Investigation of the charge state of heteroatoms in organic compounds of third-row elements by x-ray fluorescence spectroscopy 11. Redistribution of electron density in simple phosphorus-containing molecules upon complexation with AlBr3

G. N. Dolenko, V. P. Elin, O. Kh Poleshchuk, A. L. Litvin, V. K. Voronov

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    1 Citation (Scopus)

    Abstract

    The electron density on the atom in the ligands PCl3, PPH3, SPCl3, and OPCl3 by means of which they are coordinated to a metal atom, decreases upon coordination with AlBr3 twice as much as does the total electron density of the ligands, and the ionicity of the PCl bonds in the ligands increases appreciably upon complexation.

    Original languageEnglish
    Pages (from-to)352-354
    Number of pages3
    JournalBulletin of the Academy of Sciences of the USSR Division of Chemical Science
    Volume40
    Issue number2
    DOIs
    Publication statusPublished - Feb 1991

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    Fluorescence spectroscopy
    Complexation
    Organic compounds
    Phosphorus
    Carrier concentration
    Ligands
    X rays
    Molecules
    Atoms
    Metals

    ASJC Scopus subject areas

    • Chemistry(all)

    Cite this

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    abstract = "The electron density on the atom in the ligands PCl3, PPH3, SPCl3, and OPCl3 by means of which they are coordinated to a metal atom, decreases upon coordination with AlBr3 twice as much as does the total electron density of the ligands, and the ionicity of the PCl bonds in the ligands increases appreciably upon complexation.",
    author = "Dolenko, {G. N.} and Elin, {V. P.} and Poleshchuk, {O. Kh} and Litvin, {A. L.} and Voronov, {V. K.}",
    year = "1991",
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    T1 - Investigation of the charge state of heteroatoms in organic compounds of third-row elements by x-ray fluorescence spectroscopy 11. Redistribution of electron density in simple phosphorus-containing molecules upon complexation with AlBr3

    AU - Dolenko, G. N.

    AU - Elin, V. P.

    AU - Poleshchuk, O. Kh

    AU - Litvin, A. L.

    AU - Voronov, V. K.

    PY - 1991/2

    Y1 - 1991/2

    N2 - The electron density on the atom in the ligands PCl3, PPH3, SPCl3, and OPCl3 by means of which they are coordinated to a metal atom, decreases upon coordination with AlBr3 twice as much as does the total electron density of the ligands, and the ionicity of the PCl bonds in the ligands increases appreciably upon complexation.

    AB - The electron density on the atom in the ligands PCl3, PPH3, SPCl3, and OPCl3 by means of which they are coordinated to a metal atom, decreases upon coordination with AlBr3 twice as much as does the total electron density of the ligands, and the ionicity of the PCl bonds in the ligands increases appreciably upon complexation.

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