Investigation of the Interaction of Palladium with Potassium Tetrafluorobromate

Abstract

In this investigation, the interaction of metallic palladium with potassium tetrafluorobromate was examined in open system, the reaction products were identified using X-ray phase analysis. A thermogram of the interaction of Pd with KBrF₄ was obtained, the temperature range of the reaction (187.9-328C) and the thermal effect (431.31 J/g) were determined. It was found that the fluorination process is a multi-stage process. The solubility of the obtained K₂PdF₆ compound in nitric and hydrochloric acids was investigated. The process of extraction of palladium from nitric acid solutions with tributyl phosphate was carried out and the influence of the concentration of palladium and the acidity of the initial solution on the distribution coefficient was investigated.

Original language	English
Article number	012021
Journal	Journal of Physics: Conference Series
Volume	1443
Issue number	1
DOIs	https://doi.org/10.1088/1742-6596/1443/1/012021
Publication status	Published - 7 Jan 2020
Event	International Conference for Young Scientists on Issues of Physics and Technology in Science, Power Industry and Medicine 2019, IPTSPIM 2019 - Tomsk, Russian Federation Duration: 30 Sep 2019 → 5 Oct 2019

ASJC Scopus subject areas

Physics and Astronomy(all)

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title = "Investigation of the Interaction of Palladium with Potassium Tetrafluorobromate",

abstract = "In this investigation, the interaction of metallic palladium with potassium tetrafluorobromate was examined in open system, the reaction products were identified using X-ray phase analysis. A thermogram of the interaction of Pd with KBrF4 was obtained, the temperature range of the reaction (187.9-328C) and the thermal effect (431.31 J/g) were determined. It was found that the fluorination process is a multi-stage process. The solubility of the obtained K2PdF6 compound in nitric and hydrochloric acids was investigated. The process of extraction of palladium from nitric acid solutions with tributyl phosphate was carried out and the influence of the concentration of palladium and the acidity of the initial solution on the distribution coefficient was investigated.",

author = "Mamatova, {A. M.} and Shakimova, {A. M.} and Merkel, {K. I.} and Malin, {A. V.} and Ostvald, {R. V.}",

year = "2020",

month = jan,

day = "7",

doi = "10.1088/1742-6596/1443/1/012021",

language = "English",

volume = "1443",

journal = "Journal of Physics: Conference Series",

issn = "1742-6588",

publisher = "IOP Publishing Ltd.",

number = "1",

note = "International Conference for Young Scientists on Issues of Physics and Technology in Science, Power Industry and Medicine 2019, IPTSPIM 2019 ; Conference date: 30-09-2019 Through 05-10-2019",

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TY - JOUR

T1 - Investigation of the Interaction of Palladium with Potassium Tetrafluorobromate

AU - Mamatova, A. M.

AU - Shakimova, A. M.

AU - Merkel, K. I.

AU - Malin, A. V.

AU - Ostvald, R. V.

PY - 2020/1/7

Y1 - 2020/1/7

N2 - In this investigation, the interaction of metallic palladium with potassium tetrafluorobromate was examined in open system, the reaction products were identified using X-ray phase analysis. A thermogram of the interaction of Pd with KBrF4 was obtained, the temperature range of the reaction (187.9-328C) and the thermal effect (431.31 J/g) were determined. It was found that the fluorination process is a multi-stage process. The solubility of the obtained K2PdF6 compound in nitric and hydrochloric acids was investigated. The process of extraction of palladium from nitric acid solutions with tributyl phosphate was carried out and the influence of the concentration of palladium and the acidity of the initial solution on the distribution coefficient was investigated.

AB - In this investigation, the interaction of metallic palladium with potassium tetrafluorobromate was examined in open system, the reaction products were identified using X-ray phase analysis. A thermogram of the interaction of Pd with KBrF4 was obtained, the temperature range of the reaction (187.9-328C) and the thermal effect (431.31 J/g) were determined. It was found that the fluorination process is a multi-stage process. The solubility of the obtained K2PdF6 compound in nitric and hydrochloric acids was investigated. The process of extraction of palladium from nitric acid solutions with tributyl phosphate was carried out and the influence of the concentration of palladium and the acidity of the initial solution on the distribution coefficient was investigated.

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U2 - 10.1088/1742-6596/1443/1/012021

DO - 10.1088/1742-6596/1443/1/012021

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VL - 1443

JO - Journal of Physics: Conference Series

JF - Journal of Physics: Conference Series

SN - 1742-6588

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M1 - 012021

T2 - International Conference for Young Scientists on Issues of Physics and Technology in Science, Power Industry and Medicine 2019, IPTSPIM 2019

Y2 - 30 September 2019 through 5 October 2019

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