 4
M1 - st-2017-r0670-c
ER -