TY - JOUR
T1 - Iodination and chlorination of aromatic polycyclic hydrocarbons with iodine monochloride in aqueous sulfuric acid
AU - Chaikovskii, V. K.
AU - Filimonov, V. D.
PY - 2001/8/1
Y1 - 2001/8/1
N2 - Polycyclic aromatic hydrocarbons when treated with iodine monochloride in water solutions of sulfuric acid afford iodo-and chloroderivatives. Biphenyl, fluorene, acenaphthene, 1-nitronaphthalene undergo iodination. Naphthalene furnishes a mixture of iodo-and chloroderivatives, prevailing the latter. Anthracene and phenanthrene provide only chlorinated products. The iodine monochloride in the sulfuric acid is a stronger iodinating agent than in acetonitrile.
AB - Polycyclic aromatic hydrocarbons when treated with iodine monochloride in water solutions of sulfuric acid afford iodo-and chloroderivatives. Biphenyl, fluorene, acenaphthene, 1-nitronaphthalene undergo iodination. Naphthalene furnishes a mixture of iodo-and chloroderivatives, prevailing the latter. Anthracene and phenanthrene provide only chlorinated products. The iodine monochloride in the sulfuric acid is a stronger iodinating agent than in acetonitrile.
UR - http://www.scopus.com/inward/record.url?scp=0035732503&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0035732503&partnerID=8YFLogxK
U2 - 10.1023/A:1013192314771
DO - 10.1023/A:1013192314771
M3 - Article
AN - SCOPUS:0035732503
VL - 37
SP - 1130
EP - 1133
JO - Russian Journal of Organic Chemistry
JF - Russian Journal of Organic Chemistry
SN - 1070-4280
IS - 8
ER -