Investigation of sintering behavior of ZrO2 (Y) ceramic green body by means of non-isothermal dilatometry and thermokinetic analysis

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Abstract

Using the method of dilatometry, kinetic characteristics of compacts shrinkage manufactured from ultrafine plasmochemical ZrO2 (Y) powders and commercial Tosoh’s powders are investigated. The shrinkage curves are constructed with a DIL 402 C high-sensitivity dilatometer in a non-isothermal heating mode at different heating rates (1, 2, 5 and 10 °C min−1). It is shown that the plasmochemical powders are characterized by a lower sintering efficiency than the Tosoh’s powders. The kinetic results are processed using a Netzsch Thermokinetics license software program developed for those who make use of devices manufactured by the Netzsch-Geratebau GmbH. The kinetic characteristics of compact shrinkage are determined as a function of partial length variation using Friedman’s analysis. Considerable differences are found between the values of apparent shrinkage activation energy for plasmochemical and Tosoh’s powders in the initial and final shrinkage stages. We attribute the mentioned differences in phase composition of the powders and their degree of agglomeration. In the intermediate shrinkage stage, the values of the apparent activation energy obtained for both types of powders have only marginal differences.

Original languageEnglish
Pages (from-to)1-8
Number of pages8
JournalJournal of Thermal Analysis and Calorimetry
Volume128
Issue number2
DOIs
Publication statusAccepted/In press - 24 Nov 2016

Fingerprint

dilatometry
Powders
shrinkage
sintering
Sintering
ceramics
Kinetics
kinetics
Activation energy
activation energy
extensometers
Dilatometers
heating
agglomeration
Heating rate
Phase composition
Agglomeration
computer programs
Heating
sensitivity

Keywords

  • Dilatometry
  • Shrinkage kinetics
  • Thermokinetic analysis
  • Zirconia ceramics

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

Cite this

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title = "Investigation of sintering behavior of ZrO2 (Y) ceramic green body by means of non-isothermal dilatometry and thermokinetic analysis",
abstract = "Using the method of dilatometry, kinetic characteristics of compacts shrinkage manufactured from ultrafine plasmochemical ZrO2 (Y) powders and commercial Tosoh’s powders are investigated. The shrinkage curves are constructed with a DIL 402 C high-sensitivity dilatometer in a non-isothermal heating mode at different heating rates (1, 2, 5 and 10 °C min−1). It is shown that the plasmochemical powders are characterized by a lower sintering efficiency than the Tosoh’s powders. The kinetic results are processed using a Netzsch Thermokinetics license software program developed for those who make use of devices manufactured by the Netzsch-Geratebau GmbH. The kinetic characteristics of compact shrinkage are determined as a function of partial length variation using Friedman’s analysis. Considerable differences are found between the values of apparent shrinkage activation energy for plasmochemical and Tosoh’s powders in the initial and final shrinkage stages. We attribute the mentioned differences in phase composition of the powders and their degree of agglomeration. In the intermediate shrinkage stage, the values of the apparent activation energy obtained for both types of powders have only marginal differences.",
keywords = "Dilatometry, Shrinkage kinetics, Thermokinetic analysis, Zirconia ceramics",
author = "Surzhikov, {A. P.} and Ghyngazov, {S. A.} and Frangulyan, {T. S.} and Vasil’ev, {I. P.} and Chernyavskii, {A. V.}",
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AU - Surzhikov, A. P.

AU - Ghyngazov, S. A.

AU - Frangulyan, T. S.

AU - Vasil’ev, I. P.

AU - Chernyavskii, A. V.

PY - 2016/11/24

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N2 - Using the method of dilatometry, kinetic characteristics of compacts shrinkage manufactured from ultrafine plasmochemical ZrO2 (Y) powders and commercial Tosoh’s powders are investigated. The shrinkage curves are constructed with a DIL 402 C high-sensitivity dilatometer in a non-isothermal heating mode at different heating rates (1, 2, 5 and 10 °C min−1). It is shown that the plasmochemical powders are characterized by a lower sintering efficiency than the Tosoh’s powders. The kinetic results are processed using a Netzsch Thermokinetics license software program developed for those who make use of devices manufactured by the Netzsch-Geratebau GmbH. The kinetic characteristics of compact shrinkage are determined as a function of partial length variation using Friedman’s analysis. Considerable differences are found between the values of apparent shrinkage activation energy for plasmochemical and Tosoh’s powders in the initial and final shrinkage stages. We attribute the mentioned differences in phase composition of the powders and their degree of agglomeration. In the intermediate shrinkage stage, the values of the apparent activation energy obtained for both types of powders have only marginal differences.

AB - Using the method of dilatometry, kinetic characteristics of compacts shrinkage manufactured from ultrafine plasmochemical ZrO2 (Y) powders and commercial Tosoh’s powders are investigated. The shrinkage curves are constructed with a DIL 402 C high-sensitivity dilatometer in a non-isothermal heating mode at different heating rates (1, 2, 5 and 10 °C min−1). It is shown that the plasmochemical powders are characterized by a lower sintering efficiency than the Tosoh’s powders. The kinetic results are processed using a Netzsch Thermokinetics license software program developed for those who make use of devices manufactured by the Netzsch-Geratebau GmbH. The kinetic characteristics of compact shrinkage are determined as a function of partial length variation using Friedman’s analysis. Considerable differences are found between the values of apparent shrinkage activation energy for plasmochemical and Tosoh’s powders in the initial and final shrinkage stages. We attribute the mentioned differences in phase composition of the powders and their degree of agglomeration. In the intermediate shrinkage stage, the values of the apparent activation energy obtained for both types of powders have only marginal differences.

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