Iodination of nitroarenes by a superactive reagent based on iodine chloride

V. K. Chaikovskii, T. S. Kharlova, V. D. Filimnov

The Kizhner Research Center

Research output: Contribution to journal › Article › peer-review

Abstract

Iodine chloride reacts with Ag₂SO₃ in H₂SO₄ to give a new superelectrophilic reagent capable of iodinating nitrobenzene, halogenated nitrobenzenes, nitrotoluenes, and aromatic compounds with two nitro groups in the ring. Mononitroarenes are easily iodinated at 0-20°C, while dinitroarenes require heating to 100-170°C.

Original language	English
Pages (from-to)	1291-1294
Number of pages	4
Journal	Russian Chemical Bulletin
Volume	48
Issue number	7
DOIs	https://doi.org/10.1007/BF02495292
Publication status	Published - Jul 1999

Keywords

electrophilic iodine
iodination
iodine chloride
nitroarenes

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1007/BF02495292

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title = "Iodination of nitroarenes by a superactive reagent based on iodine chloride",

abstract = "Iodine chloride reacts with Ag2SO3 in H2SO4 to give a new superelectrophilic reagent capable of iodinating nitrobenzene, halogenated nitrobenzenes, nitrotoluenes, and aromatic compounds with two nitro groups in the ring. Mononitroarenes are easily iodinated at 0-20°C, while dinitroarenes require heating to 100-170°C.",

keywords = "electrophilic iodine, iodination, iodine chloride, nitroarenes",

author = "Chaikovskii, {V. K.} and Kharlova, {T. S.} and Filimnov, {V. D.}",

year = "1999",

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volume = "48",

pages = "1291--1294",

journal = "Russian Chemical Bulletin",

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T1 - Iodination of nitroarenes by a superactive reagent based on iodine chloride

AU - Chaikovskii, V. K.

AU - Kharlova, T. S.

AU - Filimnov, V. D.

PY - 1999/7

Y1 - 1999/7

N2 - Iodine chloride reacts with Ag2SO3 in H2SO4 to give a new superelectrophilic reagent capable of iodinating nitrobenzene, halogenated nitrobenzenes, nitrotoluenes, and aromatic compounds with two nitro groups in the ring. Mononitroarenes are easily iodinated at 0-20°C, while dinitroarenes require heating to 100-170°C.

AB - Iodine chloride reacts with Ag2SO3 in H2SO4 to give a new superelectrophilic reagent capable of iodinating nitrobenzene, halogenated nitrobenzenes, nitrotoluenes, and aromatic compounds with two nitro groups in the ring. Mononitroarenes are easily iodinated at 0-20°C, while dinitroarenes require heating to 100-170°C.

KW - electrophilic iodine

KW - iodination

KW - iodine chloride

KW - nitroarenes

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