Abstract
The electronic structure of SbCl5L complexes has been analyzed on the basis of the fluorescence spectra of the sulfur and chlorine atoms as well as quantum chemical XαDV and PM3 calculations. The results have been compared with the corresponding data for SnCl4L2 and TiCl4L2 complexes. An increase in electron density on the chlorine atoms accompanied by a decrease on the central metal atom has been observed for the complexes arranged according to their stability. The arrangement of Sn, Sb, and Ti complexes with dimethyl sulfide according to their increasing stability is in disagreement with the order of the complexes with respect to electron density on the sulfur atom.
| Original language | English |
|---|---|
| Pages (from-to) | 215-222 |
| Number of pages | 8 |
| Journal | Journal of Molecular Structure |
| Volume | 324 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - 18 Aug 1994 |
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ASJC Scopus subject areas
- Structural Biology
- Organic Chemistry
- Physical and Theoretical Chemistry
- Spectroscopy
- Materials Science (miscellaneous)
- Atomic and Molecular Physics, and Optics
Cite this
Investigation of the electronic structure of SnCl4L2, TiCl4L2 and SbCl5L complexes by X-ray fluorescence spectroscopy. / Poleshchuk, O. Kh; Nogaj, B.; Kasprzak, J.; Koput, J.; Dolenko, G. N.; Elin, V. P.; Ivanovskii, A. L.
In: Journal of Molecular Structure, Vol. 324, No. 3, 18.08.1994, p. 215-222.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Investigation of the electronic structure of SnCl4L2, TiCl4L2 and SbCl5L complexes by X-ray fluorescence spectroscopy
AU - Poleshchuk, O. Kh
AU - Nogaj, B.
AU - Kasprzak, J.
AU - Koput, J.
AU - Dolenko, G. N.
AU - Elin, V. P.
AU - Ivanovskii, A. L.
PY - 1994/8/18
Y1 - 1994/8/18
N2 - The electronic structure of SbCl5L complexes has been analyzed on the basis of the fluorescence spectra of the sulfur and chlorine atoms as well as quantum chemical XαDV and PM3 calculations. The results have been compared with the corresponding data for SnCl4L2 and TiCl4L2 complexes. An increase in electron density on the chlorine atoms accompanied by a decrease on the central metal atom has been observed for the complexes arranged according to their stability. The arrangement of Sn, Sb, and Ti complexes with dimethyl sulfide according to their increasing stability is in disagreement with the order of the complexes with respect to electron density on the sulfur atom.
AB - The electronic structure of SbCl5L complexes has been analyzed on the basis of the fluorescence spectra of the sulfur and chlorine atoms as well as quantum chemical XαDV and PM3 calculations. The results have been compared with the corresponding data for SnCl4L2 and TiCl4L2 complexes. An increase in electron density on the chlorine atoms accompanied by a decrease on the central metal atom has been observed for the complexes arranged according to their stability. The arrangement of Sn, Sb, and Ti complexes with dimethyl sulfide according to their increasing stability is in disagreement with the order of the complexes with respect to electron density on the sulfur atom.
UR - http://www.scopus.com/inward/record.url?scp=0001362732&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0001362732&partnerID=8YFLogxK
U2 - 10.1016/0022-2860(94)08316-9
DO - 10.1016/0022-2860(94)08316-9
M3 - Article
AN - SCOPUS:0001362732
VL - 324
SP - 215
EP - 222
JO - Journal of Molecular Structure
JF - Journal of Molecular Structure
SN - 0022-2860
IS - 3
ER -