Investigation of the electronic structure of SnCl4L2, TiCl4L2 and SbCl5L complexes by X-ray fluorescence spectroscopy

O. Kh Poleshchuk, B. Nogaj, J. Kasprzak, J. Koput, G. N. Dolenko, V. P. Elin, A. L. Ivanovskii

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    Abstract

    The electronic structure of SbCl5L complexes has been analyzed on the basis of the fluorescence spectra of the sulfur and chlorine atoms as well as quantum chemical XαDV and PM3 calculations. The results have been compared with the corresponding data for SnCl4L2 and TiCl4L2 complexes. An increase in electron density on the chlorine atoms accompanied by a decrease on the central metal atom has been observed for the complexes arranged according to their stability. The arrangement of Sn, Sb, and Ti complexes with dimethyl sulfide according to their increasing stability is in disagreement with the order of the complexes with respect to electron density on the sulfur atom.

    Original languageEnglish
    Pages (from-to)215-222
    Number of pages8
    JournalJournal of Molecular Structure
    Volume324
    Issue number3
    DOIs
    Publication statusPublished - 18 Aug 1994

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    ASJC Scopus subject areas

    • Structural Biology
    • Organic Chemistry
    • Physical and Theoretical Chemistry
    • Spectroscopy
    • Materials Science (miscellaneous)
    • Atomic and Molecular Physics, and Optics

    Cite this

    Poleshchuk, O. K., Nogaj, B., Kasprzak, J., Koput, J., Dolenko, G. N., Elin, V. P., & Ivanovskii, A. L. (1994). Investigation of the electronic structure of SnCl4L2, TiCl4L2 and SbCl5L complexes by X-ray fluorescence spectroscopy. Journal of Molecular Structure, 324(3), 215-222. https://doi.org/10.1016/0022-2860(94)08316-9