Iodination of nitroarenes by a superactive reagent based on iodine chloride

V. K. Chaikovskii, T. S. Kharlova, V. D. Filimnov

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Iodine chloride reacts with Ag2SO3 in H2SO4 to give a new superelectrophilic reagent capable of iodinating nitrobenzene, halogenated nitrobenzenes, nitrotoluenes, and aromatic compounds with two nitro groups in the ring. Mononitroarenes are easily iodinated at 0-20°C, while dinitroarenes require heating to 100-170°C.

Original languageEnglish
Pages (from-to)1291-1294
Number of pages4
JournalRussian Chemical Bulletin
Volume48
Issue number7
DOIs
Publication statusPublished - Jul 1999

Fingerprint

Nitrobenzenes
Aromatic compounds
Heating
iodine monochloride
nitrobenzene

Keywords

  • electrophilic iodine
  • iodination
  • iodine chloride
  • nitroarenes

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Iodination of nitroarenes by a superactive reagent based on iodine chloride. / Chaikovskii, V. K.; Kharlova, T. S.; Filimnov, V. D.

In: Russian Chemical Bulletin, Vol. 48, No. 7, 07.1999, p. 1291-1294.

Research output: Contribution to journalArticle

Chaikovskii, V. K. ; Kharlova, T. S. ; Filimnov, V. D. / Iodination of nitroarenes by a superactive reagent based on iodine chloride. In: Russian Chemical Bulletin. 1999 ; Vol. 48, No. 7. pp. 1291-1294.
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