Abstract
Polycyclic aromatic hydrocarbons when treated with iodine monochloride in water solutions of sulfuric acid afford iodo-and chloroderivatives. Biphenyl, fluorene, acenaphthene, 1-nitronaphthalene undergo iodination. Naphthalene furnishes a mixture of iodo-and chloroderivatives, prevailing the latter. Anthracene and phenanthrene provide only chlorinated products. The iodine monochloride in the sulfuric acid is a stronger iodinating agent than in acetonitrile.
| Original language | English |
|---|---|
| Pages (from-to) | 1130-1133 |
| Number of pages | 4 |
| Journal | Russian Journal of Organic Chemistry |
| Volume | 37 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - 1 Aug 2001 |
Fingerprint
ASJC Scopus subject areas
- Organic Chemistry
Cite this
Iodination and chlorination of aromatic polycyclic hydrocarbons with iodine monochloride in aqueous sulfuric acid. / Chaikovskii, V. K.; Filimonov, V. D.
In: Russian Journal of Organic Chemistry, Vol. 37, No. 8, 01.08.2001, p. 1130-1133.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Iodination and chlorination of aromatic polycyclic hydrocarbons with iodine monochloride in aqueous sulfuric acid
AU - Chaikovskii, V. K.
AU - Filimonov, V. D.
PY - 2001/8/1
Y1 - 2001/8/1
N2 - Polycyclic aromatic hydrocarbons when treated with iodine monochloride in water solutions of sulfuric acid afford iodo-and chloroderivatives. Biphenyl, fluorene, acenaphthene, 1-nitronaphthalene undergo iodination. Naphthalene furnishes a mixture of iodo-and chloroderivatives, prevailing the latter. Anthracene and phenanthrene provide only chlorinated products. The iodine monochloride in the sulfuric acid is a stronger iodinating agent than in acetonitrile.
AB - Polycyclic aromatic hydrocarbons when treated with iodine monochloride in water solutions of sulfuric acid afford iodo-and chloroderivatives. Biphenyl, fluorene, acenaphthene, 1-nitronaphthalene undergo iodination. Naphthalene furnishes a mixture of iodo-and chloroderivatives, prevailing the latter. Anthracene and phenanthrene provide only chlorinated products. The iodine monochloride in the sulfuric acid is a stronger iodinating agent than in acetonitrile.
UR - http://www.scopus.com/inward/record.url?scp=0035732503&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0035732503&partnerID=8YFLogxK
U2 - 10.1023/A:1013192314771
DO - 10.1023/A:1013192314771
M3 - Article
AN - SCOPUS:0035732503
VL - 37
SP - 1130
EP - 1133
JO - Russian Journal of Organic Chemistry
JF - Russian Journal of Organic Chemistry
SN - 1070-4280
IS - 8
ER -