Investigation of the charge state of heteroatoms in organic compounds of third-row elements by x-ray fluorescence spectroscopy 11. Redistribution of electron density in simple phosphorus-containing molecules upon complexation with AlBr₃

G. N. Dolenko, V. P. Elin, O. Kh Poleshchuk, A. L. Litvin, V. K. Voronov

Research output: Contribution to journal › Article

Abstract

The electron density on the atom in the ligands PCl₃, PPH₃, SPCl₃, and OPCl₃ by means of which they are coordinated to a metal atom, decreases upon coordination with AlBr₃ twice as much as does the total electron density of the ligands, and the ionicity of the PCl bonds in the ligands increases appreciably upon complexation.

Original language	English
Pages (from-to)	352-354
Number of pages	3
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	40
Issue number	2
DOIs	https://doi.org/10.1007/BF00965430
Publication status	Published - Feb 1991

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Dolenko, G. N., Elin, V. P., Poleshchuk, O. K., Litvin, A. L., & Voronov, V. K. (1991). Investigation of the charge state of heteroatoms in organic compounds of third-row elements by x-ray fluorescence spectroscopy 11. Redistribution of electron density in simple phosphorus-containing molecules upon complexation with AlBr₃ Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 40(2), 352-354. https://doi.org/10.1007/BF00965430

Investigation of the charge state of heteroatoms in organic compounds of third-row elements by x-ray fluorescence spectroscopy 11. Redistribution of electron density in simple phosphorus-containing molecules upon complexation with AlBr₃ . / Dolenko, G. N.; Elin, V. P.; Poleshchuk, O. Kh; Litvin, A. L.; Voronov, V. K.

In: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, Vol. 40, No. 2, 02.1991, p. 352-354.

Research output: Contribution to journal › Article

Dolenko, GN, Elin, VP, Poleshchuk, OK, Litvin, AL & Voronov, VK 1991, 'Investigation of the charge state of heteroatoms in organic compounds of third-row elements by x-ray fluorescence spectroscopy 11. Redistribution of electron density in simple phosphorus-containing molecules upon complexation with AlBr₃ ', Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, vol. 40, no. 2, pp. 352-354. https://doi.org/10.1007/BF00965430

Dolenko GN, Elin VP, Poleshchuk OK, Litvin AL, Voronov VK. Investigation of the charge state of heteroatoms in organic compounds of third-row elements by x-ray fluorescence spectroscopy 11. Redistribution of electron density in simple phosphorus-containing molecules upon complexation with AlBr₃ Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1991 Feb;40(2):352-354. https://doi.org/10.1007/BF00965430

Dolenko, G. N. ; Elin, V. P. ; Poleshchuk, O. Kh ; Litvin, A. L. ; Voronov, V. K. / Investigation of the charge state of heteroatoms in organic compounds of third-row elements by x-ray fluorescence spectroscopy 11. Redistribution of electron density in simple phosphorus-containing molecules upon complexation with AlBr₃ In: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1991 ; Vol. 40, No. 2. pp. 352-354.

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abstract = "The electron density on the atom in the ligands PCl3, PPH3, SPCl3, and OPCl3 by means of which they are coordinated to a metal atom, decreases upon coordination with AlBr3 twice as much as does the total electron density of the ligands, and the ionicity of the PCl bonds in the ligands increases appreciably upon complexation.",

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10.1007/BF00965430