Investigation of the laws of ionizing radiation effect on the stability of the colloidal solutions of iron

L. R. Merinova, L. N. Shiyan, G. E. Remnev, Andrey Vladimirovich Stepanov, M. I. Kaikanov, D. A. Voyno

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

In the paper, the effect of the pulse electron radiation on the stability of the colloidal iron solutions is studied. The work is performed on the standard test solutions which correspond to the real natural and waste water regarding their chemical composition. The irradiation was performed using the pulse accelerator TEA-500 with the electron energy 500 keV and pulse duration 60 ns. The dose was calculated using the potassium nitrate recommended for measuring the dose of the pulse electron radiation. The standard test solution used for radiation contained iron, silicon and humic substances ions in the correlation 5.6:20:2.2 mg/l, respectively. The solutions were subjected to radiation within the range of 0.6-5.0 Mrad. The efficiency of radiation was estimated by the variation in iron chromaticity and concentration in the initial and irradiated solution. The decrease in iron concentration and solution chromaticity after the radiation indicates the violation of the stability of the colloidal solution and the Fe(OH)3 coagulation sludge. To explain the interaction of the radiation with the colloidal particles, the water radiolysis mechanism was considered, since the most of the ionizing radiation energy is consumed for the interaction with the water forming a large spectrum of radiolysis products. In the paper we offer the interaction mechanism of hydrated electron and the colloidal particles on the ground that the hydrated electron has a much longer life compared to H and OH radicals and is formed with a large radiation-chemical output which is equal to 3.3÷3.5 ions per 100 eV. The lifetime of the hydrated electron is 2.3*10-4 s. Besides, the size of the hydrated electron is 0.38 nm that is much less than the size of micelle and because of these factors it interacts with the micelle nucleus. According to the literature data, the mechanism of the electron transfer to the micelle nucleus is accompanied with the violation of the double electrical layer, the destruction of the micelle forming the Fe(OH)3 sludge that was observed during the electron beam irradiation of the standard test colloidal solutions. In the paper we present the results on the effect of the ion nitrate on the kinetics of the variation in iron ion color and concentration in the standard test solution.

Original languageEnglish
Title of host publicationProceedings - 2012 7th International Forum on Strategic Technology, IFOST 2012
DOIs
Publication statusPublished - 2012
Event2012 7th International Forum on Strategic Technology, IFOST 2012 - Tomsk, Russian Federation
Duration: 18 Sep 201221 Sep 2012

Other

Other2012 7th International Forum on Strategic Technology, IFOST 2012
CountryRussian Federation
CityTomsk
Period18.9.1221.9.12

Fingerprint

Radiation effects
Ionizing radiation
Iron
Radiation
Electrons
Micelles
Radiolysis
Ions
Nitrates
Irradiation
Silicon steel
Coagulation
Dosimetry
Particle accelerators
Potassium
Water
Electron beams
Wastewater
Color
Kinetics

Keywords

  • colloidal solutions
  • humic substances
  • hydrated electron
  • pulse electron

ASJC Scopus subject areas

  • Management of Technology and Innovation

Cite this

Merinova, L. R., Shiyan, L. N., Remnev, G. E., Stepanov, A. V., Kaikanov, M. I., & Voyno, D. A. (2012). Investigation of the laws of ionizing radiation effect on the stability of the colloidal solutions of iron. In Proceedings - 2012 7th International Forum on Strategic Technology, IFOST 2012 [6357492] https://doi.org/10.1109/IFOST.2012.6357492

Investigation of the laws of ionizing radiation effect on the stability of the colloidal solutions of iron. / Merinova, L. R.; Shiyan, L. N.; Remnev, G. E.; Stepanov, Andrey Vladimirovich; Kaikanov, M. I.; Voyno, D. A.

Proceedings - 2012 7th International Forum on Strategic Technology, IFOST 2012. 2012. 6357492.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Merinova, LR, Shiyan, LN, Remnev, GE, Stepanov, AV, Kaikanov, MI & Voyno, DA 2012, Investigation of the laws of ionizing radiation effect on the stability of the colloidal solutions of iron. in Proceedings - 2012 7th International Forum on Strategic Technology, IFOST 2012., 6357492, 2012 7th International Forum on Strategic Technology, IFOST 2012, Tomsk, Russian Federation, 18.9.12. https://doi.org/10.1109/IFOST.2012.6357492
Merinova LR, Shiyan LN, Remnev GE, Stepanov AV, Kaikanov MI, Voyno DA. Investigation of the laws of ionizing radiation effect on the stability of the colloidal solutions of iron. In Proceedings - 2012 7th International Forum on Strategic Technology, IFOST 2012. 2012. 6357492 https://doi.org/10.1109/IFOST.2012.6357492
Merinova, L. R. ; Shiyan, L. N. ; Remnev, G. E. ; Stepanov, Andrey Vladimirovich ; Kaikanov, M. I. ; Voyno, D. A. / Investigation of the laws of ionizing radiation effect on the stability of the colloidal solutions of iron. Proceedings - 2012 7th International Forum on Strategic Technology, IFOST 2012. 2012.
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