Iodine Monoacetate for Efficient Oxyiodinations of Alkenes and Alkynes

Abstract

A novel and inexpensive, environmentally friendly method for the preparation of iodine monoacetate is presented using iodine and Oxone in acetic acid/acetic anhydride. The reagent is used in a highly efficient approach for the regio- and diastereoselective iodoacetoxylation of alkenes and alkynes in a simple one-pot process.

Original language	English
Article number	st-2017-r0670-c
Pages (from-to)	415-418
Number of pages	4
Journal	Synlett
Volume	29
Issue number	4
DOIs	https://doi.org/10.1055/s-0036-1589119
Publication status	Accepted/In press - 27 Sep 2017
Externally published	Yes

Keywords

alkenes
alkynes
iodine
iodine(I)acetate
oxyiodination

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.1055/s-0036-1589119

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Hokamp, T., Storm, A. T., Yusubov, M., & Wirth, T. (Accepted/In press). Iodine Monoacetate for Efficient Oxyiodinations of Alkenes and Alkynes. Synlett, 29(4), 415-418. [st-2017-r0670-c]. https://doi.org/10.1055/s-0036-1589119

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author = "Tobias Hokamp and Storm, {Alena Therese} and Mekhman Yusubov and Thomas Wirth",

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AU - Yusubov, Mekhman

AU - Wirth, Thomas

PY - 2017/9/27

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KW - alkenes

KW - alkynes

KW - iodine

KW - iodine(I)acetate

KW - oxyiodination

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