Abstract
Iodine chloride reacts with Ag2SO3 in H2SO4 to give a new superelectrophilic reagent capable of iodinating nitrobenzene, halogenated nitrobenzenes, nitrotoluenes, and aromatic compounds with two nitro groups in the ring. Mononitroarenes are easily iodinated at 0-20°C, while dinitroarenes require heating to 100-170°C.
| Original language | English |
|---|---|
| Pages (from-to) | 1291-1294 |
| Number of pages | 4 |
| Journal | Russian Chemical Bulletin |
| Volume | 48 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - Jul 1999 |
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Keywords
- electrophilic iodine
- iodination
- iodine chloride
- nitroarenes
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Chaikovskii, V. K., Kharlova, T. S., & Filimnov, V. D. (1999). Iodination of nitroarenes by a superactive reagent based on iodine chloride. Russian Chemical Bulletin, 48(7), 1291-1294. https://doi.org/10.1007/BF02495292